Oxygen-scavenging containers

Abstract

A container providing effective oxygen-scavenging functionality, while having high L* color or low darkness. The container has at least one wall, wherein the wall comprises a populated area, and wherein the populated area comprises a film-forming polymer; and a population of particles comprising an effective amount of oxygen-scavenging particles, wherein the number of oxygen scavenging particles does not exceed a concentration of about (1×10 7 particles÷T) per cubic centimeter of polymer wherein T is the thickness of the populated area in mils; and wherein the change in the transmission Hunter L* of said wall is less than about 0.4 per mil of the container wall when compared to a control that does not contain oxygen-scavenging particles.

1 . A container having at least one wall, wherein the wall is a monolayer and comprises a populated area, and wherein the populated area comprises: 
 a film-forming polymer selected from the group consisting of polyethylene terephthalate, copolymers of polyethylene terephthalate, polyethylene naphthalate, copolymers of polyethylene naphthalate, polybutylene terephthalate, copolymers of polybutylene terephthalate, polytrimethylene terephthalate, and copolymers of polytrimethylene terephthalate; and    a population of particles comprising an effective amount of oxygen-scavenging particles, wherein the number of oxygen scavenging particles does not exceed a concentration of about      (1×10 7  particles÷T) per cubic centimeter of polymer    wherein T is the thickness of the populated area in mils;    wherein the oxygen scavenging particles comprise an element selected from the group consisting of calcium, magnesium, scandium, titanium, vanadium, chromium, manganese, iron, cobalt, nickel, copper, zinc, silver, tin, aluminum, germanium, silicon, lead, cadmium, and rhodium;    wherein the change in the transmission Hunter L* of said wall is less than about 0.4 per mil of the container wall when compared to a control that does not contain    oxygen-scavenging particles, wherein the concentration of oxygen scavenging particles is less than 3000 parts per million parts of populated area and said wall is of multilayer construction.    
   
   
       2 . The container of  claim 1 , wherein the film-forming polymer is selected from the group consisting of copolymers of polyethylene terephthalate, copolymers of polyethylene naphthalate, copolymers of polybutylene terephthalate, and copolymers of polytrimethylene terephthalate and the film forming polymer is prepared from one or more polyfunctional comonomers.  
   
   
       3 . The container of  claim 2 , wherein said polyfunctional comonomers are selected from the group consisting of pyromellitic dianhydride and pentaerythritol.  
   
   
       4 . The container of  claim 1 , wherein said effective amount is at least about 50 parts by weight oxygen-scavenging particles per million parts by weight polymer.  
   
   
       5 . The container of  claim 1 , wherein said oxygen-scavenging particles comprise iron.  
   
   
       6 . The container of  claim 2 , wherein said oxygen-scavenging particles comprise iron.  
   
   
       7 . The container of  claim 3 , wherein said oxygen-scavenging particles comprise iron.  
   
   
       8 . The container of  claim 1 , wherein said polymer further comprises one or more components selected from the group consisting of impact modifiers, surface lubricants, denesting agents, stabilizers, crystallization aids, antioxidants, ultraviolet light absorbing agents, catalyst deactivators, colorants, nucleating agents, acetaldehyde reducing agents, reheat reducing agents, fillers, branching agents, blowing agents, and accelerants.  
   
   
       9 . The container of  claim 1 , wherein said population of particles further comprises reaction-enhancing particles.  
   
   
       10 . The container of  claim 9 , wherein said reaction-enhancing particles comprise hydroscopic materials, electrolytic acidifying agents, non-electrolytic acidifying agents, metal halides, metal sulfates, metal bisulfates, or mixtures thereof.  
   
   
       11 . The container of  claim 1 , wherein said oxygen-scavenging particles are pretreated with at least one reaction-enhancing agent.  
   
   
       12 . The container of  claim 1 , wherein said container is a stretched bottle having a sidewall thickness of from about 11 to about 25 mils and a shift in transmission Hunter L* from the control sidewall of less than about 0.25 units per mil of container wall.  
   
   
       13 . The container of  claim 1 , wherein said oxygen-scavenging particles comprise carbon monoxide-reduced sponge iron.