US2004221870A1PendingUtilityA1

Product and method to clean titanium surfaces

Priority: Oct 24, 2001Filed: Apr 22, 2004Published: Nov 11, 2004
Est. expiryOct 24, 2021(expired)· nominal 20-yr term from priority
C23G 1/02C23G 1/106C23G 1/205C23G 1/103C11D 3/222C11D 3/1266C11D 17/0043C11D 3/044C11D 17/003C11D 3/042C23G 1/00C11D 2111/16
36
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Claims

Abstract

A cleaning product that is useful for cleaning titanium surfaces such as titanium facades and panels includes, separately, (A) a descaling substance consisting of a mixture of nitric acid and hydrofluoric acid, a thickener, a surfactant, an indicator, water and, optionally, a propellant; and (B) a fixative composition that consists of a base, a thickener, a surfactant and a propellant.

Claims

exact text as granted — not AI-modified
1 . A cleaning product that is comprised, separately, of: 
 A) a descaling substance that consists of:    A.1) a mixture of nitric acid and hydrofluoric acid;    A.2) a thickener;    A.3) a surfactant;    A.4) an indicator;    A.5) water; and, optionally,    A.6) a propellant; and    B) a fixative that consists of:    B.1) a base;    B.2) a thickener;    B.3) a surfactant;    B.4) water; and    B.5) a propellant.    
     
     
         2 . A cleaning product according to  claim 1 , wherein the mixture of nitric acid and hydrofluoric acid is present in this descaling substance at a concentration ranging from 1% to 20% in weight relative to the total descaling compound.  
     
     
         3 . A cleaning product according to  claim 1 , wherein the weight ratio of nitric acid: hydrofluoric acid is 10:1.  
     
     
         4 . A cleaning product according to  claim 1 , wherein the thickener present in the descaling compound is of water-soluble organic pseudoplastic type.  
     
     
         5 . A cleaning product according to  claim 4 , wherein said water-soluble organic pseudoplastic thickener is selected from cellulotic type thickeners and natural gums.  
     
     
         6 . A cleaning product according to  claim 5 , wherein said thickener is xanthane gum.  
     
     
         7 . A cleaning product according to  claim 1 , wherein said descaling substance contains this thickener in a concentration ranging from 0.1% to 1% in weight relative to the total descaling composition.  
     
     
         8 . A cleaning product according to  claim 1 , wherein the surfactant present in the descaling substance is selected from anionic and cationic surfactants.  
     
     
         9 . A cleaning product according to  claim 8 , wherein the surfactant is sodium dodecyl sulphate.  
     
     
         10 . A cleaning product according to  claim 1 , wherein the descaling substance contains this surfactant in a concentration ranging from 0.1 to 1% in weight relative to the total descaling composition.  
     
     
         11 . A cleaning product according to  claim 1 , wherein the indicator is phenophthalein.  
     
     
         12 . A cleaning product according to  claim 1 , wherein the indicator is present in the descaling substance at a concentration lower than 0.1% in weight relative to the total descaling composition.  
     
     
         13 . A cleaning product according to  claim 1 , wherein the propellant present in this descaling composition is a liquated gas selected from among hydrocarbons and hydrofluorocarbons (HFC).  
     
     
         14 . A cleaning product according to  claim 13 , wherein the propellant is HFC 134a.  
     
     
         15 . A cleaning product according to  claim 1 , wherein the descaling composition contains a liquated gas as a propellant at a concentration ranging from 5% to 20% in weight relative to the total descaling composition.  
     
     
         16 . A cleaning product according to  claim 1 , wherein the propellant present in the descaling substance is a compressed gas.  
     
     
         17 . A cleaning product according to  claim 16 , wherein the compressed gas is nitrogen, carbon dioxide, nitrous oxide or air.  
     
     
         18 . A cleaning product according to  claim 1 , wherein the base, present in this fixative composition is either an alkaline metal hydroxide or trisodium phosphate.  
     
     
         19 . A cleaning product according to  claim 18 , wherein the base present in the fixative composition is sodium hydroxide.  
     
     
         20 . A cleaning product according to  claim 1 , wherein the base is present in this fixative at a concentration ranging from 1 to 20% relative to the total fixative composition.  
     
     
         21 . A cleaning product according to  claim 1 , wherein the thickening agent present in the fixative is an inorganic silicate-based thickener.  
     
     
         22 . A cleaning product according to  claim 21 , wherein the thickening agent is sepiolite.  
     
     
         23 . A cleaning product according to  claim 1 , wherein the fixative contains the thickening agent in a concentration ranging from 1% to 8% in weight relative to the total fixative composition.  
     
     
         24 . A cleaning product according to  claim 1 , wherein the surfactant present in the fixative composition is selected from anionic or cationic surfactants.  
     
     
         25 . A cleaning product according to  claim 24 , wherein the surfactant is sodium dodecylsulphate.  
     
     
         26 . A cleaning product according to  claim 1 , wherein the fixative contains this surfactant at a concentration ranging from 0.1% to 1% in weight relative to the total of fixative composition.  
     
     
         27 . A cleaning product according to  claim 1 , wherein the propellant present in the fixative is a liquated gas chosen from hydrocarbons or hydrofluorocarbons (HFC).  
     
     
         28 . A cleaning product according to  claim 27 , wherein the propellant is HFC 134a.  
     
     
         29 . A cleaning product according to  claim 1 , wherein the fixative contains a liquated gas as a propellant in a concentration ranging from 5% to 20% in weight of the total said fixative.  
     
     
         30 . A cleaning product according to  claim 1 , wherein the propellant present in this fixative is a compressed gas.  
     
     
         31 . A cleaning product according to  claim 30 , wherein the compressed gas is nitrogen, carbon dioxide, nitrous oxide or air.  
     
     
         32 . A cleaning product according to  claim 1 , further comprising, separately:  
       
         
           
                 
               
                     
                 
                     
                 
                   A) a descaling substance containing: 
                 
                 
                 
                 
               
                     
                   A mixture of: 
                     
                 
                     
                   Nitric acid (HNO 3 ) 
                    1-10% 
                 
                     
                   Hydrofluoric acid (HF) 
                   0.1-1% 
                 
                     
                   In which the weight ratio HNO 3 :HF is 10:1 
                 
                     
                   A thickener 
                   0.1-1% 
                 
                     
                   A surfactant 
                   0.1-1% 
                 
                     
                   An indicator 
                    <0.1% 
                 
                     
                   A propellant (liquated gas) 
                    5-20% 
                 
                     
                   Water (as required for) 
                      100% 
                 
                 
               
                   Where the percentages are percentages in weight relative 
                 
                   to the total descaling substance; and 
                 
                   B) a fixative containing: 
                 
                 
                 
                 
               
                     
                   A base 
                    5-15% 
                 
                     
                   A thickener 
                     2-8% 
                 
                     
                   A surfactant 
                   0.1-1% 
                 
                     
                   A propellant (liquated gas) 
                    5-20% 
                 
                     
                   Water (as required for) 
                      100% 
                 
                 
               
                   Where the percentages are percentages in weight relative 
                 
                   to the total fixative composition. 
                 
                     
                 
                     
                 
             
                
                
               
               
                
               
            
             
                
                
                
                
                
                
                
                
                
               
            
             
                
                
                
               
            
             
                
                
                
                
                
               
            
             
                
                
                
                
               
            
           
         
         Where the percentages are percentages in weight relative to the total fixative composition.  
       
     
     
         33 . A cleaning product according to  claim 32 , further comprising, separately:  
       
         
           
                 
               
                     
                 
                     
                 
                   A) A descaling substance containing: 
                 
                 
                 
                 
               
                     
                   A mixture of: 
                     
                 
                     
                   HNO 3  60% 
                    1-10% 
                 
                     
                   HF 48% 
                   0.1-1% 
                 
                     
                   With a weight ratio 
                 
                     
                   HNO 3 :HF of 10:1 
                 
                     
                   Xanthane gum 
                   0.1-1% 
                 
                     
                   Sodium dodecylsulphate 
                   0.1-1% 
                 
                     
                   Phenolphthalein 
                    <0.1% 
                 
                     
                   HFC 134a (liquated gas) 
                    5-20% 
                 
                     
                   Water (as required for) 
                      100% 
                 
                 
               
                   Where the percentages are percentages in weight relative 
                 
                   to the total descaling composition; and 
                 
                   B) a fixative containing: 
                 
                 
                 
                 
               
                     
                   NaOH 
                    5-15% 
                 
                     
                   sepiolite 
                     2-8% 
                 
                     
                   sodium dodecylsulphate 
                   0.1-1% 
                 
                     
                   HEC 134a (liquated gas) 
                    5-20% 
                 
                     
                   Water (as required for) 
                      100% 
                 
                 
               
                   Where the percentages are percentages in weight relative 
                 
                   to the total fixative composition. 
                 
                     
                 
                     
                 
             
                
                
               
               
                
               
            
             
                
                
                
                
                
                
                
                
                
                
               
            
             
                
                
                
               
            
             
                
                
                
                
                
               
            
             
                
                
                
                
               
            
           
         
         Where the percentages are percentages in weight relative to the total fixative composition.  
       
     
     
         34 . A cleaning product according to  claim 1 , wherein the descaling composition is presented as foam, spray gel or gel.  
     
     
         35 . A cleaning product according to  claim 1 , wherein the fixative is present as foam or spray gel.  
     
     
         36 . A method of cleaning titanium surfaces comprising the steps of: 
 a) provision of a cleaning product that is comprised, separately, of: 
 a descaling substance that consists of a mixture of nitric acid and hydrofluoric acid, a thickener, a surfactant, an indicator, water and, optionally, a propellant; and  
 a fixative that consists of a base, a thickener, a surfactant, water and a propellant  
   b) application of the descaling substance of the said cleaning product on the surface to be cleaned and leaving this to act for a given period of time;    c) application of the fixative of this cleaning product to the titanium surface previously treated with this descaling substance in stage b), and leaving this to act for a given period of time;    d) aspiration of the titanium surface previously treated with these descaling and fixative substances in stages b) and c); and    e) rinsing the treated titanium surface after carrying out stage d).    
     
     
         37 . A method according to  claim 36 , wherein the application of the descaling substance to the titanium surface to be cleaned is done by a spray gun or by a sponge trowel, and left to act for a period of time ranging from 15 seconds to 10 minutes before applying the fixative.  
     
     
         38 . A method according to  claim 36 , wherein the application of the fixative on the titanium surface to be cleaned, previously treated with the descaling substance is done using a spray gun, and is left to act for a period ranging from 15 seconds to 5 minutes before starting stage d) after confirming that the neutralization has taken place.  
     
     
         39 . A method according to  claim 36 , wherein rinsing of the treated titanium surface is done with water jets at a temperature ranging from 5° C. to 30° C.

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