Method of producing a thermoplastically moldable fiber-reinforced semifinished product

Abstract

A continuous method for producing a thermoplastically moldable semifinished product of a thermoplastic material and reinforcing fibers, comprises blending thermoplastic fibers and reinforcing fibers together to form a nonwoven blend, consolidating the nonwoven blend by needling or by a thermal treatment, heating the consolidated nonwoven blend to a temperature above the softening temperature of the thermoplastic, compressing the consolidated nonwoven blend successively in a heated compression mold and in a cooled compression mold at a pressure of less than 0.8 bar for at least 3 seconds, and optionally applying functional layers to the semifinished product. The preferred product is a thermoplastically moldable semifinished product of a thermoplastic material and reinforcing fibers with an average length of 20 to 60 mm and an air pore content of 35 to 65 vol %.

1 . A continuous process for the preparation of a porous thermoformable semifinished product having a porosity of from 25 volume percent to 75 volume percent from thermoplastic fibers and reinforcing fibers, comprising the steps of: 
 a) blending from 10 to 80 weight percent of thermoplastic fibers with 90 to 20 weight percent of reinforcing fibers, said reinforcing fibers supplied as individual fibers or as multi-fiber strands which are opened into individual fibers during blending, to form a lofty, continuous non-woven mat;    b) consolidating the lofty non-woven mat of step a) by needling, or by thermal treatment which melts the thermoplastic fibers only partially, to form a porous and flexible but handleable consolidated mat;    c) heating the consolidated mat to a temperature above the melting point of the thermoplastic fibers;    d) compressing the consolidated mat while still hot in a heated double band press at a pressure of 0.8 bar or less for a period of at least 3 seconds to form a densified but still porous product containing reinforcing fibers and molten thermoplastic; and    e) cooling said densified porous product at a pressure of 0.8 bar or less in a cool zone of a double band press maintained at a temperature below the melt temperature of the thermoplastic fibers, for a time period sufficient to allow the thermoplastic to solidify and form a porous thermoformable intermediate product.    
   
   
       2 . The process of  claim 1 , wherein prior to or during step d), at least one functional layer is compressed onto the heated consolidated mat.  
   
   
       3 . The process of  claim 2 , wherein prior to the heated zone of the double band press is positioned a heated roll pair which force the functional layer(s) against the heated consolidated mat.  
   
   
       4 . The process of  claim 3 , wherein the heated roll pair exert a line pressure of from 10 to 50 N/mm.  
   
   
       5 . The process of  claim 2  wherein at least one functional layer is a molten film of a compatible thermoplastic.  
   
   
       6 . The process of  claim 1 , wherein the average length of the thermoplastic fibers and the average length of the reinforcing fibers differ by no more than 25% prior to needling.  
   
   
       7 . The process of  claim 1 , wherein the thermoplastic fibers and reinforcing fibers are air blended, deposited on a moving belt, and carded.  
   
   
       8 . The process of  claim 1 , wherein the reinforcing fibers are supplied to the process as multi-fiber strands.  
   
   
       9 . The process of  claim 1 , wherein the average fiber length of the thermoplastic fibers and the reinforcing fibers lies within the range of 20 mm to 120 mm prior to needling.  
   
   
       10 . The process of  claim 1 , wherein the porosity of the porous thermoformable intermediate product is uniformly distributed.  
   
   
       11 . The process of  claim 1 , wherein the heated zone of the double band press is maintained at a temperature greater than 80° C. and the cool zone of the double band press is maintained at a temperature of less than 30° C.  
   
   
       12 . The process of  claim 1 , wherein the pressure during step d) is between 0.05 bar to 0.5 bar.  
   
   
       13 . The process of  claim 1 , wherein a dwell time in the heated zone of the double band press is from 5 to 60 seconds.  
   
   
       14 . The process of  claim 1 , wherein within the double band press following the cool zone is a cooled roll pair which exert pressure on the porous, thermoformable intermediate product, the line pressure between the cooled roll pair being from 10 to 50 N/mm.  
   
   
       15 . The process of  claim 1  wherein the amounts of thermoplastic fibers and reinforcing fibers are such that the porous, thermoformable intermediate product has a thermoplastic content of between 20 to 65 weight percent, a reinforcing fiber content between 80 and 35 weight percent, the thermoplastic fibers and reinforcing fibers each having an average length of from 20 mm to 60 mm, the porous, thermoformable intermediate product having a content of from 35% to 65% by volume of uniformly distributed porosity, and having an areal weight of between 250 to 1800 g/m 2 .  
   
   
       16 . The process of  claim 15 , wherein said reinforcing fiber comprises basalt fibers.  
   
   
       17 . The process of  claim 16 , wherein basalt fibers and natural fibers are present as reinforcing fibers, in a weight ratio of 10:90 to 50:50.  
   
   
       18 . The process of  claim 1 , wherein the lofty, continuous non-woven mat has a void content V of from 85 volume percent to greater than 99 volume percent, and the flexible but handleable consolidated mat is consolidated by at least one needle punching consolidation step and has a volume percent porosity of from 0.85V to 0.95V, and the porous thermoformable intermediate product has a void content of 0.25V to 0.8V and minimally 25 volume percent porosity.  
   
   
       19 . The process of  claim 1 , further comprising f) allowing a compressed product formed in step (e) to re-expand to a greater thickness while at a temperature at or higher than the melting temperature of the thermoplastic and cooling under contact but at low or no pressure such that the final thickness of the fully cooled intermediate product is less than that in the initial portion of the cool zone.  
   
   
       20 . The process of  claim 19 , wherein said step of re-expanding is accomplished outside said double band press by reheating the porous thermoformable intermediate product.