Lipid vesicle-based fuel additives and liquid energy sources containing same

Abstract

Liquid energy sources, e.g., liquid fuels comprising lipid vesicles having fuel additives such as water are disclosed herein. The liquid energy sources, methods for preparation, and methods of enhancing engine performance disclosed herein employing the lipid vesicles result in enhanced fuel efficiency and/or lowered engine emissions. The invention further relates to liquid energy sources containing such additives which further comprise a polymeric dispersion assistant, which reduces the interfacial tension and coalescence of vesicles during dispersion process and storage, and thereby provide transparent looks to the liquid energy source.

What is claimed is:  
     
         1 . A liquid energy source comprising a liquid fuel and lipid vesicles comprising at least one lipid bilayer formed from at least one wall former material, said lipid vesicles further comprising at least one cavity containing a fuel additive.  
     
     
         2 . The liquid energy source of  claim 1 , wherein said liquid energy source further comprises a polymeric dispersion assistant.  
     
     
         3 . The liquid energy source of  claim 2 , wherein said liquid energy source is transparent.  
     
     
         4 . The liquid energy source of  claim 1 , wherein said lipid vesicles are paucilamellar.  
     
     
         5 . The liquid energy source of  claim 4 , wherein said paucilamellar lipid vesicles have 2-10 lipid bilayers surrounding an amorphous central cavity.  
     
     
         6 . The liquid energy source of  claim 1 , wherein said lipid bilayer comprises a primary wall former material and a secondary wall former material.  
     
     
         7 . The liquid energy source of  claim 6 , wherein said primary wall former material is a non-ionic amphiphile.  
     
     
         8 . The liquid energy source of  claim 6  wherein said primary wall former material is selected from the group consisting of C 12 -C 18  fatty alcohols, polyoxyethylene acyl alcohols, polyglycerols, sorbitan fatty acid esters, ethoxylated sorbitan fatty acid esters, C 12 -C 18  glycol monoesters, C 12 -C 18  glyceryl mono- and diesters, propylene glycol stearate, sucrose distearate, glyceryl dilaurate, glucosides, and their salts, and mixtures thereof.  
     
     
         9 . The liquid energy source of  claim 6  wherein said lipid vesicles further comprise a sterol, selected from the group consisting of cholesterol, cholesterol derivatives, ethoxylated cholesterol, hydrocortisone, phytosterol, and mixtures thereof.  
     
     
         10 . The liquid energy source of  claim 1 , wherein said at least one of said lipid bilayers further comprises a charge producing agent selected from the group consisting of dimethylstearyl amine, dicetyl phosphate, cetyl sulfate, phosphatidic acid, phosphatidyl serine, oleic acid, palmitic acid, stearylamines, oleylamines, and mixtures thereof.  
     
     
         11 . The liquid energy source of  claim 1  wherein said lipid vesicles are present in said liquid fuel in an amount sufficient to provide a concentration of said fuel additive in the range of from 0.01% to 10%.  
     
     
         12 . The liquid energy source of  claim 1  wherein said fuel additive is selected from the group consisting of water, ethanol, hydrazine, hydrogen peroxide, soya methyl ester and methyl isobutane ketone, and mixtures thereof.  
     
     
         13 . The liquid energy source of  claim 12  wherein said fuel additive is water.  
     
     
         14 . The liquid energy source of  claim 13  wherein said lipid vesicles are present in said liquid fuel in an amount sufficient to provide a concentration of water in said liquid fuel of about 5% or less.  
     
     
         15 . The liquid energy source of  claim 8  wherein said secondary wall former material is selected from the group consisting of quaternary dimethyldiacylamines, polyoxyethylene acyl alcohols, sorbitan fatty acid esters and ethoxylated sorbitan fatty acid esters and mixtures thereof.  
     
     
         16 . The liquid energy source of  claim 1 , wherein said liquid fuel is suitable for use in an internal combustion engine.  
     
     
         17 . The liquid energy source of  claim 1 , wherein said liquid fuel is selected from the group consisting of gasoline, diesel fuels, alternative fuels, bio-diesel, engineered fuels, kerosene, jet aviation fuels and mixtures thereof.  
     
     
         18 . The liquid energy source of  claim 2 , wherein said polymeric dispersion assistant is selected from the group comprised of polyoxyethylene/polyoxypropylene block polymers, PEG diesters of polyhydroxy fatty acids and PEG diesters of fatty acids.  
     
     
         19 . The liquid energy source of  claim 18 , wherein said polymeric dispersion assistant has the formula:  
       
         
           
           
               
               
           
         
       
       wherein the values of x, y, and z are each independently integers between about 1 and 100.  
     
     
         20 . The liquid energy source of  claim 19 , wherein the average value of x and the average value of z are each independently between about 2 and about 21 and the average value of y is between about 16 and about 67.  
     
     
         21 . The liquid energy source of  claim 20 , wherein the average value of x and the average value of z are each independently about 3, and the average value of y is about 30.  
     
     
         22 . The liquid energy source of  claim 20 , wherein the average value of x and the average value of z are each independently about 6, and the average value of y is about 39.  
     
     
         23 . The liquid energy source of  claim 20 , wherein the average value of x and the average value of z are each independently about 7, and the average value of y is about 54.  
     
     
         24 . The liquid energy source of  claim 18 , wherein said polymer has the formula:  
       
         
           
           
               
               
           
         
         wherein each RCO group is independently derived from a polyhydroxy fatty acid; and  
         the value of n is from about 15 to 40.  
       
     
     
         25 . The liquid energy source of  claim 18 , wherein said polymeric dispersion assistant is represented by the following formula:  
       
         
           
           
               
               
           
         
         wherein each RCO is independently derived from fatty acids; and  
         the value of n is from about 15 to 40.  
       
     
     
         26 . The liquid energy source of  claim 25 , wherein said fatty acids are selected from the group consisting of stearic, palmitic, oleic, and lauric acid.  
     
     
         27 . A method of improving the efficiency of an internal combustion engine, comprising fueling said internal combustion engine with a liquid energy source comprising a liquid fuel and lipid vesicles comprising at least one lipid bilayer formed from at least one wall former material, said lipid vesicles further comprising at least one cavity containing a fuel additive.  
     
     
         28 . The method of  claim 27 , wherein said liquid energy source further comprises a polymeric dispersion assistant.  
     
     
         29 . The method of  claim 27 , wherein said lipid vesicles are paucilamellar lipid vesicles have 2-10 lipid bilayers surrounding an amorphous central cavity.  
     
     
         30 . The method of  claim 27 , wherein said lipid bilayer comprises a primary wall former material and a secondary wall former material.  
     
     
         31 . The method of  claim 30 , wherein said primary wall former material is a non-ionic amphiphile.  
     
     
         32 . The method of  claim 30  wherein said primary wall former material is selected from the group consisting of C 12 -C 18  fatty alcohols, polyoxyethylene acyl alcohols, polyglycerols, sorbitan fatty acid esters, ethoxylated sorbitan fatty acid esters, C 12 -C 18  glycol monoesters, C 12 -C 18  glyceryl mono- and diesters, propylene glycol stearate, sucrose distearate, glyceryl dilaurate, and glucosides, and mixtures thereof.  
     
     
         33 . The method of  claim 30  wherein said lipid vesicles further comprise a sterol, selected from the group consisting of cholesterol, cholesterol derivatives, ethoxylated cholesterol, hydrocortisone, phytosterol, and mixtures thereof.  
     
     
         34 . The liquid energy source of  claim 27 , wherein said at least one lipid bilayer further comprises a charge producing agent selected from the group consisting of dimethylstearyl amine, dicetyl phosphate, cetyl sulfate, phosphatidic acid, phosphatidyl serine, oleic acid, palmitic acid, stearylamines, oleylamines, and mixtures thereof.  
     
     
         35 . The method of  claim 27  wherein said lipid vesicles are present in said liquid fuel in an amount sufficient to provide a concentration of said fuel additive in the range of from 0.01% to 10%.  
     
     
         36 . The method of  claim 27  wherein said fuel additive is selected from the group consisting. of water, ethanol, hydrazine, hydrogen peroxide, soya methyl ester and methyl isobutane ketone, and mixtures thereof.  
     
     
         37 . The method of  claim 36  wherein said fuel additive is water.  
     
     
         38 . The method of  claim 37  wherein said lipid vesicles are present in said liquid fuel in an amount sufficient to provide a concentration of water in said liquid fuel of about 5% or less.  
     
     
         39 . The method of  claim 27 , wherein said liquid fuel is selected from the group consisting of gasoline, diesel fuels, alternative fuels, bio-diesel, engineered fuels, kerosene, jet aviation fuels and mixtures thereof.  
     
     
         40 . The method of  claim 28 , wherein said polymeric dispersion assistant is selected from the group comprised of polyoxyethylene/polyoxypropylene block polymers, PEG diesters of polyhydroxy fatty acids and PEG diesters of fatty acids.  
     
     
         41 . The method of  claim 40 , wherein said polymeric dispersion assistant has the formula:  
       
         
           
           
               
               
           
         
       
       wherein the values of x, y, and z are each independently integers between about 1 and 100.  
     
     
         42 . The method of  claim 41 , wherein the average value of x and the average value of z are each independently between about 2 and about 21 and the average value of y is between about 16 and about 67.  
     
     
         43 . The method of  claim 42 , wherein the average value of x and the average value of z are each independently about 3, and the average value of y is about 30.  
     
     
         44 . The method of  claim 43 , wherein the average value of x and the average value of z are each independently about 6, and the average value of y is about 39.  
     
     
         45 . The method of  claim 42 , wherein the average value of x and the average value of z are each independently about 7, and the average value of y is about 54.  
     
     
         46 . The method of  claim 40 , wherein said polymer has the formula:  
       
         
           
           
               
               
           
         
         wherein each RCO group is independently derived from a polyhydroxy fatty acid; and  
         the value of n is from about 15 to 40.  
       
     
     
         47 . The method of  claim 40 , wherein said polymeric dispersion assistant is represented by the following formula:  
       
         
           
           
               
               
           
         
         wherein each RCO is independently derived from fatty acids; and  
         the value of n is from about 15 to 40.  
       
     
     
         48 . The method of  claim 47 , wherein said fatty acids are selected from the group consisting of stearic, palmitic, oleic, and lauric acid.