Decontamination method and system, such as an in situ groundwater decontamination system, producing dissolved oxygen and reactive initiators

Abstract

An apparatus for decontamination contaminated groundwater in-situ by increasing the quantity of dissolved oxygen in the contaminated groundwater and generating reactive initiators to remediate the contaminated groundwater. The apparatus includes a submersible pump, an electrolytic cell, and a distribution chamber attached to an outlet of the cell. The distribution chamber is vertically oriented and longitudinally-extending from the outlet of the cell. As the groundwater flows across charging plates of the cell, some of the molecules break into their component parts of hydrogen gas and oxygen gas. A selected vertical length of the chamber provides a resident time for the fluid allowing a majority of the gaseous oxygen to transition to dissolved oxygen.

1 . An apparatus for in-situ decontamination of a contaminated groundwater, comprising: 
 a pump having an intake for drawing the contaminated groundwater into the pump;    an electrolytic cell enclosed in a housing, the housing having an inlet and an outlet, the inlet of the housing coupled to the pump to receive groundwater from the pump; and    a gas distribution chamber coupled to the outlet of the housing of the electrolytic cell, the gas distribution chamber including at least one opening at an end distal to the electrolytic cell.    
     
     
         2 . The apparatus of  claim 1  wherein the gas distribution chamber is vertically oriented and longitudinally extends a selected vertical distance above the outlet of the housing.  
     
     
         3 . A system for decontaminating contaminated groundwater in-situ, comprising: 
 a well having a bottom elevation below a water level of the contaminated groundwater;    a pump having an intake, the intake positioned in the well below the water level of the contaminated groundwater;    an electrolytic cell enclosed in a housing, the housing positioned above and coupled to the pump, wherein the pump draws contaminated groundwater into the intake and circulates the contaminated groundwater through the electrolytic cell; and    a gas distribution chamber positioned above the electrolytic cell, the gas distribution chamber coupled to the housing, the distribution chamber having an outlet for exiting circulated groundwater.    
     
     
         4 . The system of  claim 3  wherein the electrolytic cell includes electrolytic plates comprising anodes and cathodes coated in a plated material, wherein the plating material on the electrolytic plates is selected from the group consisting of noble and transition metals.  
     
     
         5 . The system of  claim 3  wherein the electrolytic cell includes electrolytic plates comprising anodes and cathodes, wherein the anodes are coated with tin and the cathodes are coated with platinum.  
     
     
         6 . The system of  claim 3 , further comprising replaceable absorbant filtration materials positioned in a head space of the well, wherein the filtration materials reduce an escape of off gases.  
     
     
         7 . The system of  claim 3 , further comprising support cables attached to the gas distribution chamber for lowering the system into place.  
     
     
         8 . The system of  claim 3 , further comprising a power supply wherein the power supply is a reversible polarity constant current DC power system.  
     
     
         9 . An apparatus for in-situ decontamination of a contaminated fluid, comprising: 
 a pump having an intake for drawing the contaminated fluid into the pump;    a cell having an inlet and an outlet, the inlet coupled to the pump to receive fluid from the pump; and    a chamber coupled to the outlet of the cell, the chamber including at least one opening at an end distal to the cell.    
     
     
         10 . A method of facilitating accelerated in-situ bioremediation of a body of water, comprising: 
 positioning an in-situ oxygen generating device having an electrolytic cell in the body of water;    pumping in-situ fluid from the body of water into the electrolytic cell of the oxygen generating device;    passing an electric current through the electrolytic cell to create a process liquid in which hydrogen gas and oxygen gas are generated;    moving the process liquid through the gas distribution chamber over a sufficient distance to allow the oxygen gas to dissolve into dissolved oxygen; and    returning the process liquid to the body of water.    
     
     
         11 . The method of  claim 10 , further comprising reversing the polarity of the electric current flowing through the electrolytic cell to clean the cell.  
     
     
         12 . The method of  claim 10  wherein the body of water is an underground aquifer and the method further comprises drilling a borehole to form a well into the aquifer wherein a bottom of the borehole extends below a water table.  
     
     
         13 . The method of  claim 11 , further comprising inserting a casing into the well wherein a selected lower portion of the casing is perforated to allow liquid to flow through the casing.