Treatment of crude oil fractions, fossil fuels, and products thereof with sonic energy

Abstract

In crude oil fractions, fossil fuels, and organic liquids in general in which it is desirable to reduce the levels of sulfur-containing and nitrogen-containing components, the process reduces the level of these compounds via the application of sonic energy. The process can be performed both with and without the added presence of an oxidizing agent, and with or without elevated temperature and/or pressure. The invention is performed either as a continuous process or a batch process.

1 - 49 . (canceled)  
     
     
         50 . A process for removing organic sulfur from a crude oil fraction, said process comprising: 
 (a) exposing crude oil to sonic energy in the absence of hydrogen peroxide or hydroperoxides, also in the absence of a metallic catalyst, and deriving a crude oil fraction; and    (b) contacting said crude oil fraction derived in step (a) with hydrogen gas under conditions causing conversion of said organic sulfur originally present in said crude oil to hydrogen sulfide by hydrodesulfurization.    
     
     
         51 . The process of  claim 50  wherein said crude oil fraction is a fraction boiling within the diesel range.  
     
     
         52 . The process of  claim 51  wherein said crude oil fraction is a member selected from the group consisting of fluid catalytic cracking (FCC) cycle oil fractions, coker distillate fractions, straight run diesel fractions, and blends thereof.  
     
     
         53 . The process of  claim 50  wherein said crude oil fraction is a fraction boiling within the gas oil range.  
     
     
         54 . The process of  claim 53  wherein said crude oil fraction is a member selected form the group consisting of FCC cycle oil, FCC slurry oil, light gas oil, heavy gas oil, and coker gas oil.  
     
     
         55 . The process of  claim 50  wherein in step (a) said crude oil is exposed to said sonic energy in the absence of an aqueous phase having a surface active agent.  
     
     
         56 . A process for removing organic sulfur from a crude oil fraction, said process comprising: 
 (a) exposing the crude oil fraction to sonic energy in the absence of an aqueous phase; and    (b) contacting said crude oil fraction exposed to sonic energy in step (a) with hydrogen gas under conditions causing conversion of said organic sulfur originally present in said crude oil fraction to hydrogen sulfide by hydrodesulfurization.    
     
     
         57 . The process of  claim 56  wherein said crude oil fraction is a fraction boiling within the diesel range.  
     
     
         58 . The process of  claim 57  wherein said crude oil fraction is a member selected from the group consisting of fluid catalytic cracking (FCC) cycle oil fractions, coker distillate fractions, straight run diesel fractions, and blends thereof.  
     
     
         59 . The process of  claim 56  wherein said crude oil fraction is a fraction boiling within the gas oil range.  
     
     
         60 . The process of  claim 59  wherein said crude oil fraction is a member selected form the group consisting of FCC cycle oil, FCC slurry oil, light gas oil, heavy gas oil, and coker gas oil.  
     
     
         61 . A process for removing organic sulfur from a crude oil fraction, said process comprising: 
 (a) exposing the crude oil fraction to sonic energy in the absence of a surface active agent; and    (b) contacting said crude oil fraction exposed to sonic energy in step (a) with hydrogen gas under conditions causing conversion of said organic sulfur originally present in said crude oil fraction to hydrogen sulfide by hydrodesulfurization.    
     
     
         62 . The process of  claim 61  wherein said crude oil fraction is a fraction boiling within the diesel range.  
     
     
         63 . The process of  claim 62  wherein said crude oil fraction is a member selected from the group consisting of fluid catalytic cracking (FCC) cycle oil fractions, coker distillate fractions, straight run diesel fractions, and blends thereof.  
     
     
         64 . The process of  claim 61  wherein said crude oil fraction is a fraction boiling within the gas oil range.  
     
     
         65 . The process of  claim 64  wherein said crude oil fraction is a member selected form the group consisting of FCC cycle oil, FCC slurry oil, light gas oil, heavy gas oil, and coker gas oil.