Toner particle, electrophotographic toner, developing agent, toner cartridge and image forming apparatus, and manufacture method of toner particle

Abstract

In accordance with an embodiment, a toner particle comprises two or more glass transition temperatures. Wherein, a first glass transition temperature is within a range from 5 degrees centigrade to 20 degrees centigrade and a second glass transition temperature is within a range from 50 degrees centigrade to 65 degrees centigrade.

What is claimed is: 
     
       1. A toner particle, comprising: a binder resin, a coloring agent, and a wax, wherein
 two or more glass transition temperatures exist, and 
 a first glass transition temperature for a core of the toner particle is in a first range from 5 degrees centigrade to equal to or less than 9 degrees centigrade; 
 a second glass transition temperature for a shell of the toner particle is in a second range from 50 degrees centigrade to 65 degrees centigrade, and 
 a difference between the first glass transition temperature and the second glass transition temperature is within a third range from 40 degrees centigrade to 50 degrees centigrade. 
 
     
     
       2. The toner particle according to  claim 1 , wherein
 the two or more glass transition temperatures only include the first glass transition temperature and the second glass transition temperature. 
 
     
     
       3. The toner particle according to  claim 1 , further comprising:
 a capsule structure constituted by the core and the shell. 
 
     
     
       4. The toner particle according to  claim 1 , wherein
 the compound comprises at least one of a charge control agent and a cross-linkable material. 
 
     
     
       5. The toner particle according to  claim 1 , wherein
 the shell binder resin having a thickness in a range from equal to or greater than 0.4 μm to less than 1.8 μm. 
 
     
     
       6. An electrophotographic toner comprising a toner particle according to  claim 1 . 
     
     
       7. A developing agent comprising the electrophotographic toner according to  claim 6 . 
     
     
       8. A toner cartridge for housing the electrophotographic toner according to  claim 6 . 
     
     
       9. An image forming apparatus for housing the electrophotographic toner according to  claim 6 . 
     
     
       10. A manufacture method of a toner particle, comprising:
 adding a flocculant in a mixture containing a first binder resin, a coloring agent, and a wax to form a core through aggregating the mixture at a first temperature of more than 20 degrees centigrade; 
 cooling the core to a second temperature smaller than 20 degrees centigrade and adding a flocculant in the core at a third temperature smaller than 20 degrees centigrade; and 
 adding a second binder resin in the core added with the flocculant more than twice at different temperatures to form a shell through fusing the second binder resin for the shell in the core; wherein 
 a first glass transition temperature of the first binder resin for the core is in a first range from 0 degree centigrade to 20 degrees centigrade; 
 a second glass transition temperature of the second binder resin for the shell is in a second range from 55 degrees centigrade to 75 degrees centigrade, and 
 a difference between the first glass transition temperature and the second glass transition temperature is within a third range from 40 degrees centigrade to 50 degrees centigrade. 
 
     
     
       11. The manufacture method of the toner particle according to  claim 10 , wherein
 the first binder resin and the second binder resin have identical chemical structures. 
 
     
     
       12. The manufacture method of a toner particle according to  claim 10 , wherein
 the compound includes at least one of a charge control agent and a cross-linkable material. 
 
     
     
       13. A manufacture method of a toner particle, comprising:
 aggregating a first binder resin, a coloring agent, and a wax in a dispersion at a first temperature of more than 20 degrees centigrade to form a toner core; 
 cooling the toner core in the dispersion to a second temperature of less than 20 degrees centigrade; 
 adding a second binder resin in the dispersion including the toner core at a third temperature to form a shell, the third temperature having a range from more than 10 degrees centigrade to less than 20 degrees centigrade; 
 aggregating the toner core and the second binder resin in the dispersion; heating the dispersion to form an aggregated particle; and 
 fusing the aggregated particle; wherein 
 a first glass transition temperature of the toner core is in a first range from 0 degree centigrade to 20 degrees centigrade; 
 a second glass transition temperature of the shell is in a second range from 55 degrees centigrade to 75 degrees centigrade, and 
 a difference between the first glass transition temperature and the second glass transition temperature is within a third range from 40 degrees centigrade to 50 degrees centigrade. 
 
     
     
       14. The manufacture method of the toner particle according to  claim 13 , wherein
 the second binder resin is added in the dispersion through a first adding of the second binder resin and a second adding of the second binder resin. 
 
     
     
       15. The manufacture method of a toner particle, according to  claim 14 , wherein
 the first adding of the second binder resin is performed at a fourth temperature, the fourth temperature being less than 20 degrees centigrade; and 
 the second adding of the second binder resin is performed at a fifth temperature, the fourth temperature being higher than the first temperature. 
 
     
     
       16. The manufacture method of a toner particle, according to  claim 15 , wherein
 a difference between the fourth temperature and the fifth temperature is more than 15 degrees centigrade. 
 
     
     
       17. The manufacture method of a toner particle, according to  claim 13 , wherein
 the second binder resin is added in the dispersion through a first adding of the second binder resin, a second adding of the second binder resin, and a third adding of the second binder resin. 
 
     
     
       18. The manufacture method of a toner particle, according to  claim 17 , wherein
 the first adding of the second binder resin is performed at a sixth temperature, the sixth temperature being more than 10 degrees centigrade and less than 20 degrees centigrade; 
 the second adding of the second binder resin is performed at a seventh temperature, the seventh temperature being more than 30 degrees centigrade and less than 36 degrees centigrade; and 
 the third adding of the second binder resin is performed at an eighth temperature, the eighth temperature being more than 40 degrees centigrade and less than 50 degrees centigrade. 
 
     
     
       19. The manufacture method of the toner particle according to  claim 13 , wherein
 the first binder resin and the second binder resin have identical chemical structures. 
 
     
     
       20. The manufacture method of a toner particle according to  claim 13 , wherein
 the compound comprises at least one of a charge control agent and a cross-linkable material.