Compact reforming reactor

Abstract

Reforming reactor for the conversion of a process fluid into hydrogen comprising: a reforming section which is contained within a closed volume, a boiler section and a combustion section, in which said reforming section contains one or more catalyst tubes filled with reforming catalyst, said boiler section is provided with one or more flow channels for the passage of flue gas from the combustion section and said combustion section is provided with at least one burner, wherein the heat exchanging medium required for the reforming of said process fluid in the one or more catalyst tubes is a gas-liquid mixture that self-circulates and is encapsulated inside said closed volume and wherein at least a portion of said closed volume protrudes inside said boiler section.

1 . Reforming reactor for the conversion of a process fluid into hydrogen comprising: a reforming section which is contained within a closed volume, a boiler section and a combustion section, in which said reforming section contains one or more catalyst tubes filled with reforming catalyst, said boiler section is provided with one or more flow channels for the passage of flue gas from the combustion section and said combustion section is provided with at least one burner, wherein the heat exchanging medium required for the reforming of said process fluid in the one or more catalyst tubes is a gas-liquid mixture that self-circulates and is encapsulated inside said closed volume and wherein at least a portion of said closed volume protrudes inside said boiler section.  
   
   
       2 . Reactor according to claim,  1  in which the portion of said closed volume inside which the gas-liquid mixture self-circulates protrudes inside the boiler section as a single elongated element or as a number of elongated elements so as to form a plurality of circumferentially and radially spaced elongated elements, and in which said elongated elements are in fluid communication with one another.  
   
   
       3 . Reactor according to  claim 2 , in which the boiler section of the reactor is provided with a number of vertically spaced or horizontally spaced baffles in which said baffles are arranged substantially transverse to the flow direction of the flue gas generated in the combustion section.  
   
   
       4 . Reactor according to  claim 2 , wherein the one or more elongated members, which are preferably formed as tubes, are provided with a sleeve so as to allow for the passage of flue gas through the annular region defined by said elongated member and said sleeve.  
   
   
       5 . Reactor according to  claim 1 , in which at least one process feed tube carrying the process fluid to be converted extends inside said closed volume of the reactor.  
   
   
       6 . Reactor according to  claim 5 , in which the at least one process feed tube carrying the process fluid to be converted enters the reactor through a conduct arranged in the outer wall of the reactor and wherein said process fluid is preheated by indirect contact with exiting converted gas from the reforming section of the reactor.  
   
   
       7 . Reactor according to  claim 5 , in which said at least one process feed tube extends vertically into a transition compartment from which at least one process tube carrying process gas to be converted extends vertically inside the closed volume of the reactor and wherein the at least one process tube carrying the process gas is formed as a coil.  
   
   
       8 . Reactor according to  claim 1 , in which said closed volume containing said reforming section and boiler section are substantially surrounded by an insulated housing, wherein said insulated housing is encased by a first annular region carrying flue gas and a second annular region carrying combustion air.  
   
   
       9 . Reactor according to  claim 1 , wherein the process fluid entering the reactor is a mixture of methanol and water and the gas-liquid mixture is a saturated steam-water system circulating at a pressure of 55 to 110 bar g and a temperature of 270° C. to about 320° C.  
   
   
       10 . Reactor according to  claim 1 , wherein said combustion section is provided with a single catalytic burner and wherein said catalytic burner is provided as wire mesh layers arranged in series which are coated with ceramic and impregnated with an oxidation catalyst, whereby the heat generated in the combustion is transferred by a convection mechanism to the self-circulating gas-liquid mixture via the generated flue gas.