Decorative material and decorative sheet

Abstract

An object of the present invention is to realize a configuration of decorative sheet, particularly a decorative paper and the like, or a decorative material in which it is adhered, that is: a grain depression is not visible; excellent in scratch resistance, also in contamination resistance; and three-dimensional design can be expressed, at low cost. For attaining the above-mentioned object, the present invention uses a delustering silica, whose surface is treated with a fatty acid based wax such as stearic acid, as a delustering silica in a decorative material 10 in which a luster adjusting resin layer 2, which is formed of a cross-linked cured material of an ionizing radiation curing resin composition containing a delustering silica, is provided on a base material 1. The luster adjusting resin layer may be formed with an even thickness. However, a convex-concave surface design can be expressed by forming the luster adjusting resin layer partially in a pattern. The luster adjusting resin layer is formed with an ionizing radiation curing resin composition, particularly with no solvent, by a gravure printing or gravure coating using a doctor blade and a gravure plate.

1 - 12 . (canceled)  
   
   
       13 . A decorative material, wherein a luster adjusting resin layer, which is formed of a cross-linked cured material of an ionizing radiation curing resin composition containing a delustering silica, is provided on a base material, and 
 the delustering silica is a silica whose surface is treated with a fatty acid based wax.    
   
   
       14 . A decorative material, wherein a luster adjusting resin layer, which is formed of a cross-linked cured material of an ionizing radiation curing resin composition containing a delustering silica, is provided on a base material, and 
 the luster adjusting resin layer further contains either one or both of a magnesium hydroxide and a magnesium carbonate, as a filler.    
   
   
       15 . The decorative material according to  claim 13 , wherein the luster adjusting resin layer is formed partially, in a pattern, to form a convex-concave surface design of the luster adjusting resin layer.  
   
   
       16 . The decorative material according to  claim 14 , wherein the luster adjusting resin layer is formed partially, in a pattern, to form a convex-concave surface design of the luster adjusting resin layer.  
   
   
       17 . A method for manufacturing, the decorative material according to  claim 13 , wherein the ionizing radiation curing resin composition is formed into the luster adjusting resin layer, with no solvent, by using a doctor blade and a gravure plate.  
   
   
       18 . A method for manufacturing, the decorative material according to  claim 14 , wherein the ionizing radiation curing resin composition is formed into the luster adjusting resin layer, with no solvent, by using a doctor blade and a gravure plate.  
   
   
       19 . A decorative sheet, wherein a convex pattern is formed on a base material sheet, 
 the convex pattern is formed of a cross-link curing resin ink, and a non-printed part is covered with the ink flown from a printed part by the ink to the non-printed part, so that the ink of the convex shape of the printed part is remained.    
   
   
       20 . The decorative sheet according to  claim 19 , wherein the cross-link curing resin comprises: a delustering silica for adjusting luster; and a fine particle silica whose average particle diameter is smaller than the delustering silica.  
   
   
       21 . The decorative sheet according to  claim 19 , wherein the cross-link. curing resin is an ionizing radiation curing resin.  
   
   
       22 . The decorative sheet according to  claim 21 , wherein the ionizing radiation curing resin contains an aluminum hydroxide.  
   
   
       23 . The decorative sheet according to  claim 21 , wherein the ionizing radiation curing resin contains the delustering silica for adjusting luster, and further, contains either of a magnesium hydroxide and a magnesium carbonate, as a filler.  
   
   
       24 . The decorative sheet according to  claim 21 , wherein the ionizing radiation curing resin contains the delustering silica for adjusting luster, and 
 the delustering silica is a silica whose surface is treated with a fatty acid based wax.    
   
   
       25 . A method for manufacturing the decorative sheet according to  claim 23 , wherein the convex pattern, which is formed of the ionizing radiation curing resin containing the delustering silica, is formed on the decorative sheet, and 
 the ionizing radiation curing resin ink is formed into the convex pattern, with no solvent, by using a doctor blade and a gravure plate.    
   
   
       26 . A decorative plate, wherein the decorative sheet according to  claim 19  is laminated on an adhered base material so that the base material sheet is faced to the adhered base material.