Compositions for inhibiting corrosion

Abstract

The present disclosure relates to agents, compositions, and methods for inhibiting corrosion in various substrates, for example in metal substrates. The present disclosure also relates to compositions for inhibiting corrosion comprising at least one organic heterocyclic compound and at least one metal salt or mixed metal salt selected from rare earth, alkali earth and transition metals.

The invention claimed is: 
     
       1. A method comprising:
 applying a corrosion inhibitor composition to a surface of a substrate, wherein the corrosion inhibitor composition comprises: 
 at least one metal salt or mixed metal salt, wherein the metal is selected from the group consisting of Zn, La, Pr, Ce, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Co, Y, Sc, Zr, and combination(s) thereof; and 
 at least one corrosion inhibiting agent selected from an organic heterocyclic compound of Formula 1: 
 
       
         
           
           
               
               
           
         
         
           wherein:
 A is fused with one or more aryl or heteroaryl rings to form an imidazo-pyrazine wherein the ring is optionally substituted with one or more substituents, wherein a dotted line represents one or more optional double bonds; 
 Y 1  is selected from the group consisting of S or SH, wherein the dotted line represents a double bond when Y 1  is S or is absent when Y 1  is SH; 
 X 1  is selected from the group consisting of N and NH; 
 X 2  is selected from the group consisting of N and NR 5 ; and 
 R 5  is selected from the group consisting of hydrogen, amino, C 1 -C 10 alkyl, C 2 -C 10 alkenyl, C 2 -C 10 alkynyl, aryl, and heteroaryl, wherein amino, alkyl, alkenyl, alkynyl, aryl, or heteroaryl is optionally substituted. 
 
         
       
     
     
       2. The method of  claim 1 , wherein each of the metal salt or mixed metal salt and the corrosion inhibiting agent are provided as individual components in the composition and not a preformed metal-organic complex. 
     
     
       3. The method of  claim 1 , wherein a ratio of metal salt:corrosion inhibiting agent in the corrosion inhibitor composition is provided with an excess of the metal salt in comparison to the corrosion inhibiting agent. 
     
     
       4. The method of  claim 1 , wherein Y 1  is SH. 
     
     
       5. The method of  claim 1 , wherein X 1  is N. 
     
     
       6. The method of  claim 1 , wherein X 2  is NH. 
     
     
       7. The method of  claim 1 , wherein the metal is selected from at least one of La, Pr, Ce, Co, and Y. 
     
     
       8. The method of  claim 1 , wherein the metal is selected from at least one of Zn, Pr, and Ce. 
     
     
       9. The method of  claim 1 , wherein the substrate is a copper-containing metal substrate. 
     
     
       10. The method of  claim 1 , wherein the imidazo-pyrazine is 1H-imidazo[4,5-b]pyrazine-2-thiol. 
     
     
       11. A composition comprising:
 at least one metal salt or mixed metal salt, wherein the metal is selected from the group consisting of Zn, La, Pr, Ce, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Co, Y, Sc, Zr, and combination(s) thereof; and 
 at least one corrosion inhibiting agent selected from an organic heterocyclic compound of Formula 1: 
 
       
         
           
           
               
               
           
         
         
           wherein:
 A is fused with one or more aryl or heteroaryl rings to form an imidazo-pyrazine, wherein the ring is optionally substituted with one or more substituents, wherein a dotted line represents one or more optional double bonds; 
 Y 1  is selected from the group consisting of S or SH, wherein the dotted line represents a double bond when Y 1  is S or is absent when Y 1  is SH; 
 X 1  is selected from the group consisting of N and NH; 
 X 2  is selected from the group consisting of N and NR 5 ; and 
 R 5  is selected from the group consisting of hydrogen, amino, C 1 -C 10 alkyl, C 2 -C 10 alkenyl, C 2 -C 10 alkynyl, aryl, and heteroaryl, wherein amino, alkyl, alkenyl, alkynyl, aryl, or heteroaryl is optionally substituted. 
 
         
       
     
     
       12. The composition of  claim 11 , wherein each of the metal salt or mixed metal salt and the corrosion inhibiting agent are provided as individual components in the composition and not a preformed metal-organic complex. 
     
     
       13. The composition of  claim 11 , wherein a ratio of metal salt:corrosion inhibiting agent in the corrosion inhibitor composition is provided with an excess of the metal salt in comparison to the corrosion inhibiting agent. 
     
     
       14. The composition of  claim 11 , wherein the composition has a concentration of the corrosion inhibiting agent of about 10 −3  M to about 5×10 −6  M. 
     
     
       15. The composition of  claim 11 , wherein the composition has a concentration of the metal of about 10 −3  M to about 5×10 −6  M. 
     
     
       16. The composition of  claim 11 , wherein the composition further comprises an organic polymer. 
     
     
       17. The composition of  claim 16 , wherein the organic polymer comprises one or more epoxy based resins. 
     
     
       18. The composition of  claim 11 , wherein the imidazo-pyrazine is 1H-imidazo[4,5-b]pyrazine-2-thiol. 
     
     
       19. The composition of  claim 11 , wherein the metal is selected from at least one of La, Pr, Ce, Co, and Y. 
     
     
       20. The composition of  claim 11 , wherein the metal is selected from at least one of Zn, Pr, and Ce.