US2004136936A1PendingUtilityA1

Hair spray and consumer sprays with reduced volatile organic compounds

56
Priority: Sep 17, 1997Filed: Oct 15, 2003Published: Jul 15, 2004
Est. expirySep 17, 2017(expired)· nominal 20-yr term from priority
A61Q 5/06A61K 8/37A61K 8/34
56
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Claims

Abstract

A consumer article comprising a hand-held spray container, and a sprayable composition contained within the spray container comprising ethanol or isopropanol and methyl acetate or t-butyl acetate, a hair care composition comprising a fixative, ethanol, and methyl acetate or t-butyl acetate, and a method of fixing hair comprising spraying the compositions of this invention onto hair.

Claims

exact text as granted — not AI-modified
What is claimed is:  
     
         1 . A hair care composition comprising: 
 a. a fixative;    b. alkanol component comprising ethanol, isopropanol or mixtures thereof; and    c. methyl acetate.    
     
     
         2 . The hair care composition of  claim 1 , wherein the fixative is present in an amount in the range of from approximately 1 weight % to approximately 12 weight %.  
     
     
         3 . The hair care composition of  claim 1 , wherein the fixative is present in the range of from approximately 2 weight % to approximately 10 weight %.  
     
     
         4 . The hair care composition of  claim 1 , wherein the fixative is present in the range of from approximately 4 weight % to approximately 8 weight %.  
     
     
         5 . The hair care composition of  claim 1 , wherein the fixative is present in the range of from approximately 4 weight % to approximately 6 weight %.  
     
     
         6 . The hair care composition of  claim 1 , wherein the fixative is present in the range of from approximately 1 weight % to approximately 7 weight %.  
     
     
         7 . The hair care composition of  claim 1 , wherein the fixative is present in the range of from approximately 1 weight % to approximately 10 weight %.  
     
     
         8 . The hair care composition of  claim 1 , wherein the alkanol is present in the range of from approximately 20 weight % to approximately 50 weight %.  
     
     
         9 . The hair care composition of  claim 1 , wherein the alkanol is present in the range of from approximately 20 weight % to approximately 45 weight %.  
     
     
         10 . The hair care composition of  claim 1 , wherein the alkanol is present in the range of from approximately 20 weight % to approximately 40 weight %.  
     
     
         11 . The hair care composition of  claim 1 , wherein the alkanol is present in the range of from approximately 20 weight % to approximately 35 weight %.  
     
     
         12 . The hair care composition of  claim 1 , wherein the alkanol is present in the range of from approximately 20 weight % to approximately 30 weight %.  
     
     
         13 . The hair care composition of  claim 1 , wherein the alkanol is present in the range of from approximately 20 weight % to approximately 25 weight %.  
     
     
         14 . The hair care composition of  claim 1 , wherein the alkanol is present in the range of from approximately 25 weight % to approximately 50 weight %.  
     
     
         15 . The hair care composition of  claim 1 , wherein the alkanol is present in the range of from approximately 30 weight % to approximately 50 weight %.  
     
     
         16 . The hair care composition of  claim 1 , wherein the alkanol is present in the range of from approximately 35 weight % to approximately 50 weight %.  
     
     
         17 . The hair care composition of  claim 1 , wherein the alkanol is present in the range of from approximately 40 weight % to approximately 50 weight %.  
     
     
         18 . The hair care composition of  claim 1 , wherein the alkanol is present in the range of from approximately 45 weight % to approximately 50 weight %.  
     
     
         19 . The hair care composition of  claim 1 , wherein the methyl acetate is present in the range of from approximately 1 weight % to approximately 60 weight %.  
     
     
         20 . The hair care composition of  claim 1 , wherein the methyl acetate is present in the range of from approximately 3 weight % to approximately 60 weight %.  
     
     
         21 . The hair care composition of  claim 1 , wherein the methyl acetate is present in the range of from approximately 5 weight % to approximately 60 weight %.  
     
     
         22 . The hair care composition of  claim 1 , wherein the methyl acetate is present in the range of from approximately 10 weight % to approximately 60 weight %.  
     
     
         23 . The hair care composition of  claim 1 , wherein the methyl acetate is present in the range of from approximately 15 weight % to approximately 60 weight %.  
     
     
         24 . The hair care composition of  claim 1 , wherein the methyl acetate is present in the range of from approximately 20 weight percent to approximately 60 weight %.  
     
     
         25 . The hair care composition of  claim 1 , wherein the methyl acetate is present in the range of from approximately 25 weight % to approximately 60 weight %.  
     
     
         26 . The hair care composition of  claim 1 , wherein the methyl acetate is present in the range of from approximately 30 weight % to approximately 60 weight %.  
     
     
         27 . The hair care composition of  claim 1 , wherein the methyl acetate is present in the range of from approximately 1 weight % to approximately 55 weight %.  
     
     
         28 . The hair care composition of  claim 1 , wherein the methyl acetate is present in the range of from approximately 1 weight % to approximately 50 weight %.  
     
     
         29 . The hair care composition of  claim 1 , wherein the methyl acetate is present in the range of from approximately 1 weight % to approximately 45 weight %.  
     
     
         30 . The hair care composition of  claim 1 , wherein the methyl acetate is present in the range of from approximately 1 weight % to approximately 40 weight %.  
     
     
         31 . The hair care composition of  claim 1 , wherein the methyl acetate is present in the range of from approximately 1 weight % to approximately 35 weight %.  
     
     
         32 . The hair care composition of  claim 1 , wherein the methyl acetate is present in the range of from approximately 1 weight % to approximately 30 weight %.  
     
     
         33 . The hair care composition of  claim 1 , further comprising water.  
     
     
         34 . The hair care composition of  claim 33 , wherein the water is present in the range of from approximately 0.01 weight % to approximately 45 weight %.  
     
     
         35 . The hair care composition of  claim 33 , wherein the water is present in the range of from approximately 0.01 weight % to approximately 30 weight %.  
     
     
         36 . The hair care composition of  claim 1 , further comprising a propellant.  
     
     
         37 . The hair care composition of  claim 36 , wherein the propellant is present in the range of from approximately 15 weight % to approximately 45 weight %.  
     
     
         38 . The hair care composition of  claim 36 , wherein the propellant is present in the range of from approximately 20 weight % to approximately 45 weight %.  
     
     
         39 . The hair care composition of  claim 36 , wherein the propellant is present in the range of from approximately 25 weight % to approximately 45 weight %.  
     
     
         40 . The hair care composition of  claim 36 , wherein the propellant is present in the range of from approximately 30 weight % to approximately 45 weight %.  
     
     
         41 . The hair care composition of  claim 36 , wherein the propellant is present in the range of from approximately 35 weight % to approximately 45 weight %.  
     
     
         42 . The hair care composition of  claim 36 , wherein the propellant is present in the range of from approximately 40 weight % to approximately 45 weight %.  
     
     
         43 . The hair care composition of  claim 36 , wherein the propellant is present in the range of from approximately 15 weight % to approximately 40 weight %.  
     
     
         44 . The hair care composition of  claim 36 , wherein the propellant is present in the range of from approximately 15 weight % to approximately 35 weight %.  
     
     
         45 . The hair care composition of  claim 36 , wherein the propellant is present in the range of from approximately 15 weight % to approximately 30 weight %.  
     
     
         46 . The hair care composition of  claim 36 , wherein the propellant is present in the range of from approximately 15 weight % to approximately 25 weight %.  
     
     
         47 . The hair care composition of  claim 36 , wherein the propellant is present in the range of from approximately 15 weight % to approximately 20 weight %.  
     
     
         48 . The hair care composition of  claim 36 , wherein the propellant comprises dimethyl ether.  
     
     
         49 . The hair care composition of  claim 1 , comprising a volatile organic compound content less than approximately 55%.  
     
     
         50 . The hair care composition of  claim 1  comprising: 
 a. from about 1 to about 12 weight % fixative;  
 b. from about 20 to about 90 weight % ethanol; and  
 c. from about 1 to about 60 weight % methyl acetate.  
 
     
     
         51 . The hair care composition of  claim 1  comprising: 
 a. from about 4 to about 8 weight % fixative;  
 b. from about 30 to about 55 weight % ethanol; and  
 c. from about 10 to about 40 weight % methyl acetate.  
 
     
     
         52 . The hair care composition of  claim 1  wherein the fixative comprises: 
 a. a polymer or copolymer of acrylic acid and/or methacrylic acid or one of their polymerizable esters;  
 b. a polymer or copolymer of acrylamide, hydroxy acrylate, t-butylaminoethyl methacrylate, octyl acrylate, octylacrylamide, vinyl caprolactam, crotonic acid, dimethylaminopropylacrylamide, vinylpyrrolidone, vinyl acetate, vinyl propionate, vinyl caprolactam, and/or dimethicone;  
 c. an ethyl, propyl, or butyl ester of polyvinyl methyl ether and maleic anhydride copolymer;  
 d. a vinyl acetate/crotonates/vinyl neodecanoate copolymer;  
 e. an octylacrylamide/acrylates/butylaminoethyl methacrylate copolymer; or  
 f. a mixture thereof.  
 
     
     
         53 . The hair care composition of  claim 1  wherein the fixative is a vinyl acetate/crotonates/vinyl neodecanoate copolymer or octylacrylamide/acrylates/butylaminoethyl methacrylate copolymer.  
     
     
         54 . The hair care composition of  claim 1  further comprising water, wherein the fixative is a water dispersible sulfopolyester.  
     
     
         55 . The hair care composition of  claim 1  further comprising water, wherein the fixative is a diglycol/cyclohexane dimethanol/isophthalates/sodium sulfoisophthalate copolymer.  
     
     
         56 . The hair care composition of  claim 1  further comprising water and a propellant, wherein the propellant comprises dimethyl ether.  
     
     
         57 . The hair care composition of  claim 1  further comprising 
 a propellant, wherein the propellant comprises methane, ethane, propane, isobutane, n-butane, dimethyl ether, 1,1-difluoroethane, 1,1,1,2-tetrafluoroethane, or a mixture thereof.  
 
     
     
         58 . The hair care composition of  claim 1  further comprising 
 a propellant, wherein the propellant comprises propane and isobutane.  
 
     
     
         59 . The hair care composition of  claim 1  further comprising 
 a propellant, wherein the propellant comprises from about 5 to about 50 parts by weight propane, and from about 50 to about 95 parts by weight isobutane.  
 
     
     
         60 . The hair care composition of  claim 1  further comprising a propellant, wherein the propellant comprises 1,1-difluoroethane.  
     
     
         61 . The hair care composition of  claim 1  comprising: 
 a. from about 1 to about 10 weight % fixative;  
 b. from about 20 to about 75 weight % ethanol;  
 c. from about 1 to about 60 weight % methyl acetate; and  
 d. from about 15 to about 45 weight % propellant.  
 
     
     
         62 . The hair care composition of  claim 1  comprising: 
 a. from about 2 to about 8 weight % fixative;  
 b. from about 20 to about 55 weight % ethanol;  
 c. from about 10 to about 40 weight % methyl acetate; and  
 d. from about 20 to about 35 weight % propellant.  
 
     
     
         63 . The hair care composition of  claim 1  comprising: 
 a. from about 1 to about 12 weight % fixative;  
 b. from about 20 to about 90 weight % ethanol;  
 c. from about 1 to about 60 weight % methyl acetate; and  
 d. from about 0.01 to about 45 weight % water.  
 
     
     
         64 . The hair care composition of  claim 1  comprising: 
 a. from about 4 to about 8 weight % fixative;  
 b. from about 30 to about 55 weight % ethanol;  
 c. from about 10 to about 40 weight % methyl acetate; and  
 d. from about 0.01 to about 30 weight % water.  
 
     
     
         65 . The hair care composition of  claim 1  comprising: 
 a. from about 1 to about 10 weight % fixative;  
 b. from about 20 to about 75 weight % ethanol;  
 c. from about 1 to about 60 weight % methyl acetate;  
 d. from about 0.01 to about 45 weight % water; and  
 e. from about 15 to about 45 weight % propellant.  
 
     
     
         66 . The hair care composition of  claim 1  comprising: 
 a. from about 2 to about 8 weight % fixative;  
 b. from about 20 to about 55 weight % ethanol;  
 c. from about 10 to about 40 weight % methyl acetate;  
 d. from about 0.01 to about 30 weight % water; and  
 e. from about 20 to about 35 weight % propellant.  
 
     
     
         67 . The hair care composition of  claim 1  further comprising water, wherein the composition comprises from about 5 to about 10 weight % methyl acetate, and the molar ratio of water to ethanol does not exceed about 10.  
     
     
         68 . The hair care composition of  claim 1  further comprising water, wherein the composition comprises from about 11 to about 15 weight % methyl acetate, and the molar ratio of water to ethanol does not exceed about 6.  
     
     
         69 . The hair care composition of  claim 1  further comprising water, wherein the composition comprises from about 16 to about 20 weight % methyl acetate, and the molar ratio of water to ethanol does not exceed about 3.5.  
     
     
         70 . The hair care composition of  claim 1  further comprising water, wherein the composition comprises from about 21 to about 25 weight % methyl acetate, and the molar ratio of water to ethanol does not exceed about 2.5.  
     
     
         71 . The hair care composition of  claim 1  further comprising water, wherein the composition comprises from about 26 to about 30 weight % methyl acetate, and the molar ratio of water to ethanol does not exceed about 2.0.  
     
     
         72 . The hair care composition of  claim 1  further comprising water, wherein the composition comprises from about 31 to about 40 weight % methyl acetate, and the molar ratio of water to ethanol does not exceed about 1.6.  
     
     
         73 . The hair care composition of  claim 1  further comprising a neutralizer.  
     
     
         74 . The hair care composition of  claim 1  further comprising from about 0.1 to about 5 weight % of a neutralizer, wherein the neutralizer comprises aminomethyl propanediol; aminomethyl propanol; dimethylaminomethyl propanol; triisopropyl amine; dimethyl stearamine; dimethyl hydrogenated tallow amine; triethanolamine; tris(hydroxymethyl)aminomethane; sodium hydroxide; potassium hydroxide; ammonium hydroxide; or diethylpropylamine.  
     
     
         75 . The hair care composition of  claim 1  further comprising from about 0.1 to about 5 weight % of a neutralizer, wherein the neutralizer comprises 2-amino, 2-methyl, 1-propanol.  
     
     
         76 . The hair care composition of  claim 1  substantially free of any additional organic nonpropellant solvents.  
     
     
         77 . The hair care composition of  claim 1  selected from the group consisting of a spritz, a spray gel, a setting lotion, a glaze, and a mousse.  
     
     
         78 . The hair care composition of  claim 1 , wherein the composition is in the form of a hair spray.  
     
     
         79 . The hair care composition of  claim 1 , comprising: 
 a. from about 1 to about 7 weight % fixative;    b. from about 20 to about 90 weight % ethanol; and    c. from about 1 to about 40 weight % methyl acetate.    
     
     
         80 . A consumer article comprising: 
 a. a hand-held spray container; and    b. a sprayable composition contained within the spray container comprising the hair care composition of  claim 1 .    
     
     
         81 . The consumer article of  claim 82 , wherein the sprayable composition further comprises a perspiration deodorant, antiperspirant, or mixture thereof.  
     
     
         82 . The consumer article of  claim 82 , wherein the sprayable composition further comprises a room or surface deodorant, disinfectant, fragrance, or mixture thereof.  
     
     
         83 . A method of fixing hair comprising spraying the composition of  claim 1  onto hair.  
     
     
         84 . A hair care composition comprising: 
 a. a fixative;    b. alkanol component comprising ethanol, isopropanol or mixtures thereof; and    c. t-butyl acetate.

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