Two-part aqueous composition for oxidative coloration of hair

Abstract

A two-part high aqueous-content system for oxidative coloration of hair utilizing an aqueous dye lotion formulation containing hydroxypropyl bisisosteramidopropyidimonium chloride conditioner, optionally with one or more surfactants, preferably a monomeric quaternary surfactant.

What is claimed is:  
     
         1 . A high aqueous-content dye lotion formulation for use in a two-part composition for oxidative dyeing of hair, the dye lotion formulation comprising: 
 at least about 50% by weight water;    a tinctorial effective amount of at least one primary dye intermediate and at least one coupler for the formation of an oxidative dye; and    a conditioning effective amount of hydroxypropyl bisisosteramidopropyidimonium chloride conditioner.    
     
     
         2 . A dye lotion formulation of  claim 1  wherein the conditioner is present in the lotion formulation in an amount of from about 1 to about 3% by weight.  
     
     
         3 . A dye lotion formulation of  claim 1  wherein the conditioner is present in the lotion formulation in an amount of about 2% by weight.  
     
     
         4 . A two-part aqueous composition for coloring and providing conditioning to human hair and which forms a gel on mixing of the two parts, the two-part aqueous composition comprising: 
 (a) an aqueous lotion first part comprising: a tinctorially effective amount of at least one primary dye intermediate and at least one coupler for the formation of oxidation dyes, a conditioning effective amount of hydroxypropyl bisisosteramidopropyldimonium chloride conditioner, and at least 50% by weight water; and    (b) an aqueous developer second part comprising: an oxidizing effective amount of a peroxide oxidizer, at least about 70% by weight water.    
     
     
         5 . A two-part aqueous composition of  claim 4  wherein 
 (a) the aqueous lotion first part has a pH of from about 7 to about 11 and contains from about 0.005% by weight to about 5% by weight of the at least one primary dye intermediate and the at least one coupler for the formation of oxidation dyes, a conditioning effective amount of at least about 0.1% by weight of the hydroxypropyl bisisosteramidopropyldimonium chloride conditioner; and  
 (b) the aqueous developer second part has a pH of from about 2 to about 6 and contains from about 0.5% by weight to about 40% by weight of the peroxide oxidizer.  
 
     
     
         6 . A composition of  claim 5  wherein: 
 a: the pH of the lotion is from 9.0 to 10.5, the primary dye intermediate and the coupler content is from 0.005% to 2.5% by weight; and  
 b: the pH of the aqueous developer is from 2.5 to 4.5, the peroxide oxidizer content is from 0.5% to 30% by weight hydrogen peroxide, and the water content is from about 70% to about 95% by weight.  
 
     
     
         7 . A composition of  claim 5  wherein the developer contains from about 0.5% to about 15% by weight of hydrogen peroxide.  
     
     
         8 . A composition of  claim 6  wherein the developer contains from about 3% to about 13% by weight of hydrogen peroxide.  
     
     
         9 . A composition of  claim 4  wherein the aqueous lotion first part additionally comprises a monomeric quaternary surfactant.  
     
     
         10 . A composition of in  claim 6  wherein: 
 the lotion formulation additionally comprises one or more surfactants selected from the group consisting of lauryl betaine, lauroamphoglycinate, lauroamphopropylsulfonate, lauroamphopropionate, lauroamphocarboxyglycinate, lauryl sultane, myristamidopropyl betaine, myristyl betaine, myristoamphoglycinate, myristyl propionate, stearoamphoglycinate, cocamidoethyl betaine, cocamidopropyl betaine, cocamidopropyl hydroxysultane, cocamidopropyl dimethylamine propionate, cocoamphoglycinate, cocoamphocarboxypropionate, cocoamphocarboxyglycinate, coco-betaine, cocoamphopropionate, cocoamphopropylsulfonate and soytrimonium chloride; and  
 the primary dye intermediate is selected from the group consisting of 2-methyl-benzene-1,4-diamine, benzene-1,4-diamine, 2-(2,5-diamino-phenyl)-ethanol, 1-(2,5-diamino-phenyl)-ethanol, 2-[(4-amino-phenyl)-(2-hydroxy-ethyl)-amino]-ethanol. 4-amino-phenol, 4-methylamino-phenol, 4-amino-3-methyl-phenol, 1-(5-amino-2-hydroxy-phenyl)-ethane -1,2-diol, 2-amino-phenol, 2-amino-5-methyl-phenol, 2-amino-6-methyl-phenol, N-(4-amino-3-hydroxy-phenyl)-acetamide, pyrimidine-2,4,5,6-tetramine and 2-(4,5-diamino-1H-pyrazol-1-yl)ethanol; and  
 the coupler is selected from the group consisting of: benzene-1,3-diol, 4-chlorobenzene-1,3-diol, naphthalen-1-o, 2-methyl-naphthalen-1-o, 2-methyl-benzene -1,3-diol, 2-(2,4-diamino-phenoxy)-ethanol, 2-(3-amino-4-methoxy-phenylamino)-ethanol, 2-[2,4-diamino-5-(2-hydroxy-ethoxy)-phenoxy]-ethanol, 3-(2,4-diamino-phenoxy)-propan -1-ol, 3-amino-phenol, 5-amino-2-methyl-phenol, 5-(2-hydroxy-ethylamino) -2-methyl-phenol, 3-amino-2-methyl-phenol, 3,4-dihydro-2H-1,4-benzoxazin-6-ol, 4-methyl-2-phenyl-2,4-dihydro-3H-pyrazol-3-one, and 1H-indol-6-ol, and 2-aminopyridin-3-ol.  
 
     
     
         11 . A kit containing a two-part aqueous composition, which forms a gel on mixing of the two parts for coloring human hair comprising separate first and second containers: 
 (a) the first container containing an aqueous lotion first part comprising: a tinctorially effective amount of at least one primary dye intermediate and at least one coupler for the formation of oxidation dyes, a conditioning effective amount of hydroxypropyl bisisosteramidopropyldimonium chloride conditioner, and at least 50% by weight water; and    (b) the second container containing an aqueous developer second part comprising: an oxidizing effective amount of a peroxide oxidizer, at least about 70% by weight water.    
     
     
         12 . A kit according to  claim 11  wherein: 
 (a) the first container containing the aqueous lotion first part has a pH of from about 7 to about 11 and contains from about 0.005% to about 5% by weight of the at least one primary dye intermediate and the at least one coupler for the formation of oxidation dyes, a conditioning effective amount of at least about 0.1% by weight of the hydroxypropyl bisisosteramidopropyldimonium chloride conditioner; and  
 (b) the second container containing the aqueous developer second part has a pH of from about 2 to about 6 and contains from about 0.5% to about 40% by weight of the peroxide oxidizer.  
 
     
     
         13 . A kit of  claim 12  wherein: 
 a: the pH of the lotion is from 9.0 to 10.5, the primary dye intermediate and the coupler content is from 0.005% to 2.5% by weight, and the content of the conditioner is from about 1% to about 3% by weight; and  
 b: the pH of the aqueous developer is from 2.5 to 4.5, the peroxide oxidizer content is from 0.5% to 30% by weight hydrogen peroxide, and the water content is about 70% to about 95% by weight.  
 
     
     
         14 . A kit of  claim 12  wherein the developer contains from about 0.5% to about 15% by weight of hydrogen peroxide.  
     
     
         15 . A kit of  claim 13  wherein the developer contains from about 3% to about 13% by weight of hydrogen peroxide.  
     
     
         16 . A kit of  claim 12  wherein the aqueous liquid lotion first part in the first container additionally comprises a monomeric quaternary surfactant.  
     
     
         17 . A kit of  claim 13  wherein: 
 the lotion formulation additionally comprises one or more surfactants selected from the group consisting of lauryl betaine, lauroamphoglycinate, lauroamphopropylsulfonate, lauroamphopropionate, lauroamphocarboxyglycinate, lauryl sultane, myristamidopropyl betaine, myristyl betaine, myristoamphoglycinate, myristyl propionate, stearoamphoglycinate, stearoamphopropylsulfonate, stearyl betaine, cocamidopropyl dimethylamine propionate, cocoamphoglycinate, cocoamphocarboxypropionate, cocoaphocarboxyglycinate, cocobetaine, cocoamphopropionate, cocoamphopropylsulfonate, and soytrimonium chloride; and  
 the primary dye intermediate is selected from the group consisting of the primary intermediate is selected from the group consisting of 2-methyl-benzene-1,4-diamine, benzene-1,4-diamine, 2-(2,5-diamino-phenyl)-ethanol, 1-(2,5-diamino-phenyl)-ethanol, 2-[(4-amino-phenyl)-(2-hydroxy-ethyl)-amino]-ethanol. 4-amino-phenol, 4-methylamino-phenol, 4-amino-3-methyl-phenol, 1-(5-amino-2-hydroxy-phenyl)-ethane-1 ,2-diol, 2-amino-phenol, 2-amino-5-methyl-phenol, 2-amino-6-methyl-phenol, N-(4-amino-3-hydroxy-phenyl)-acetamide, pyrimidine-2,4,5,6-tetramine and 2-(4,5-diamino-1H-pyrazol -1-yl)ethanol; and  
 the coupler is selected from the group consisting of: benzene-1,3-diol, 4-chlorobenzene-1,3-diol, naphthalen-1-ol, 2-methyl-naphthalen-1-ol, 2-methyl-benzene -1,3-diol, 2-(2,4-diamino-phenoxy)-ethanol, 2-(3-amino-4-methoxy-phenylamino)-ethanol, 2-[2 ,4-diamino-5-(2-hydroxy-ethoxy)-phenoxy]-ethanol, 3-(2 ,4-diamino-phenoxy)-propan -1-ol, 3-amino-phenol, 5-amino-2-methyl-phenol, 5-(2-hydroxy-ethylamino)-2-methyl-phenol, 3-amino-2-methyl-phenol, 3,4-dihydro-2H-1,4-benzoxazin-6-ol, 4-methyl-2-phenyl-2,4-dihydro-3H-pyrazol-3-one, and 1H-indol-6-ol, and 2-aminopyridin-3-ol.  
 
     
     
         18 . A method of coloring human hair which comprises contacting the hair with a mixture of a two-part aqueous composition which forms a gel on mixing of the two parts, wherein the two part aqueous composition comprises: 
 (a) an aqueous lotion first part comprising: a tinctorially effective amount of at least one primary dye intermediate and at least one coupler for the formation of oxidation dyes, a conditioning effective amount of hydroxypropyl bisisosteramidopropyldimonium chloride conditioner, and at least 50% by weight water; and    (b) an aqueous developer second part comprising: an oxidizing effective amount of a peroxide oxidizer, at least about 70% by weight water; and maintaining such contact until the hair is permanently dyed.    
     
     
         19 . A method of  claim 18  wherein: 
 (a) the aqueous lotion first part has a pH of from about 7 to about 11 and contains from about 0.005% to about 5% by weight of the at least one primary dye intermediate and at the least one coupler for the formation of oxidation dyes, and a conditioning effective amount of at least about 0.15 by weight of the hydroxypropyl bisisosteramidopropyldimonium chloride conditioner; and  
 (b) the aqueous developer second part has a pH of from about 2 to about 6 and contains from about 0.5% to about 40% by weight of the peroxide oxidizer.  
 
     
     
         20 . A method of  claim 19  wherein: 
 (a) the pH of the lotion is from 9.0 to 10.5, the primary dye intermediate and the coupler content is from 0.005% to 2.5% by weight, the hydroxypropyl bisisosteramidopropyldimonium chloride conditioner content is from about 0.1 to about 5% by weight; and  
 (b) the pH of the aqueous developer is from 2.5 to 4.5, and the peroxide oxidizer content is from 0.5% to 30% by weight.  
 
     
     
         21 . A method of  claim 19  wherein the developer contains from about 0.5% to about 15% by weight of hydrogen peroxide.  
     
     
         22 . A method of  claim 20  wherein the developer contains from about 3% to about 13% by weight of hydrogen peroxide.  
     
     
         23 . A method of  claim 19  wherein the aqueous lotion first part additionally comprises a monomeric quaternary surfactant.  
     
     
         24 . A method of  claim 20  wherein: 
 the aqueous lotion first part additionally comprises a surfactant selected from the group consisting of lauryl betaine, lauroamphoglycinate, lauroamphopropylsulfonate, lauroamphopropionate, lauroamphocarboxyglycinate, lauryl sultane, myristamidopropyl betairie, myristyl betaine, myristoamphoglycinate, myristyl propionate, stearoamphoglycinate, stearoamphopropionate, stearoamphopropylsulfonate, stearyl betairie, cocamidoethyl betaine, cocamidopropyl betaine, cocamidopropyl hydroxysultane, cocamidopropyl dimethylamine propionate, cocoamphoglycinate, cocoamphocarboxypropionate, cocoaphocarboxyglycinate, cocobetaine, cocoamphopropionate, cocoamphopropylsulfonate, soytrimonium chloride; and  
 the primary dye intermediate is selected from the group consisting of the primary intermediate is selected from the group consisting of 2-methyl-benzene-1,4-diamine, benzene-1,4-diamine, 2-(2,5-diamino-phenyl)-ethanol, 1-(2,5-diamino-phenyl)-ethanol, 2-[(4-amino-phenyl)-(2-hydroxy-ethyl)-amino]-ethanol, 4-amino-phenol, 4-methylamino-phenol, 4-amino-3-methyl-phenol, 1-(5-amino-2-hydroxy-phenyl)-ethane-1,2-diol, 2-amino-phenol, 2-amino-5-methyl-phenol, 2-amino-6-methyl-phenol, N-(4-amino-3-hydroxy-phenyl)-acetamide, pyrimidine-2,4,5,6-tetramine and 2-(4,5-diamino-1H-pyrazol-1-yl)ethanol; and  
 the coupler is selected from the group consisting of: benzene-1,3-diol, 4-chlorobenzene-1,3-diol, naphthalen-1-ol, 2-methyl-naphthalen-1-ol, 2-methyl-benzene-1,3-diol, 2-(2,4-diamino-phenoxy)-ethanol, 2-(3-amino-4-methoxy-phenylamino)-ethanol, 2-[2,4-diamino-5-(2-hydroxy-ethoxy)-phenoxy]-ethanol, 3-(2,4-diamino-phenoxy)-propan-1-ol, 3-amino-phenol, 5-amino-2-methyl-phenol, 5-(2-hydroxy-ethylamino)-2-methyl-phenol, 3-amino-2-methyl-phenol, 3,4-dihydro-2H-1,4-benzoxazin-6-ol, 4-methyl-2-phenyl-2,4-dihydro-3H-pyrazol-3-one, and 1H-indol-6-ol, and 2-aminopyridin-3-ol.  
 
     
     
         25 . In a method for oxidative coloring of hair with a two-part dyeing composition comprising a first dye base lotion formulation and a second developer formulation the improvement comprising using as the dye base lotion formulation a formulation comprising: 
 at least about 50% by weight water;    a tinctorial effective amount of at least one primary dye intermediate and at least one coupler for the formation of an oxidative dye; and    a conditioning effective amount of hydroxypropyl bisisosteramidopropyldimonium chloride conditioner.    
     
     
         26 . The method of  claim 25  wherein the conditioner is present in the lotion formulation in an amount of from about 1 to about 3% by weight.  
     
     
         27 . The method of  claim 25  wherein the conditioner is present in the lotion formulation in an amount of about 2% by weight.  
     
     
         28 . The method of  claim 25  wherein lotion formulation has a pH of from about 7 to about 11.