Photo mask, focus measuring method using the mask, and method of manufacturing semiconductor device

Abstract

A photo mask includes an asymmetrical diffraction grating pattern in which diffraction efficiencies of plus primary diffracted light and minus primary diffracted light are different, the asymmetrical diffraction grating pattern including a shielding portion which shields light, a first transmitting portion which transmits light, and a second transmitting portion which transmits light, a ratio of widths of the shielding portion, the first transmitting portion, and the second transmitting portion being n11 where n is a positive real number except 2, the asymmetrical diffraction grating pattern approximately satisfying 163°≦360°/(n+2)+θ≦197° where θ (≠90°) indicates an absolute value of a difference between a phase of the light transmitted through the first transmitting portion and that of the light transmitted through the second transmitting portion, and a reference pattern for obtaining an image as a reference for measuring a shift of an image of the asymmetrical diffraction grating pattern.

1 . A photo mask comprising: 
 an asymmetrical diffraction grating pattern in which diffraction efficiencies of plus primary diffracted light and minus primary diffracted light are different, the asymmetrical diffraction grating pattern including a shielding portion which shields light; a first transmitting portion which transmits light; and a second transmitting portion which transmits light, a ratio of widths of the shielding portion, the first transmitting portion, and the second transmitting portion being n:1:1 where n is a positive real number except 2, the asymmetrical diffraction grating pattern approximately satisfying 163°≦360°/(n+2)+θ≦197° where θ (≠90°) indicates an absolute value of a difference between a phase of the light transmitted through the first transmitting portion and that of the light transmitted through the second transmitting portion; and    a reference pattern configured to obtain an image as a reference for measuring a shift of an image of the asymmetrical diffraction grating pattern.    
   
   
       2 . The photo mask according to  claim 1 , wherein the reference pattern is an asymmetrical diffraction grating pattern symmetrical to the asymmetrical diffraction grating pattern.  
   
   
       3 . The photo mask according to  claim 1 , wherein the reference pattern includes first and second reference patterns, and the asymmetrical diffraction grating pattern is disposed between the first and second reference patterns.  
   
   
       4 . The photo mask according to  claim 1 , wherein the asymmetrical diffraction grating pattern includes first and second asymmetrical diffraction grating patterns, and the reference pattern is disposed between the first and second asymmetrical diffraction grating patterns.  
   
   
       5 . The photo mask according to  claim 1 , wherein the asymmetrical diffraction grating pattern includes first and second asymmetrical diffraction grating patterns, the reference pattern includes first and second reference patterns, the first asymmetrical diffraction grating pattern and the first reference pattern are arranged in parallel on a first line, and the second asymmetrical diffraction grating pattern and the second reference pattern are arranged in parallel on a second line vertical to the first line.  
   
   
       6 . The photo mask according to  claim 1 , wherein the asymmetrical diffraction grating pattern includes a plurality of asymmetrical diffraction grating patterns, the reference pattern includes a plurality of reference patterns, and the plurality of asymmetrical diffraction grating patterns and the plurality of reference patterns are arranged in parallel on a line, and alternately arranged.  
   
   
       7 . The photo mask according to  claim 1 , wherein the θ and the n approximately satisfy 360°/(n+2)+θ=180°.  
   
   
       8 . The photo mask according to  claim 1 , wherein the θ is approximately 36°, and the n is approximately 0.5.  
   
   
       9 . The photo mask according to  claim 1 , wherein the θ is approximately 60°, and the n is approximately 1.  
   
   
       10 . The photo mask according to  claim 1 , wherein the θ is approximately 108°, and the n is approximately 3.  
   
   
       11 . The photo mask according to  claim 1 , further comprising: a device pattern.  
   
   
       12 . The photo mask according to  claim 2 , further comprising: a device pattern.  
   
   
       13 . A focus measuring method comprising: 
 preparing a focus test mask, the focus test mask comprising: an asymmetrical diffraction grating pattern in which diffraction efficiencies of plus primary diffracted light and minus primary diffracted light are different, the asymmetrical diffraction grating pattern including a shielding portion which shields light, a first transmitting portion which transmits light, and a second transmitting portion which transmits light, a ratio of widths of the shielding portion, the first transmitting portion, and the second transmitting portion being n:1:1 where n is a positive real number except 2, the asymmetrical diffraction grating pattern approximately satisfying 163°≦360°/(n+2)+θ≦197° where θ (≠90°) indicates an absolute value of a difference between a phase of the light transmitted through the first transmitting portion and that of the light transmitted through the second transmitting portion; and a reference pattern configured to obtain an image as a reference for measuring a shift of an image of the asymmetrical diffraction grating pattern;    applying a photosensitive agent on the substrate;    exposing images of the asymmetrical diffraction grating pattern and the reference pattern in the photo mask at the same time onto the substrate;    developing a pattern transferred on the substrate; and    measuring a relative distance between the images of the asymmetrical diffraction grating pattern and the reference pattern formed on the substrate.    
   
   
       14 . The focus measuring method according to  claim 13 , wherein the reference pattern is an asymmetrical diffraction grating pattern symmetrical to the asymmetrical diffraction grating pattern.  
   
   
       15 . The focus measuring method according to  claim 13 , wherein the reference pattern includes first and second reference patterns, and the asymmetrical diffraction grating pattern is disposed between the first and second reference patterns.  
   
   
       16 . The focus measuring method according to  claim 13 , wherein the asymmetrical diffraction grating pattern includes first and second asymmetrical diffraction grating patterns, and the reference pattern is disposed between the first and second asymmetrical diffraction grating patterns.  
   
   
       17 . The focus measuring method according to  claim 13 , wherein the asymmetrical diffraction grating pattern includes first and second asymmetrical diffraction grating patterns, the reference pattern includes first and second reference patterns, the first asymmetrical diffraction grating pattern and the first reference pattern are arranged in parallel on a first line, and the second asymmetrical diffraction grating pattern and the second reference pattern are arranged in parallel on a second line vertical to the first line.  
   
   
       18 . The focus measuring method according to  claim 13 , wherein the asymmetrical diffraction grating pattern includes a plurality of asymmetrical diffraction grating patterns, the reference pattern includes a plurality of reference patterns, and the plurality of asymmetrical diffraction grating pattern and plurality of the reference pattern are arranged in parallel on a line, and alternately arranged.  
   
   
       19 . The focus measuring method according to  claim 13 , wherein the θ and the n approximately satisfy 360°/(n+2)+θ=180°.  
   
   
       20 . A method of manufacturing a semiconductor device comprising: 
 preparing an exposure mask, the exposure mask comprising an asymmetrical diffraction grating pattern in which diffraction efficiencies of plus primary diffracted light and minus primary diffracted light are different, the asymmetrical diffraction grating pattern including a shielding portion which shields light, a first transmitting portion which transmits light, and a second transmitting portion which transmits light, a ratio of widths of the shielding portion, the first transmitting portion, and the second transmitting portion being n:1:1 where n is a positive real number except 2, the asymmetrical diffraction grating pattern approximately satisfying 163°≦360°/(n+2)+θ≦197° where θ (≠90°) indicates an absolute value of a difference between a phase of the light transmitted through the first transmitting portion and that of the light transmitted through the second transmitting portion; a reference pattern configured to obtain an image which is a reference in measuring a shift of an image of the asymmetrical diffraction grating pattern; and a device pattern;    applying a photosensitive agent on the substrate;    exposing images of the asymmetrical diffraction grating pattern, the reference pattern, and the device pattern in the photo mask at the same time onto the substrate;    developing a pattern transferred on the substrate;    inspecting the device pattern formed on the substrate; and    measuring a relative distance between the images of the asymmetrical diffraction grating pattern and the reference pattern in a case where a defect is detected in the device pattern in the inspecting the device pattern formed on the substrate.