High-strength black polyurethane foams

Abstract

Black polyurethane foams that exhibit higher strength black colorations without the need for concomitant increases in black colorants therein are provided. Such a resultant jetter black foam article is possible through the unexpectedly effective introduction of small amounts of certain toner compounds or combinations that exhibit specific measurable appearance characteristics. Such toners exhibit at least one absorption peak within a specific range of wavelengths (e.g., from about 560 to 610 nm) and specific ranges of half-height bandwidths (from 40 to 130 nm). Furthermore, such a compound or combination of compounds, is preferably liquid in nature (at room temperature) or in dispersion form and may thus be easily incorporated within target polyurethane precursor compositions for admixture with either black pigments (or dispersions thereof), black polymeric (liquid) colorants, or both. Methods of high strength black polyurethane foam production as well as separate pigmented and liquid polymeric colored foams of such type including the necessary toner compounds and/or combinations, as noted above, are also encompassed within this invention.

1 - 8 . (canceled)  
   
   
       9 . A black-colored polyurethane foam article containing a black coloring agent comprising (i) a red colorant exhibiting a peak absorbance between about 465 nm and about 540 nm, (ii) a yellow colorant exhibiting a peak absorbance between about 400 nm and about 465 nm, and (iii) a blue colorant exhibiting a peak absorbance between about 540 nm and about 700 nm, the polyurethane foam article comprising (a) the black coloring agent, and (b) at least one discrete toner compound comprising a triphenylmethane chromophore, the toner compound exhibiting at least one absorption peak having a λ max  between 560 nm and 610 nm within said article and a half-height bandwidth range of from 40 nm to 130 nm in relation to said at least one absorption peak.  
   
   
       10 . The article of  claim 9 , wherein said at least one toner compound exhibits a half-height bandwidth of at most 120 nm in relation to said at least one absorption peak.  
   
   
       11 . The article of  claim 9 , wherein the cumulative mass of said at least one toner compound is in the range of about 0.1 to about 6% of the cumulative mass of said black coloring agent.  
   
   
       12 . The article of  claim 9 , wherein the triphenylmethane chromophore conforms to the structure of Formula (II)  
     
       
         
         
             
             
         
       
       wherein R 5 , R 6 , R 7 , R 8 , R 9 , and R 10  are the same or different and are selected from the group consisting of hydrogen, C 1 -C 20  alkyl, C 1 -C 20  alkoxy, phenyl and substituted phenyl, and [polyoxyalkylene constituent] z R′, wherein z is from 1 to 20, polyoxyalkylene constituent comprises at least one monomer selected from the group consisting of a C 2 -C 20  alkyleneoxy group, glycidyl, or mixtures thereof and R′ is a group selected from the group consisting of hydrogen, C 1 -C 20  alkyl, C 1 -C 20  alkylester, halo, hydroxy, thio, cyano, sulfonyl, sulfo, sulfato, aryl, nitro, carboxyl, C 1 -C 20  alkoxyl, amino, alkylamino, acrylamino, C 1 -C 20  alkylthio, alkylsulfonyl, C 1 -C 20  alkoxylcarbonyl and phenylthio; wherein X is selected from the group consisting of F, Cl, Br, I, NO 2 , SO 4 , HSO 4 , P 0   4 , HOP 4 , H 2 PO 4 , and R″SO 3  and R″ is selected from the group consisting of C 1 -C 20  alkyl, phenyl, or substituted phenyl.  
     
   
   
       13 . In a black-colored polyurethane foam article containing a black coloring agent comprising (i) a red colorant exhibiting a peak absorbance between about 465 nm and about 540 nm, (ii) a yellow colorant exhibiting a peak absorbance between about 400 nm and about 465 nm, and (iii) a blue colorant exhibiting a peak absorbance between about 540 nm and about 700 nm, the improvement comprising the inclusion of at least one discrete toner compound comprising a triphenylmethane chromophore, the toner compound exhibiting at least one absorption peak having a λ max  between 560 nm and 610 nm within said article and a half-height bandwidth range of from 40 nm to 130 nm in relation to said at least one absorption peak.  
   
   
       14 . The article of  claim 13 , wherein said at least one toner compound exhibits a half-height bandwidth of at most 120 nm in relation to said at least one absorption peak.  
   
   
       15 . The article of  claim 13 , wherein the cumulative mass of said at least one toner compound is in the range of about 0.1 to about 6% of the cumulative mass of said black coloring agent.  
   
   
       16 . The article of  claim 13 , wherein the triphenylmethane chromophore conforms to the structure of Formula (II)  
     
       
         
         
             
             
         
       
       wherein R 5 , R 6 , R 7 , R 8 , R 9 , and R 10  are the same or different and are selected from the group consisting of hydrogen, C 1 -C 20  alkyl, C 1 -C 20  alkoxy, phenyl and substituted phenyl, and [polyoxyalkylene constituent] z R′, wherein z is from 1 to 20, polyoxyalkylene constituent comprises at least one monomer selected from the group consisting of a C 2 -C 20  alkyleneoxy group, glycidyl, or mixtures thereof, and R′ is a group selected from the group consisting of hydrogen, C 1 -C 20  alkyl, C 1 -C 20  alkylester, halo, hydroxy, thio, cyano, sulfonyl, sulfo, sulfato, aryl, nitro, carboxyl, C 1 -C 20  alkoxyl, amino, alkylamino, acrylamino, C 1 -C 20  alkylthio, alkylsulfonyl, C 1 -C 20  alkoxylcarbonyl and phenylthio; wherein X is selected from the group consisting of F, Cl, Br, I, NO 2 , SO 4 , HSO 4 , PO 4 , HPO 4 , H 2 PO 4 , and R″SO 3  and R″ is the group consisting of C 1 -C 20  alkyl, phenyl, or substituted phenyl.