US2003096797A1PendingUtilityA1

Novel pharmaceutical formulations comprising aminoalkyl phosphorothioates

Assignee: MEDIMMUNE ONCOLOGYPriority: Jun 15, 1999Filed: Sep 26, 2002Published: May 22, 2003
Est. expiryJun 15, 2019(expired)· nominal 20-yr term from priority
A61K 31/66
55
PatentIndex Score
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Claims

Abstract

The present invention provides novel pharmaceutical compositions comprising aminoalkyl phosphorothioate compounds in combination with surfactants, hydrotropes and chelating agents. The compositions are well-suited for subcutaneous administration.

Claims

exact text as granted — not AI-modified
What is claimed is:  
     
         1 . A pharmaceutical composition comprising an amount of an aminoalkyl phosphorothioate and a surfactant which enhances the biological activity of the composition.  
     
     
         2 . The pharmaceutical composition of  claim 1 , wherein the amount of aminoalkyl phosphorothioate is from about 10 mg to about 3000 mg.  
     
     
         3 . The pharmaceutical composition of  claim 1 , wherein the amount of surfactant is added in the form of an aqueous dispersion, said dispersion having a concentration of from about 0.1 mg/ml to about 20 mg/ml.  
     
     
         4 . The pharmaceutical composition of  claim 1 , wherein the biological activity is cytoprotection, radio- or chemo-protection.  
     
     
         5 . The pharmaceutical composition of  claim 1 , wherein the aminoalkyl phosphorothioate is amifostine or S-3-(3-methylaminopropylamino)-3-propyl dihydrogen phosphorothioate.  
     
     
         6 . The pharmaceutical composition of  claim 4 , wherein the aminoalkyl phosphorothioate is amifostine.  
     
     
         7 . The pharmaceutical composition of  claim 1 , wherein the surfactant is selected from the group consisting of cholic acid, a salt of cholic acid, deoxycholic acid, a salt of deoxycholic acid, taurocholic acid, polyvinylpyrrolidone, a salt of taurocholic acid, TWEEN 80 and sodium dodecylsulfate.  
     
     
         8 . The pharmaceutical composition of  claim 5 , wherein the surfactant is sodium deoxycholate.  
     
     
         9 . The pharmaceutical composition of  claim 1 , wherein said composition is freeze-dried or lyophilized.  
     
     
         10 . The pharmaceutical composition of  claim 1 , wherein said composition is a liquid.  
     
     
         11 . A pharmaceutical composition which comprises a therapeutically effective amount of amifostine and sodium deoxycholate.  
     
     
         12 . A pharmaceutical composition comprising an amount of an aminoalkyl phosphorothioate and a hydrotrope.  
     
     
         13 . The pharmaceutical composition of  claim 1 , further comprising a hydrotrope.  
     
     
         14 . The pharmaceutical composition of  claim 13 , wherein the hydrotrope is added in the form of an aqueous solution, having a concentration of from about 0.5 mg/ml to about 100 mg/ml.  
     
     
         15 . The pharmaceutical composition of  claim 13 , wherein the hydrotrope is selected from the group consisting of sorbitol, mannitol, nicotinic acid, nicotinamide, 2,5-dihydroxybenzoic acid, ascorbic acid, ascorbyl dipalmitate, fructose, glucose, glucose glutamate, glucuronic acid, glycerin, 1,2,6-hexanetriol, hydroxystearyl methylglucamine, inositol, lactose, maltitol, sorbeth-20, sucrose, thioglycerin, tris(hydroxymethyl)nitromethane, tromethamine and xylitol.  
     
     
         16 . The pharmaceutical composition of  claim 13 , wherein the hydrotrope is a polyhydroxylated alcohol.  
     
     
         17 . The pharmaceutical composition of  claim 16 , wherein the polyhydroxylated alcohol is sorbitol.  
     
     
         18 . The pharmaceutical composition of  claim 13 , wherein said composition is freeze-dried or lyophilized.  
     
     
         19 . The pharmaceutical composition of  claim 13 , wherein said composition is a liquid.  
     
     
         20 . A pharmaceutical composition comprising an amount of an aminoalkyl phosphorothioate, a hydrotrope and a chelating agent.  
     
     
         21 . The pharmaceutical composition of  claim 20 , wherein the chelating agent is added in the form of an aqueous dispersion, said dispersion having a concentration of from about 0.5 mg/ml to about 100 mg/ml.  
     
     
         22 . The pharmaceutical composition of  claim 20 , wherein the aminoalkyl phosphorothioate is amifostine or S-3-(3-methylaminopropylamino)-3-propyl dihydrogen phosphorothioate..  
     
     
         23 . The pharmaceutical composition of  claim 20 , wherein the hydrotrope is selected from the group consisting of sorbitol, mannitol, nicotinic acid, nicotinamide, 2,5-dihydroxybenzoic acid, ascorbic acid, ascorbyl dipalmitate, fructose, glucose, glucose glutamate, glucuronic acid, glycerin, 1,2,6-hexanetriol, hydroxystearyl methylglucamine, inositol, lactose, maltitol, sorbeth-20, sucrose, thioglycerin, tris(hydroxymethyl)nitromethane, tromethamine and xylitol.  
     
     
         24 . The pharmaceutical composition of  claim 20 , wherein the hydrotrope is sorbitol.  
     
     
         25 . The pharmaceutical composition of  claim 20 , wherein the chelating agent is EDTA or DTPA.  
     
     
         26 . The pharmaceutical composition of  claim 20 , wherein the chelating agent is EDTA.  
     
     
         27 . The pharmaceutical composition of  claim 20 , wherein said composition is freeze-dried or lyophilized.  
     
     
         28 . The pharmaceutical composition of  claim 20 , wherein said composition is a liquid.  
     
     
         29 . A pharmaceutical composition which comprises a therapeutically effective amount of amifostine, an amount of sorbitol and an amount of EDTA.  
     
     
         30 . The pharmaceutical composition of claims  1  or  13 , further comprising a chelating agent.  
     
     
         31 . The pharmaceutical composition of  claim 30 , wherein the chelating agent is EDTA.  
     
     
         32 . The pharmaceutical composition of  claim 30 , wherein said composition is freeze-dried or lyophilized.  
     
     
         33 . The pharmaceutical composition of  claim 30 , wherein said composition is a liquid.  
     
     
         34 . A pharmaceutical composition comprising an amount of an aminoalkyl phosphorothioate and a chelating agent, wherein said pharmaceutical composition is adapted for use via subcutaneous administration.  
     
     
         35 . The pharmaceutical composition of  claim 34 , wherein the aminoalkyl phosphorothioate is amifostine or S-3-(3-methylaminopropylamino)-3-propyl dihydrogen phosphorothioate.  
     
     
         36 . The pharmaceutical composition of  claim 20 , wherein the chelating agent is EDTA.  
     
     
         37 . A pharmaceutical composition which comprises a therapeutically effective amount of amifostine, an amount of sodium deoxycholate, an amount of sorbitol and an amount of EDTA.  
     
     
         38 . The pharmaceutical composition of  claim 1 ,  11 ,  12 ,  13 ,  20  or  34  wherein the composition has a pH of between about 6 and about 8.  
     
     
         39 . The pharmaceutical composition of  claim 1 , wherein said pharmaceutical composition is adapted for use via subcutaneous administration.  
     
     
         40 . A pharmaceutical composition adapted for use via subcutaneous administration, comprising amifostine and a compound selected from the group consisting of 0.075% Sodium Deoxycholate, 2% Sorbitol, 2% Edetate Disodium, 0.2% Edetate Disodium, 1% Tween 80, 1% Choline Chloride, 0.02% Sodium Dodecyl Sulfate, WR-1065 and mixtures thereof, and wherein the composition has a pH of between about 6 and about 8.  
     
     
         41 . The pharmaceutical composition of  claim 1 , wherein said pharmaceutical composition is adapted for use via intravenous administration.  
     
     
         42 . The pharmaceutical composition of  claim 1 , wherein said pharmaceutical composition is adapted for use via oral administration.  
     
     
         43 . A unit dosage form which comprises a pharmaceutical composition of  claim 1 ,  11 ,  12 ,  13 ,  20 , or  34 .  
     
     
         44 . A method of treating a patient having cancer from the toxicities associated with radio- or chemotherapy, using the pharmaceutical composition of  claim 1 ,  11 ,  12 ,  13 ,  20  or  34 .  
     
     
         45 . A method of protecting a patient having cancer from the toxicities associated with radio- or chemotherapy, using the pharmaceutical composition of  claim 1 ,  11 ,  12 ,  13 ,  20  or  34 .  
     
     
         46 . A method of treating a patient having MDS, using the pharmaceutical composition of  claim 1 ,  11 ,  12 ,  13 ,  20  or  34 .  
     
     
         47 . A method of protecting a patient having MDS, using the pharmaceutical composition of  claim 1 ,  11 ,  12 ,  13 ,  20  or  34 .

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