US2003039888A1PendingUtilityA1
Primary alkaline battery including nickel oxyhydroxide
Est. expiryAug 4, 2020(expired)· nominal 20-yr term from priority
Y02E60/10H01M 6/085H01M 4/364H01M 4/366H01M 4/52H01M 4/621H01M 6/08Y10T29/49108
45
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Claims
Abstract
An alkaline battery has a cathode including a nickel oxyhydroxide.
Claims
exact text as granted — not AI-modifiedWhat is claimed is:
1 . A primary alkaline battery comprising:
a cathode comprising cobalt oxyhydroxide-modified nickel oxyhydroxide; an anode; a separator; and an alkaline electrolyte.
2 . The battery of claim 1 , wherein the cobalt oxyhydroxide-modified nickel oxyhydroxide has a coating of a cobalt oxyhydroxide on a nickel oxyhydroxide.
3 . The battery of claim 1 , wherein the coating is substantially uniform.
4 . The battery of claim 1 , wherein the nickel oxyhydroxide is γ-NiOOH.
5 . The battery of claim 1 , wherein the cobalt oxyhydroxide is a sodium or potassium modified cobalt oxyhydroxide.
6 . The battery of claim 5 , wherein the cobalt oxyhydroxide is a potassium modified cobalt oxyhydroxide.
7 . The battery of claim 1 , wherein the cobalt oxyhydroxide-modified nickel oxyhydroxide is derived from nickel hydroxide coated with between 2% and 15% cobalt hydroxide by weight.
8 . The battery of claim 1 , wherein the cobalt oxyhydroxide-modified nickel oxyhydroxide is derived from nickel hydroxide coated with between 3% and 10% cobalt hydroxide by weight.
9 . The battery of claim 1 , wherein the cobalt oxyhydroxide-modified nickel oxyhydroxide is derived from nickel hydroxide coated with between 4% and 8% cobalt hydroxide by weight.
10 . The battery of claim 1 , wherein the cobalt oxyhydroxide-modified nickel oxyhydroxide is derived from nickel hydroxide coated with 5% cobalt hydroxide by weight.
11 . The battery of claim 1 , wherein the cobalt oxyhydroxide-modified nickel oxyhydroxide is derived from α-Ni(OH) 2 .
12 . The battery of claim 1 , wherein the anode comprises zinc.
13 . The battery of claim 1 , wherein the nickel oxyhydroxide is substantially non-fractured.
14 . The battery of claim 1 , wherein the cathode further includes an oxidizing additive.
15 . The battery of claim 14 , wherein the oxidizing additive includes K 2 S 2 O 8 or KMnO 4 .
16 . A primary alkaline battery comprising:
a cathode comprising a nickel oxyhydroxide derived from α-Ni(OH) 2 ; an anode; a separator; and an alkaline electrolyte.
17 . The battery of claim 16 , wherein the nickel oxyhydroxide is a cobalt oxyhydroxide-modified nickel oxyhydroxide.
18 . The battery of claim 16 , wherein the cobalt oxyhydroxide-modified nickel oxyhydroxide has a coating of a cobalt oxyhydroxide on a nickel oxyhydroxide.
19 . The battery of claim 18 , wherein the coating is substantially uniform.
20 . The battery of claim 18 , wherein the cobalt oxyhydroxide is a sodium or potassium modified cobalt oxyhydroxide.
21 . The battery of claim 18 , wherein the cobalt oxyhydroxide is a potassium modified cobalt oxyhydroxide.
22 . The battery of claim 17 , wherein the cobalt oxyhydroxide-modified nickel oxyhydroxide is derived from nickel hydroxide coated with between 2% and 15% cobalt hydroxide by weight.
23 . The battery of claim 16 , wherein the anode comprises zinc.
24 . The battery of claim 16 , wherein the cathode further includes an oxidizing additive.
25 . The battery of claim 24 , wherein the oxidizing additive includes K 2 S 2 O 8 or KMnO 4 .
26 . A method of manufacturing a primary alkaline battery comprising:
forming a cobalt oxyhydroxide-modified nickel oxyhydroxide; and assembling a cathode comprising the cobalt oxyhydroxide-modified nickel oxyhydroxide, an anode, a separator, and an alkaline electrolyte to form the alkaline battery.
27 . The method of claim 26 , wherein forming a cobalt oxyhydroxide-modified nickel oxyhydroxide includes converting α-Ni(OH) 2 to nickel oxyhydroxide.
28 . The method of claim 26 , wherein forming cobalt oxyhydroxide-modified nickel oxyhydroxide includes converting nickel hydroxide coated with between 3% and 15% cobalt hydroxide by weight.
29 . The method of claim 26 , wherein the nickel oxyhydroxide is substantially non-fractured.
30 . The battery of claim 26 , wherein the cathode further includes an oxidizing additive.
31 . The battery of claim 30 , wherein the oxidizing additive includes K 2 S 2 O 8 or KMnO 4 .
32 . A method of manufacturing a primary alkaline battery comprising:
forming substantially non-fractured nickel oxyhydroxide; and assembling a cathode comprising the nickel oxyhydroxide, an anode, a separator, and an alkaline electrolyte to form the alkaline battery.
33 . The method of claim 32 , wherein forming nickel oxyhydroxide includes converting α-Ni(OH) 2 to nickel oxyhydroxide.
34 . The method of claim 32 , wherein the nickel oxyhydroxide is modified with cobalt oxyhydroxide.
35 . The method of claim 32 , wherein the cathode further includes K 2 S 2 O 8 or KMnO 4 .
36 . A method of decreasing capacity loss in a nickel oxyhydroxide primary alkaline battery comprising:
forming a cathode including a nickel oxyhydroxide; and assembling the cathode, an anode, a separator, and an alkaline electrolyte to form the alkaline battery, wherein the battery has a capacity loss after storage for 2 weeks at 60° C. of less than 40 percent.
37 . The method of claim 36 , further comprising converting α-Ni(OH) 2 to the nickel oxyhydroxide.
38 . The method of claim 36 , further comprising converting cobalt hydroxide-coated α-Ni(OH) 2 to the nickel oxyhydroxide.
39 . The method of claim 36 , further comprising converting cobalt hydroxide modified nickel hydroxide to the nickel oxyhydroxide.
40 . A cathode for a battery comprising non-fractured nickel oxyhydroxide or a cobalt oxyhydroxide-modified nickel oxyhydroxide.Join the waitlist — get patent alerts
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