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US11248169B2ActiveUtilityPatentIndex 50

Scintillator matertial including an activator and co-dopant

Assignee: STICHTING TECHNISCHE WETENSCHAPPENPriority: Mar 4, 2016Filed: Jul 10, 2020Granted: Feb 15, 2022
Est. expiryMar 4, 2036(~9.7 yrs left)· nominal 20-yr term from priority
Inventors:DORENBOS PIETERKRÄMER KARLALEKHIN MIKHAIL
C09K 11/7791B60T 8/1706B60W 2050/0055G06F 17/10B60T 8/261B60T 8/3225B60W 40/112G01T 1/2023B60W 2050/0052B60W 2520/10B60W 2050/0056B60W 40/114G01T 1/2006B60W 2300/36B60Y 2200/12G01T 1/2018
50
PatentIndex Score
0
Cited by
39
References
40
Claims

Abstract

The disclosure relates to a scintillator material for a radiation detector. In an embodiment, the scintillator material can include a crystalline alkaline-earth metal halide comprising at least one alkaline-earth metal selected from Mg, Ca, Sr, Ba, said alkaline-earth metal halide being doped with at least one dopant that activates the scintillation thereof other than Sm2+, and co-doped with Sm2+, said alkaline-earth metal halide comprising at least one halogen selected from Br, Cl, I.

Claims

exact text as granted — not AI-modified
What is claimed is: 
     
       1. A scintillator material, comprising:
 a dopant that activates scintillation and has a first emission wavelength; and a co-dopant having a second emission wavelength greater than the first emission wavelength, 
 wherein: 
 the scintillator material is configured to emit at a first wavelength range and at a second wavelength range spaced apart from the first wavelength range, wherein the first wavelength range includes the first emission wavelength, and the second emission wavelength range includes the second emission wavelength; 
 a wavelength of maximum emission of the scintillator material is in the second wavelength range; and 
 self-absorption of the scintillator material is higher at the first wavelength range than self-absorption at the second wavelength range. 
 
     
     
       2. The scintillator material of  claim 1 , wherein the second wavelength range is greater than 670 nm. 
     
     
       3. The scintillator material of  claim 1 , wherein the wavelength of maximum emission is greater than 700 nm. 
     
     
       4. The scintillator material of  claim 1 , wherein the scintillator material comprises a metal halide. 
     
     
       5. The scintillator material of  claim 4 , wherein the metal halide comprises an alkaline earth metal, an alkali metal, or any combination thereof. 
     
     
       6. The scintillator material of  claim 4 , wherein the metal halide comprises an alkaline earth metal including Mg, Ca, Sr, Ba, or a combination thereof. 
     
     
       7. The scintillator material of  claim 6 , wherein the metal halide further comprises an alkali metal including Li, Na, Rb, Cs, or a combination thereof. 
     
     
       8. The scintillator material of  claim 4 , wherein the metal halide comprises a halogen including Cl, Br, I, or any combination thereof. 
     
     
       9. The scintillator material of  claim 1 , wherein the dopant comprises a lanthanide. 
     
     
       10. The scintillator material of  claim 1 , wherein the dopant comprises Eu 2+ , Ce 3+ , Pr 3+ , Tl + , Yb 2+ , or any combination thereof. 
     
     
       11. The scintillator material of  claim 1 , wherein the co-dopant is capable of being excited by an excited dopant. 
     
     
       12. The scintillator material of  claim 1 , wherein the co-dopant comprises a lanthanide. 
     
     
       13. The scintillator material of  claim 12 , wherein the co-dopant comprises Sm 3+ . 
     
     
       14. The scintillator material of  claim 1 , wherein the dopant is present in the scintillator material in a proportion greater than 0.2 mol % and less than 20 mol %. 
     
     
       15. The scintillator material of  claim 1 , wherein the co-dopant is present in the scintillator material in a proportion greater than 0.01 mol % and less than 10 mol %. 
     
     
       16. A radiation detector, comprising a scintillator including the scintillator material of  claim 1 . 
     
     
       17. The radiation detector of  claim 16 , further comprising a photodetector sensitive to a wavelength in the second emission wavelength range. 
     
     
       18. A scintillator material,
 comprising a metal halide doped with a dopant that activates scintillation and a co-dopant, 
 wherein: 
 the dopant comprises a lanthanide and a first emission wavelength; and 
 the co-dopant comprises a lanthanide that is different from the dopant and a second emission wavelength greater than the first emission wavelength; and 
 wherein: 
 the scintillator material is configured to emit at a first wavelength range and at a second wavelength range spaced apart from the first wavelength range, wherein the first wavelength range includes the first emission wavelength, and the second emission wavelength range includes the second emission wavelength length; 
 a wavelength of maximum emission of the scintillator material is in the second wavelength range; and 
 self-absorption of the scintillator material is higher at the first wavelength range than self-absorption at the second wavelength range. 
 
     
     
       19. The scintillator material of  claim 18 , wherein the metal halide comprises an alkaline earth metal including Mg, Ca, Sr, Ba, or a combination thereof. 
     
     
       20. The scintillator material of  claim 18 , wherein the dopant comprises Eu 2+ , Ce 3+ , Pr 3+ , Tl + , Yb 2+ , or any combination thereof. 
     
     
       21. The scintillator material of  claim 20 , wherein the co-dopant comprises Sm 3+ . 
     
     
       22. The scintillator material of  claim 18 , wherein the second wavelength range is greater than 670 nm. 
     
     
       23. A scintillator material, comprising:
 a crystalline alkaline-earth metal halide comprising at least one alkaline-earth metal including Mg, Ca, Sr, Ba, or a combination thereof, 
 said alkaline-earth metal halide being doped with a dopant that activates scintillation of the scintillator and a co-dopant, wherein the co-dopant is Sm 2+ , wherein the dopant comprises Eu 2+ , Ce 3+ , Pr 3+ , Tl + , Yb 2+ , or a combination thereof and is different from the co-dopant; said alkaline-earth metal halide comprising a halogen including Br, Cl, I, or a combination thereof. 
 
     
     
       24. The scintillator material of  claim 23 , wherein the alkaline-earth metal halide comprises at least two halogens. 
     
     
       25. The scintillator material of  claim 23 , wherein the dopant is selected from the group consisting of Eu 2+ , Ce 3+ , Pr 3+ , Tl + , Yb 2+ , and any combination thereof. 
     
     
       26. The scintillator material of  claim 23 , wherein the dopant is present in the alkaline-earth metal halide in a proportion of more than 0.2 mol % and less than 20 mol %. 
     
     
       27. The scintillator material of  claim 23 , wherein the dopant includes Eu 2+  present in the alkaline-earth metal halide in a proportion of more than 0.2 mol % and less than 10 mol %. 
     
     
       28. The scintillator material of  claim 23 , wherein Sm 2+  is present in the alkaline-earth metal halide in a proportion of more than 0.01 mol % and less than 10 mol %. 
     
     
       29. The scintillator material of  claim 23 , wherein Sm 2+  is present in the alkaline-earth metal halide in a proportion of at least 0.05 mol % and less than 2 mol %. 
     
     
       30. The scintillator material of  claim 23 , wherein the alkaline-earth metal halide comprises strontium iodide. 
     
     
       31. The scintillator material of  claim 30 , wherein the dopant comprises Eu 2+ . 
     
     
       32. The scintillator material of  claim 23 , wherein the alkaline-earth metal halide comprises strontium iodide, Eu 2+  being the dopant present in the alkaline-earth metal halide in a proportion of more than 0.2 mol % and less than 10 mol %, Sm 2+  being present in the alkaline-earth metal halide in a proportion of more than at least 0.05 mol % and at most 1 mol %. 
     
     
       33. The scintillator material of  claim 23 , represented by a formula selected from the group consisting of:
 Sr (1−x−y) Eu x Sm y I 2 , wherein 0<x<0.2 and 0<y<0.1; 
 Sr (1−x−y) Eu x Sm y I 2(1−u−v) Br 2u Cl 2v , wherein 0<x<0.2, 0<y<0.1, 0≤u<0.5, 0≤v<0.5, and (u+v)>0; 
 Sr (1−x−y) Eu x Sm y I (2+q)(1−u−v) Br ((2+q)*u) Cl ((2+q)*v)  wherein 0<x<0.2, 0<y<0.1, 0≤u<0.5, 0≤v<0.5, −0.05<q<0.05; 
 (Sr (1−z) Ca z ) (1−x−y) Eu x Sm y I 2  wherein 0<x<0.2, 0<y<0.1, 0≤z≤1.0; 
 (Sr (1−z) Ca z ) (1−x−y) Eu x Sm y I 2(1−u−v) Br 2u Cl 2v  wherein 0<x<0.2, 0<y<0.1, 0≤u≤1.0, 0≤v≤1.0, 0≤(u+v)≤1.0, 0≤z≤1.0; 
 (Sr (1−z) Ca z ) (1−x−y) Eu x Sm y I (2+q)(1−u−v) Br ((2+q)*u) Cl ((2+q)*v)  wherein 0<x<0.2, 0<y<0.1, 0≤u≤1.0, 0≤v≤1.0, 0≤(u+v)≤1.0, 0.05<q<0.05, and 0≤z≤1.0; 
 (Eu (1−x) Yb x ) (1−y) Sm y I (2+q)(1−u−v) Br ((2+q)*u) Cl ((2+q)*v) , wherein 0≤x≤1.0, 0<y<0.1, 0≤u≤1.0, 0≤v≤1.0, 0≤(u+v)≤1.0, and 0.05<q<0.05; 
 AB (1−x−y) C x Sm y I (3+q)(1−u−v) Br ((3+q)*u) Cl ((3+q)*v) , wherein 0<x<0.2, 0<y<0.1, 0≤u≤1.0, 0≤v≤1.0, 0≤(u+v)≤1.0, and 0.05<q<0.05; 
 A 2 B (1−x−y) C x Sm y I (4+q)(1−u−v) Br ((4+q)*u) Cl ((4+q)*v) , wherein 0<x<0.2, 0<y<0.1, 0≤u≤1.0, 0≤v≤1.0, 0≤(u+v)≤1.0, and 0.1<q<0.1; and 
 AB 2(1−x−y) C 2x Sm 2y I (5+q)(1−u−v) Br ((5+q)*u) Cl ((5+q)*v) , wherein 0<x<0.2, 0<y<0.1, 0≤u≤1.0, 0≤v≤1.0, 0≤(u+v)≤1.0, and 0.1<q<0.1, 
 
       wherein A represents an element including Na, K, Cs, Rb, or any combination thereof; B represents an element including Ca, Mg, Ba, Sr, or any combination thereof; and C represents an element including Eu 2+ , Yb 2+ , or a combination thereof. 
     
     
       34. The scintillator material of  claim 23 , comprising an optical absorption coefficient of less than 50% at a maximum scintillation emission wavelength. 
     
     
       35. The scintillator material of  claim 23 , comprising a volume of greater than 1 cm 3 . 
     
     
       36. The scintillator material of  claim 23 , comprising a thickness of at least 1.8 mm. 
     
     
       37. The scintillator material of  claim 23 , wherein the scintillator material is transparent to scintillation light emitted at a depth of at least 2 mm in the scintillator material. 
     
     
       38. The scintillator material of  claim 23 , wherein the scintillator material is monocrystalline. 
     
     
       39. A radiation detector, comprising a scintillator including the scintillator material of  claim 23 . 
     
     
       40. The radiation detector of  claim 39 , comprising a photodetector sensitive to a wavelength of greater than 670 nm.

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