Breathable low-emissivity metalized sheets

Abstract

A moisture vapor permeable metalized composite sheet is formed by coating a moisture vapor permeable sheet-with at least one metal layer and at least one outer organic coating layer. The moisture vapor permeability of the composite sheet is at least about 80% of the moisture vapor permeability of the starting sheet. The composite sheet provides a barrier to air and liquid water infiltration while having high moisture vapor permeability and good thermal barrier properties. The composite sheet material is suitable for use as a building construction wrap such as roof lining and house wrap.

1 . A metalized composite sheet comprising: 
 a moisture vapor permeable sheet layer having first and second outer surfaces, the sheet layer comprising at least one of a nonwoven fabric, woven fabric, nonwoven fabric-film laminate, woven fabric-film laminate, moisture vapor permeable film and composites thereof, wherein the first outer surface of the moisture vapor permeable sheet layer is a porous sheet selected from the group consisting of microperforated films, woven fabrics and nonwoven fabrics; and at least one multi-layer coating on said first outer surface of the sheet layer, said multi-layer coating comprising:    a first metal coating layer having a thickness between about 15 nanometers and 200 nanometers adjacent the first outer surface of the sheet layer; and    an outer organic coating layer of a composition containing a material selected from the group consisting of organic polymers, organic oligomers and combinations thereof, having a thickness between about 0.2 micrometer and 2.5 micrometers deposited on the metal layer;    wherein the MVTR of the composite sheet is at least about 80% of the MVTR of the sheet layer measured prior to depositing the metal and coating layers.    
   
   
       2 . The metalized composite sheet of  claim 1 , said multi-layer coating further comprising: 
 an intermediate organic coating layer of a composition containing a material selected from the group consisting of organic polymers, organic oligomers and combinations thereof, having a thickness between about 0.02 micrometer and 2 micrometers deposited on the first outer surface of the moisture vapor permeable sheet layer, between the sheet layer and the metal coating layer;    wherein the total combined thickness of the intermediate and outer organic coating layers is no greater than about 2.5 micrometers.    
   
   
       3 . The metalized composite sheet of  claim 2 , wherein the outer organic coating layer has a thickness between about 0.2 micrometer and 1 micrometer and the intermediate organic coating layer has a thickness between about 0.02 micrometer and 1 micrometer and the total combined thickness of the organic coating layers is no greater than about 1.5 micrometers.  
   
   
       4 . The metalized composite sheet of any of claims  1 - 3 , further comprising a second multi-layer coating according to any of claims  1 - 3 , deposited on the second outer surface of the sheet layer, wherein the total combined thickness of the organic coating layers is no greater than about 2.5 micrometers.  
   
   
       5 . The metalized composite sheet of any of claims  1 - 3 , wherein the multi-layer coating substantially covers the outer surfaces of the porous sheet while leaving the pores substantially uncovered.  
   
   
       6 . The metalized composite sheet of any of claims  1 - 3 , which has a hydrostatic head of at least about 20 cm H 2 O and a MVTR of at least about 35 g/m 2 /124 hr.  
   
   
       7 . The metalized composite sheet of any of claims  1 - 3 , which has an emissivity of no greater than about 0.12.  
   
   
       8 . The metalized composite sheet of any of claims  1 - 3 , wherein the metal is selected from the group consisting of aluminum, silver, copper, gold, tin, zinc, and their alloys.  
   
   
       9 . The metalized composite sheet of  claim 8 , wherein the metal is aluminum.  
   
   
       10 . The metalized composite sheet of  claim 1 , wherein the moisture vapor permeable sheet layer comprises a nonwoven fabric.  
   
   
       11 . The metalized composite sheet of  claim 1 , wherein the moisture vapor permeable sheet is a nonwoven fabric selected from the group consisting of spunbond fabrics, spunbond-meltblown fabrics, spunbond-meltblown-spunbond fabrics, flash spun plexifilamentary sheets, and composites thereof.  
   
   
       12 . The metalized composite sheet of  claim 1 , wherein the first side of said moisture vapor permeable sheet layer is a perforated film.  
   
   
       13 . The metalized composite sheet of  claim 1 , wherein the moisture vapor permeable sheet layer comprises a woven fabric of woven tapes.  
   
   
       14 . The metalized composite sheet of  claim 1 , wherein the moisture vapor permeable sheet is selected from the group consisting of nonwoven fabric-film laminates and woven fabric-film laminates, and the film is selected from the group consisting of microporous films, perforated films and non-porous moisture vapor permeable films.  
   
   
       15 . The metalized composite sheet of  claim 1 , wherein the outer organic coating layer comprises a cross-linked polyacrylate.  
   
   
       16 . The metalized composite sheet of  claim 2  or  3 , wherein the intermediate and outer organic coating layers each comprise a cross-linked polyacrylate.  
   
   
       17 . The metalized composite sheet of any of claims  1 - 3 , wherein the moisture vapor permeable sheet layer comprises a flash spun plexifilamentary sheet.  
   
   
       18 . The metalized composite sheet of  claim 17 , wherein the flash spun plexifilamentary sheet is laminated to a spunbonded nonwoven fabric and the multi-layer coating is deposited on the flash spun sheet.  
   
   
       19 . The metalized composite sheet of  claim 1 , wherein the outer organic coating layer comprises a fluorinated acrylate oligomer.  
   
   
       20 . A metalized composite sheet comprising: 
 a porous flash spun plexifilamentary sheet layer having first and second outer surfaces and at least one multi-layer coating comprising:    a metal coating layer having a thickness between about 15 nanometers and 200 nanometers deposited on the first outer surface of the flash spun plexifilamentary sheet layer, said metal selected from the group consisting of aluminum, silver, copper, gold, tin, zinc, and their alloys; and    an outer organic coating layer of a composition containing a cross-linked polyacrylate having a thickness between about 0.2 micrometer and 1 micrometer deposited on the metal layer;    wherein the multi-layer coating substantially covers the outer surface of the flash spun plexifilamentary sheet while leaving the pores substantially uncovered.    
   
   
       21 . A metalized composite sheet comprising: 
 a porous flash spun plexifilamentary sheet layer having first and second outer surfaces and at least one multi-layer coating comprising:    an intermediate organic coating layer of a composition containing a cross-linked polyacrylate having a thickness between about 0.02 micrometer and 1 micrometer deposited on the first outer surface of said flash spun plexifilamentary sheet layer;    a metal coating layer having a thickness between about 15 nanometers and 200 nanometers deposited on said intermediate organic coating layer, said metal selected from the group consisting of aluminum, silver, copper, gold, tin, zinc, and their alloys; and    an outer organic coating layer of a composition containing a cross-linked polyacrylate having a thickness between about 0.2 micrometer and 1 micrometer deposited on the metal layer;    wherein the multi-layer coating substantially covers the outer surface of the flash spun plexifilamentary sheet while leaving the pores substantially uncovered.    
   
   
       22 . The metalized composite sheet of  claim 21 , wherein the intermediate coating layer has a thickness between about 0.025 micrometer and 0.2 micrometer.  
   
   
       23 . A roof system in a building construction comprising the metalized composite sheet of any of claims  1 ,  2 ,  3 ,  20  or  21 .  
   
   
       24 . A wall system in a building construction comprising the metalized composite sheet of any of claims  1 ,  2 ,  3 ,  20  or  21 .  
   
   
       25 . A method of reducing penetration of EMF radiation through a building comprising installing the metalized composite sheet of  claim 1  in the walls or roof of the building.