Phosphor containing Ce

Abstract

A phosphor contains a crystal phase having a chemical composition CexM3-x-yβ6γ11-z. M is one or more elements selected from the group consisting of Sc, Y, La, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu. β contains Si in an amount of 50 mol % or more of a total mol of β. γcontains N in an amount of 80 mol % or more N of a total mol of γ. x satisfies 0<x≤0.6. y satisfies 0≤y≤1.0. z satisfies 0≤z≤1.0. The phosphor shows a maximum peak of an emission spectrum in a wavelength range of 600 nm or more and 800 nm or less and a first peak of an excitation spectrum in a wavelength range of 500 nm or more and 600 nm or less.

What is claimed is: 
     
       1. A phosphor comprising a crystal phase having a chemical composition Ce x M 3-x-y β 6 γ 11-z , where
 M is one or more elements selected from the group consisting of Sc, Y, La, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu; 
 β contains Si in an amount of 50 mol % or more of a total mol of β; 
 γ contains N in an amount of 80 mol % or more of a total mol of γ; 
 0<x≤0.6; 
 0≤y≤1.0; and 
 0≤z≤1.0, wherein 
 the phosphor shows: 
 a maximum peak of an emission spectrum in a wavelength range of 600 nm or more and 800 nm or less; and 
 a first peak of an excitation spectrum in a wavelength range of 500 nm or more and 600 nm or less. 
 
     
     
       2. The phosphor according to  claim 1 , wherein
 the M contains La in an amount of 90 mol % or more of a total mol of M. 
 
     
     
       3. The phosphor according to  claim 1 , wherein
 the β further contains one or two elements selected from the group consisting of Al and Ga. 
 
     
     
       4. The phosphor according to  claim 3 , wherein
 the β contains the one or two elements in an amount (100×/6) mol % or more of the total mol of β. 
 
     
     
       5. The phosphor according to  claim 1 , wherein
 the y further contains O. 
 
     
     
       6. The phosphor according to  claim 1 , wherein
 the x satisfies 0.015≤x≤0.3. 
 
     
     
       7. The phosphor according to  claim 1 , wherein the phosphor shows
 a second peak of the excitation spectrum in a wavelength range of 350 nm or more and less than 500 nm. 
 
     
     
       8. The phosphor according to  claim 7 , wherein
 the first or second peak is the maximum peak of the excitation spectrum. 
 
     
     
       9. The phosphor according to  claim 1 , wherein
 the crystal phase has a 1/e emission lifetime of 100 ns or less. 
 
     
     
       10. The phosphor according to  claim 1 , wherein the crystal phase shows diffraction peaks in
 (1) 2θ: 17.8° or more and 18.8° or less; 
 (2) 2θ: 26.2° or more and 27.2° or less; 
 (3) 2θ: 27.2° or more and 28.2° or less; 
 (4) 2θ: 30.5° or more and 31.5° or less 
 (5) 2θ: 32.8° or more and 33.8° or less; and 
 (6) 2θ: 35.8° or more and 36.8° or less 
 in an X-ray diffraction pattern measured with Cu-Kα radiation. 
 
     
     
       11. The phosphor according to  claim 1 , wherein
 in an EXAFS radial distribution function spectrum at K-absorption edge of Ce, a first neighbor shell of Ce has a peak having a height lower than that of a peak of a second neighbor shell of Ce. 
 
     
     
       12. A phosphor comprising a crystal phase having a chemical composition Ce x M 3-x-y β 6 γ 11-z , where
 M is one or more elements selected from the group consisting of Sc, Y, La, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu; 
 β contains Si in an amount of 50 mol % or more of a total mol of β; 
 γ contains N in an amount of 80 mol % or more of a total mol of γ; 
 0<x≤0.6; 
 0≤y≤1.0; and 
 0≤z≤1.0, wherein 
 in an EXAFS radial distribution function spectrum at K-absorption edge of Ce, a first neighbor shell of Ce has a peak having a height lower than that of a peak of a second neighbor shell of Ce. 
 
     
     
       13. The phosphor according to  claim 11 , wherein
 the height of the peak of the first neighbor shell is 0.8 times or more and 0.9 times or less the height of the peak of the second neighbor shell. 
 
     
     
       14. The phosphor according to  claim 1 , wherein
 in an EXAFS radial distribution function spectrum at K-absorption edge of Ce, the coordination number of a first neighbor shell of Ce is seven. 
 
     
     
       15. A phosphor comprising:
 a crystal phase having a chemical composition Ce x M 3-x-y β 6 γ 11-z , where 
 M is one or more elements selected from the group consisting of Sc, Y, La, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu; 
 β contains Si in an amount of 50 mol % or more of a total mol of β; 
 γ contains N in an amount of 80 mol % or more of a total mol of γ; 
 0<x≤0.6; 
 0≤y≤1.0; and 
 0≤z≤1.0, wherein 
 in an EXAFS radial distribution function spectrum at K-absorption edge of Ce, the coordination number of a first neighbor shell of Ce is seven. 
 
     
     
       16. The phosphor according to  claim 1 , wherein
 the y is 0 and the z is 0. 
 
     
     
       17. A light-emitting apparatus comprising:
 an excitation light source emitting light of a wavelength of 600 nm or less; and 
 a phosphor that is irradiated with the light emitted by the excitation light source and emits fluorescence having a wavelength longer than a wavelength of the light emitted by the excitation light source, wherein 
 the phosphor comprises a crystal phase having a chemical composition Ce x M 3-x-y β 6 γ 11-z , where 
 M is one or more elements selected from the group consisting of Sc, Y, La, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu; 
 β contains Si in an amount of 50 mol % or more of a total mol of β; 
 γ contains N in an amount of 80 mol % or more of a total mol of γ; 
 0<x≤0.6; 
 0≤y≤1.0; and 
 0≤z≤1.0, and 
 the phosphor shows: 
 a maximum peak of an emission spectrum in a wavelength range of 600 nm or more and 800 nm or less; and 
 a first peak of an excitation spectrum in a wavelength range of 500 nm or more and 600 nm or less. 
 
     
     
       18. The light-emitting apparatus according to  claim 17 , wherein
 the excitation light source emits the light having a wavelength of 500 nm or more and 600 nm or less. 
 
     
     
       19. The light-emitting apparatus according to  claim 17 , wherein
 the excitation light source emits the light having a wavelength of 420 nm or more and 480 nm or less. 
 
     
     
       20. The light-emitting apparatus according to  claim 17 , wherein
 the excitation light source is an LED or an LD. 
 
     
     
       21. The light-emitting apparatus according to  claim 17 , wherein
 the phosphor is a first phosphor, 
 the light-emitting apparatus further comprises a second phosphor that is irradiated with the light emitted by the excitation light source and emits fluorescence having a wavelength longer than a wavelength of the light emitted by the excitation light source, and 
 the second phosphor shows a maximum peak of an emission spectrum in a wavelength range of 500 nm or more and 600 nm or less. 
 
     
     
       22. The light-emitting apparatus according to  claim 21 , wherein
 the second phosphor emits yellow light, and 
 the light-emitting apparatus further comprises a third phosphor that is irradiated with the light emitted by the excitation light source and emits green light.