Antioxidant and bisaminophenol derivative

Abstract

The present invention provides antioxidants made of an aromatic hydroxyamine derivative having a structure represented by the general formula (I): wherein R 1 , R 2 and R 3 are each independently a hydrogen atom or an alkyl group having 1 to 20 carbon atoms; X is a hydrogen atom or an OH group; Y is a hydrogen atom or an NHR 1 group; A is a direct bond, —O—, —NH—, —SO 2 —, —CH 2 — or —C(CH 3 ) 2 —, and when an OH group and an NHR 1 group are introduced to a unilateral benzene ring, these groups are respectively bonded to adjacent positions of the benzene ring; and n is 0 or 1 with the proviso that when n is 0, R 1 is not a hydrogen atom, as well as bisaminophenol derivatives represented by the above general formula (I) wherein n is 1; R 2 and R 3 are each a hydrogen atom; X is an OH group; Y is an NHR 1 group; A is —C(CH 3 ) 2 —; and R 1 is isopropyl, isobutyl or isohexyl. The aromatic hydroxyamine derivatives having a structure represented by the general formula (I), in particular, the bisaminophenol derivatives as novel substances, exhibit an excellent oxidation-inhibiting property, and are usable as antioxidants or polymerization inhibitors.

1 . An antioxidant made of an aromatic hydroxyamine derivative having a structure represented by the general formula (I):  
       
         
           
           
               
               
           
         
       
       wherein R 1 , R 2  and R 3  are each independently a hydrogen atom or an alkyl group having 1 to 20 carbon atoms; X is a hydrogen atom or an OH group; Y is a hydrogen atom or an NHR 1  group; A is a direct bond, —O—, —NH—, —SO 2 —, —CH 2 — or —C(CH 3 ) 2 —, and when an OH group and an NHR 1  group are introduced to a unilateral benzene ring, these groups are respectively bonded to adjacent positions of the benzene ring; and n is 0 or 1 with the proviso that when n is 0, R 1  is not a hydrogen atom.  
     
     
         2 . The antioxidant according to  claim 1 , wherein the antioxidant is used for plastics, rubbers or petroleum products.  
     
     
         3 . A bisaminophenol derivative represented by the general formula (I):  
       
         
           
           
               
               
           
         
       
       wherein n is 1; R 2  and R 3  are each a hydrogen atom; X is an OH group; Y is an NHR 1  group; A is —C(CH 3 ) 2 —; and R 1  is isopropyl, isobutyl or isohexyl.