Oxygen-scavenging containers having low haze

Abstract

A container providing effective oxygen-scavenging functionality, while having low haze. The container has at least one wall, wherein the wall comprises a populated area, and wherein the populated area comprises a film-forming polymer; and a population of particles comprising an effective amount of oxygen-scavenging particles, wherein the number of particles of said population does not exceed a concentration of about (6×10 7 particles÷T) per cubic centimeter of polymer wherein T is the thickness of the populated area in mils; and wherein the wall has a transmission Hunter haze of up to about 1 percent per mil of the container wall.

1 . A container having at least one wall, wherein the wall comprises a populated area, and wherein the populated area comprises: 
 a film-forming polymer selected from the group consisting of polyethylene terephthalate, copolymers of polyethylene terephthalate, polyethylene naphthalate, copolymers of polyethylene naphthalate, polybutylene terephthalate, copolymers of polybutylene terephthalate, polytrimethylene terephthalate, and copolymers of polytrimethylene terephthalate; and    a population of particles comprising an effective amount of oxygen-scavenging particles, wherein the number of particles of said population does not exceed a concentration of about 
 (6×10 7  particles÷T) per cubic centimeter of polymer wherein T is the thickness of the populated area in mils;  
 wherein the oxygen scavenging particles comprise an element selected from the group consisting of calcium, magnesium, scandium, titanium, vanadium, chromium, manganese, iron, cobalt, nickel, copper, zinc, silver, tin, aluminum, germanium, silicon, lead, cadmium, and rhodium;  
 wherein said wall has a transmission Hunter haze of up to about 1 percent per mil of the container wall; and  
 said wall is of a multilayer construction.  
   
   
   
       2 . The container of  claim 1 , wherein the film-forming polymer is selected from the group consisting of copolymers of polyethylene terephthalate, copolymers of polyethylene naphthalate, copolymers of polybutylene terephthalate, and copolymers of polytrimethylene terephthalate and the film forming polymer is prepared from one or more polyfunctional comonomers.  
   
   
       3 . The container of  claim 2 , wherein said polyfunctional comonomers are selected from the group consisting of pyromellitic dianhydride and pentaerythritol.  
   
   
       4 . The container of  claim 1 , wherein said oxygen-scavenging particles comprise iron.  
   
   
       5 . The container of  claim 2 , wherein said oxygen-scavenging particles comprise iron.  
   
   
       6 . The container of  claim 3 , wherein said oxygen-scavenging particles comprise iron.  
   
   
       7 . The container of  claim 1 , wherein said oxygen-scavenging particles comprise iron, and wherein said oxygen-scavenging particles are present in an amount of from about 50 to about 12,000 parts per million by weight of the resin.  
   
   
       8 . The container of  claim 1 , wherein said population of particles further comprises reaction-enhancing particles.  
   
   
       9 . The container of  claim 8 , wherein said reaction-enhancing particles comprise hydroscopic materials, electrolytic acidifying agents, non-electrolytic acidifying agents, metal halides, metal sulfates, metal bisulfates, or mixtures thereof.  
   
   
       10 . The container of  claim 1 , wherein said oxygen-scavenging particles are pretreated with at least one reaction-enhancing agent.  
   
   
       11 . The container of  claim 1 , wherein said container is a stretched bottle having a sidewall thickness of from about 11 to about 25 mils and a Hunter haze value of about 10% or less.  
   
   
       12 . The container of  claim 7 , wherein said container is a stretched bottle having a sidewall thickness of from about 11 to about 25 mils and a Hunter haze value of about 10% or less.  
   
   
       13 . The container of  claim 10 , wherein said container is a stretched bottle having a sidewall thickness of from about 11 to about 25 mils and a Hunter haze value of about 10% or less.