US12344533B2ActiveUtilityA1

Molecular sieve SSZ-116, its synthesis and use

Assignee: CHEVRON USA INCPriority: Jan 16, 2020Filed: Dec 12, 2022Granted: Jul 1, 2025
Est. expiryJan 16, 2040(~13.5 yrs left)· nominal 20-yr term from priority
C01P 2004/03C01P 2002/72B01J 29/70B01J 29/047B01J 31/0244C01B 39/48
67
PatentIndex Score
0
Cited by
3
References
6
Claims

Abstract

A novel synthetic crystalline aluminogermanosilicate molecular sieve material, designated SSZ-116, is provided. SSZ-116 can be synthesized using 3-[(3,5-di-tert-butylphenyl)methyl]-1,2-dimethyl-1H-imidazolium cations as a structure directing agent. SSZ-116 may be used in organic compound conversion reactions and/or sorptive processes.

Claims

exact text as granted — not AI-modified
The invention claimed is: 
     
       1. A molecular sieve having, in its calcined form, a powder X-ray diffraction pattern including the following peaks: 
       
         
           
                 
                 
                 
               
                     
                 
                   2-Theta [±0.30°] 
                   d-Spacing [Å] 
                   Relative Intensity 
                 
                     
                 
                     
                 
                 
                 
                 
               
                   8.68 
                   10.18 
                   vs 
                 
                   11.23 
                   7.87 
                   w 
                 
                   15.60 
                   5.68 
                   vs 
                 
                   17.68 
                   5.01 
                   vs 
                 
                   20.79 
                   4.27 
                   m 
                 
                   23.14 
                   3.84 
                   w 
                 
                   23.56 
                   3.77 
                   w 
                 
                   23.98 
                   3.71 
                   w 
                 
                   25.20 
                   3.53 
                   w 
                 
                   25.83 
                   3.42 
                   vs 
                 
                   26.83 
                   3.32 
                    w. 
                 
                     
                 
             
                
                
                
               
               
                
               
            
             
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
       
     
     
       2. The molecular sieve of  claim 1 , and having a composition comprising the molar relationship:
   Al 2 O 3 :( n )TO 2    
 
       wherein n is ≥30; and T is a tetravalent element comprising silicon and germanium. 
     
     
       3. The molecular sieve of  claim 1 , and having a composition comprising the molar relationship:
   Al 2 O 3 :( n )TO 2    
 
       wherein n is ≥50; and T is a tetravalent element comprising silicon and germanium. 
     
     
       4. A molecular sieve having, in its as-synthesized form, a powder X-ray diffraction pattern including the following peaks: 
       
         
           
                 
                 
                 
               
                     
                 
                   2-Theta [±0.30°] 
                   d-Spacing [Å] 
                   Relative Intensity 
                 
                     
                 
                     
                 
                 
                 
                 
               
                   8.59 
                   10.29 
                   m 
                 
                   11.11 
                   7.96 
                   w 
                 
                   15.65 
                   5.66 
                   vs 
                 
                   17.49 
                   5.07 
                   w 
                 
                   20.87 
                   4.25 
                   m 
                 
                   23.02 
                   3.86 
                   m 
                 
                   23.60 
                   3.77 
                   w 
                 
                   24.05 
                   3.70 
                   w 
                 
                   25.30 
                   3.52 
                   m 
                 
                   25.90 
                   3.44 
                   m 
                 
                   26.91 
                   3.31 
                    w. 
                 
                     
                 
             
                
                
                
               
               
                
               
            
             
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
       
     
     
       5. The molecular sieve of  claim 4 , having a chemical composition comprising the following molar relationship: 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   TO 2 /Al 2 O 3   
                   ≥30 
                 
                     
                   Q/TO 2   
                   >0 to 0.1 
                 
                     
                     
                 
             
                
               
               
                
                
                
               
            
           
         
       
       wherein T is a tetravalent element comprising silicon and germanium; and Q comprises 3-[(3,5-di-tert-butylphenyl)methyl]-1,2-dimethyl-1H-imidazolium cations. 
     
     
       6. The molecular sieve of  claim 4 , having a chemical composition comprising the following molar relationship: 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   TO 2 /Al 2 O 3   
                   ≥50 
                 
                     
                   Q/TO 2   
                   >0 to 0.1 
                 
                     
                     
                 
             
                
               
               
                
                
                
               
            
           
         
       
       wherein T is a tetravalent element comprising silicon and germanium; and Q comprises 3-[(3,5-di-tert-butylphenyl)methyl]-1,2-dimethyl-1H-imidazolium cations.

Join the waitlist — get patent alerts

Track US12344533B2 — get alerts on status changes and closely related new filings.

We store only your email — no account needed. See our privacy policy.