US2007169859A1PendingUtilityA1
High strength and high toughness metal and method of producing the same
Est. expirySep 30, 2024(expired)· nominal 20-yr term from priority
B23K 2103/15B22D 21/007C22C 1/00C22C 23/04B21J 5/00C22F 1/06B23K 20/122C22B 59/00C22C 23/06C22C 23/00B21B 3/00B21C 23/002
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Claims
Abstract
This invention provides a high-strength and high-toughness metal which has strength and toughness each high enough to be put to practical use in expanded applications of magnesium alloys, and a process for producing the same. The high-strength and high-toughness metal is a magnesium alloy comprising a crystal structure containing an hcp-structure magnesium phase and a long-period layered structure phase. At least a part of the long-period layered structure phase is in a curved or flexed state. The magnesium alloy comprises a atomic % of Zn and b atomic % of Gd with the balance consisting of Mg.
Claims
exact text as granted — not AI-modified1 . A high strength and high toughness metal comprising a magnesium alloy having a crystal structure having an hcp-Mg phase and a long-period stacking ordered structure phase,
wherein at least a part of said long-period stacking ordered structure phase exists in a lamellar form with a 2H structure Mg phase.
2 . A high strength and high toughness metal in which a plastically worked product produced by subjecting a magnesium alloy to a plastic working has a crystal structure having an hcp-Mg phase and a long-period stacking ordered structure phase,
wherein at least a part of said long-period stacking ordered structure phase exists in a lamellar form with a 2H structure Mg phase.
3 . The high strength and toughness metal according to claim 1 or 2 ,
wherein at least a part of said lamellar structure existing in a lamellar form is flexed or bend.
4 . A high strength and high toughness metal comprising a magnesium alloy having a crystal structure having an hcp-Mg phase and a long-period stacking ordered structure phase,
wherein at least a part of said long-period stacking ordered structure phase is flexed or bend.
5 . A high strength and high toughness metal in which a plastically worked product produce by subjecting a magnesium alloy to a plastic working has a crystal structure having an hcp-Mg phase and a long-period stacking ordered structure phase,
wherein at least a part of said long-period stacking ordered structure phase is flexed or bend.
6 . The high strength and high toughness metal according to claim 2 or 5 ,
wherein said magnesium alloy before subjecting to a plastic working has a crystal structure having a long-period stacking ordered structure phase in which flexure or bend is not formed.
7 . The high strength and high toughness metal according to any one of claims 1 , 2 and 5 ,
wherein a part of a region where said long-period stacking ordered structure phase is flexed or bend contains random grain boundaries.
8 . The high strength and high toughness metal according to any one of claims 1 , 2 , 4 and 5 ,
wherein said long-period stacking ordered structure phase has a dislocation density one-digit smaller than said hcp-Mg phase.
9 . The high strength and high toughness metal according to claim 4 ,
wherein said magnesium alloy contains Zn in an amount of “a” atomic % and Y in an amount of “b” atomic %, wherein “a” and “b” satisfy the following expressions (1) to (3): 0.5≦ a≦ 5.0; (1) 1.0≦ b≦ 5.0; and (2) 0.5 a≦b. (3)
10 . The high strength and high toughness metal according to claim 4 ,
wherein said magnesium alloy contains Zn in an amount of “a” atomic % and at least one element selected from the group consisting of Dy, Ho and Er in a total amount of “b” atomic %, wherein “a” and “b” satisfy the following expressions (1) to (3): 0.2≦ a≦ 5.0; (1) 0.2≦ b≦ 5.0; and (2) 0.5 a −0.5≦ b. (3)
11 . The high strength and high toughness metal according to claim 4 ,
wherein said magnesium alloy contains Zn in an amount of “a” atomic % and at least one element selected from the group consisting of Dy, Ho and Er in a total amount of “b” atomic %, wherein “a” and “b” satisfy the following expressions (1) to (3): 0.2≦ a≦ 3.0; (1) 0.2≦ b≦ 5.0; and (2) 2 a− 3≦ b. (3)
12 . The high strength and high toughness metal according to claim 10 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of Y, Gd, Tb, Tm and Lu in a total amount of “y” atomic %, wherein “y” satisfies the following expressions (4) to (5): 0≦ y≦ 4.8; and (4) 0.2≦ b+y≦ 5.0. (5 )
13 . The high strength and high toughness metal according to claim 9 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of Yb, Sm and Nd in a total amount of “c” atomic %, wherein “c” satisfies the following expressions (4) to (5): 0≦ c≦ 3.0; and (4) 0.2≦ b+c≦ 6.0. (5)
14 . The high strength and high toughness metal according to claim 10 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of Yb, Sm and Nd in a total amount of “c” atomic %, wherein “c” satisfies the following expressions (4) to (5): 0≦ c≦ 3.0; and (4) 0.2≦ b+c≦ 6.0. (5)
15 . The high strength and high toughness metal according to claim 9 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “c” atomic %, wherein “c” satisfies the following expressions (4) to (5): 0.2≦ c≦ 2.0; and (4) 0.2≦ b+c≦ 6.0 (5)
16 . The high strength and high toughness metal according to claim 10 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “c” atomic %, wherein “c” satisfies the following expressions (4) to (5): 0.2≦ c≦ 2.0; and (4) 0.2≦ b+c≦ 6.0 (5)
17 . The high strength and high toughness metal according to any one of claim 9 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of Yb, Sm and Nd in a total amount of “c” atomic % and at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “d” atomic %, wherein “c” and of “d” satisfy the following expressions (4) to (6): 0≦ c≦ 3.0; (4) 0≦ d≦ 2.0; and (5) 0.2≦ b+c+d≦ 6.0. (6)
18 . The high strength and high toughness metal according to claim 10 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of Yb, Sm and Nd in a total amount of “c” atomic % and at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “d” atomic %, wherein “c” and of “d” satisfy the following expressions (4) to (6): 0≦ c≦ 3.0; (4) 0≦ d≦ 2.0; and (5) 0.2≦ b+c+d≦ 6.0. (6)
19 . The high strength and high toughness metal according to claim 4 ,
wherein said magnesium alloy contains Zn in an amount of “a” atomic % and Y in an amount of “b” atomic %, wherein “a” and “b” satisfy the following expressions (1) to (3): 0.25≦ a≦ 5.0; (1) 0.5≦ b≦ 5.0; and (2) 0.5 a≦b. (3)
20 . The high strength and high toughness metal according to claim 4 ,
wherein said magnesium alloy contains Zn in an amount of “a” atomic % and at least one element selected from the group consisting of Dy, Ho and Er in a total amount of “b” atomic %, wherein “a” and “b” satisfy the following expressions (1) to (3): 0.1≦ a≦ 5.0; (1) 0.1≦ b≦ 5.0; and (2) 0.5 a− 0.5≦ b. (3 )
21 . The high strength and high toughness metal according to claim 4 ,
wherein said magnesium alloy contains Zn in an amount of “a” atomic % of Zn and at least one element selected from the group consisting of Dy, Ho and Er in a total amount of “b” atomic %, wherein “a” and “b” satisfy the following expressions (1) to (3): 0.1≦ a≦ 3.0; (1) 0.1≦ b≦ 5.0; and (2) 2 a− 3≦ b. (3)
22 . The high strength and high toughness metal according to claim 20 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of Y, Gd, Tb, Tm and Lu in a total amount of “y” atomic %, wherein “y” satisfies the following expressions (4) to (5): 0≦ y≦ 4.9; and (4) 0.1≦ b+y≦ 5.0. (5)
23 . The high strength and high toughness metal according to claim 19 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of Yb, Sm and Nd in a total amount of “c” atomic %, wherein “c” satisfies the following expressions (4) to (5): 0≦ c≦ 3.0; and (4) 0.1≦ b+c≦ 6.0. (5)
24 . The high strength and high toughness metal according to claim 20 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of Yb, Sm and Nd in a total amount of “c” atomic %, wherein “c” satisfies the following expressions (4) to (5): 0≦ c≦ 3.0; and (4) 0.1≦ b+c≦ 6.0. (5)
25 . The high strength and high toughness metal according to claim 19 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “c” atomic %, wherein “c” satisfies the following expressions (4) to (5): 0≦ c≦ 2.0; and (4) 0.1≦ b+c≦ 6.0. (5)
26 . The high strength and high toughness metal according to claim 20 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “c” atomic %, wherein “c” satisfies the following expressions. (4) to (5): 0≦ c≦ 2.0; and (4) 0.1≦ b+c≦ 6.0. (5)
27 . The high strength and high toughness metal according to claim 19 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of Yb, Sm and Nd in a total amount of “c” atomic % and at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “d” atomic %, wherein “c” and of “d” satisfy the following expressions (4) to (6): 0≦ c≦ 3.0; (4) 0≦ d≦ 2.0.; and (5) 0.1≦ b+c+d≦ 6.0. (6)
28 . The high strength and high toughness metal according to claim 20 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of Yb, Sm and Nd in a total amount of “c” atomic % and at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “d” atomic %, wherein “c” and of “d” satisfy the following expressions (4) to (6): 0≦ c≦ 3.0; (4) 0≦ d≦ 2.0.; and (5) 0.1≦ b+c+d≦ 6.0. (6)
29 . The high strength and high toughness metal according to claim 4 ,
wherein said magnesium alloy contains Zn in an amount of “a” atomic % and of at least one element selected from the group consisting of Gd, Tb, Tm and Lu in a total amount of “b” atomic %, wherein “a” and “b” satisfy the following expressions (1) to (3): 0.2≦ a≦ 5.0; (1) 0.5≦ b≦ 5.0; and (5) 0.5 a− 0.5≦ b. (6)
30 . The high strength and high toughness metal according to claim 4 ,
wherein said magnesium alloy contains Zn in an amount of “a” atomic % of Zn and at least one element selected from the group consisting of Gd, Tb, Tm and Lu in a total amount of “b” atomic %, wherein “a” and “b” satisfy the following expressions (1) to (3): 0.2 ≦a≦ 3.0; (1) 0.5 ≦b≦ 5.0.; and (5) 2 a− 3 ≦b. (6)
31 . The high strength and high toughness metal according to claim 29 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of Yb, Sm and Nd in a total amount of “c” atomic %, wherein “c” satisfies the following expressions (4) to (5): 0≦ c≦ 3.0; and (4) 0.5 ≦b+c≦ 6.0. (5)
32 . The high strength and high toughness metal according to claim 29 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “c” atomic %, wherein “c” satisfies the following expressions (4) to (5): 0≦ c≦ 2.0; and (4) 0.5≦ b+c≦ 6.0. (5)
33 . The high strength and high toughness metal according to claim 29 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of Yb, Sm and Nd in a total amount of “c” atomic % and at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “d” atomic %, wherein “c” and “d” satisfy the following expressions (4) to (6): 0≦ c≦ 3.0; (4) 0≦ d≦ 2.0; and (5) 0.5 ≦b+c+d≦ 6.0. (6)
34 . The high strength and high toughness metal according to claim 4 ,
wherein said magnesium alloy contains Zn in an amount of “a” atomic % and at least one element selected from the group consisting of Gd, Tb, Tm and Lu in a total amount of “b” atomic %, wherein “a” and “b” satisfy the following expressions (1) to (3): 0.1 ≦a≦ 5.0; (1) 0.25 ≦b≦ 5.0; and (2) 0.5 a− 0.5 ≦b. (3)
35 . The high strength and high toughness metal according to claim 4 ,
wherein said magnesium alloy contains Zn in an amount of “a” atomic % and at least one element selected from the group consisting of Gd, Tb, Tm and Lu in an amount of “b” atomic %, wherein “a” and “b” satisfy the following expressions (1) to (3): 0.1 ≦a≦ 3.0; (1) 0.25 ≦b≦ 5.0; and (2) 2 a− 3 ≦b. (3)
36 . The high strength and high toughness metal according to claim 34 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of Yb, Sm and Nd in a total amount of “c” atomic %, wherein “c” satisfy the following expressions (4) to (5): 0≦ c≦ 3.0; and (4) 0.25 ≦b+c≦ 6.0. (5)
37 . The high strength and high toughness metal according to claim 34 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “c” atomic %, wherein “c” satisfy the following expressions (4) to (5): 0≦ c≦ 2.0; and (4) 0.25 ≦b+c≦ 6.0. (5)
38 . The high strength and high toughness metal according to claim 34 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of Yb, Sm and Nd in a total amount of “c” atomic % and at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “d” atomic %, wherein “c” and of “d” satisfy the following expressions (4) to (6): 0≦ c≦ 3.0; (4) 0≦ d≦ 2.0; and (5) 0.25≦ b+c+d≦ 6.0. (6)
39 . The high strength and high toughness metal according to claim 29 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of Dy, Ho and Er in a total amount of larger than 0 atomic % to 1.5 atomic % or less.
40 . The high strength and high toughness metal according to claim 34 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of Dy, Ho and Er in a total amount of larger than 0 atomic % to 1.5 atomic % or less.
41 . The high strength and high toughness metal according to claim 29 ,
wherein said magnesium alloy contains Y in an amount of larger than 0 atomic % to 1.0 atomic % or less.
42 . The high strength and high toughness metal according to claim 34 ,
wherein said magnesium alloy contains Y in an amount of larger than 0 atomic % to 1.0 atomic % or less.
43 . The high strength and high toughness metal according to claim 29 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of Gd, Tb, Tm and Lu in a total amount of less than 3 atomic %.
44 . The high strength and high toughness metal according to claim 34 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of Gd, Tb, Tm and Lu in a total amount of less than 3 atomic %.
45 . The high strength and high toughness metal according to claim 9 ,
wherein said magnesium alloy is produced by the following manner: a mineral ore containing rare-earth elements is refined to prepare a rare-earth alloy containing plural rare-earth elements; and the rare-earth alloy is used as a part of starting material for casting to produce said magnesium alloy which contains the rare-earth elements in a total amount of 6.0 atomic % or less.
46 . The high strength and high toughness metal according to claim 10 ,
wherein said magnesium alloy is produced by the following manner: a mineral ore containing rare-earth elements is refined to prepare a rare-earth alloy containing plural rare-earth elements; and the rare-earth alloy is used as a part of starting material for casting to produce said magnesium alloy which contains the rare-earth elements in a total amount of 6.0 atomic % or less.
47 . The high strength and high toughness metal according to claim 19 ,
wherein said magnesium alloy is produced by the following manner: a mineral ore containing rare-earth elements is refined to prepare a rare-earth alloy containing plural rare-earth elements; and the rare-earth alloy is used as a part of starting material for casting to produce said magnesium alloy which contains the rare-earth elements in a total amount of 6.0 atomic % or less.
48 . The high strength and high toughness metal according to claim 20 ,
wherein said magnesium alloy is produced by the following manner: a mineral ore containing rare-earth elements is refined to prepare a rare-earth alloy containing plural rare-earth elements; and the rare-earth alloy is used as a part of starting material for casting to produce said magnesium alloy which contains the rare-earth elements in a total amount of 6.0 atomic % or less.
49 . The high strength and high toughness metal according to claim 29 ,
wherein said magnesium alloy is produced by the following manner: a mineral ore containing rare-earth elements is refined to prepare a rare-earth alloy containing plural rare-earth elements; and the rare-earth alloy is used as a part of starting material for casting to produce said magnesium alloy which contains the rare-earth elements in a total amount of 6.0 atomic % or less.
50 . The high strength and high toughness metal according to claim 34 ,
wherein said magnesium alloy is produced by the following manner: a mineral ore containing rare-earth elements is refined to prepare a rare-earth alloy containing plural rare-earth elements; and the rare-earth alloy is used as a part of starting material for casting to produce said magnesium alloy which contains the rare-earth elements in a total amount of 6.0 atomic % or less.
51 . The high strength and high toughness metal according to claim 9 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of Al, Th, Ca, Si, Mn, Zr, Ti, Hf, Nb, Ag, Sr, Sc, B and C in a total amount of larger than 0 atomic % to 2.5 atomic % or less.
52 . The high strength and high toughness metal according to claim 9 ,
wherein said magnesium alloy contains at least one precipitate selected from the group consisting of a precipitate comprising compound of Mg and rare-earth element, precipitate comprising compound of Mg and Zn, precipitate comprising compound of Zn and rare-earth element and precipitate comprising compound of Mg, Zn and rare-earth element.
53 . The high strength and high toughness metal according to claim 9 ,
wherein said magnesium alloy has a grain size of 100 nm to 500 μm.
54 . A high strength and high toughness metal having a composition of general formula of Mg (100-x-y) Y x Zn y (1<x<5, 0.3<y<6; x and y represent atomic %) and having a crystal structure having an average grain size of 1 μm or smaller,
wherein said Mg (100-x-y) Y x Zn y is produced in the following manner: a mineral ore containing rare-earth elements is refined to prepare a rare-earth alloy containing plural rare-earth elements; the rare-earth alloy is used as a part of starting material and made into liquid form; the rare-earth alloy in liquid form is rapidly solidified into powder, thin band or thin wire; and the powder, thin band or thin wire is solidified so as to be applied with shear.
55 . The high strength and high toughness metal according to claim 45 ,
wherein said rare-earth alloy contains at least one element selected from the group consisting of Y, Gd, Tb, Dy, Ho, Er, Tm and Lu in a total amount of 50 atomic % or more and at least one rare-earth element other than Y, Gd, Tb, Dy, Ho, Er, Tm and Lu in a total amount of less than 50 atomic %.
56 . The high strength and high toughness metal according to claim 54 ,
wherein said rare-earth alloy contains at least one element selected from the group consisting of Y, Gd, Tb, Dy, Ho, Er, Tm and Lu in a total amount of 50 atomic % or more and at least one rare-earth element other than Y, Gd, Tb, Dy, Ho, Er, Tm and Lu in a total amount of less than 50 atomic %.
57 . A method of producing a high strength and high toughness metal comprising:
a step for preparing a magnesium alloy having a crystal structure having an hcp-Mg phase and a long-period stacking ordered structure phase, wherein at least a part of said long-period stacking ordered structure phase exists in a lamellar form with a 2H structure Mg phase; and a step for subjecting said magnesium alloy to a plastic working to produce a plastically worked product which keeps a lamellar structure existing in a lamellar form.
58 . A method of producing a high strength and high toughness metal comprising:
a step for preparing a magnesium alloy having a crystal structure having an hcp-Mg phase and a long-period stacking ordered structure phase; and a step for subjecting said magnesium alloy to a plastic working to produce a plastically worked product in which at least a part of said long-period stacking ordered structure phase is flexed or bend.
59 . The method of producing a high strength and high toughness metal according to claim 57 ,
wherein said step for preparing a magnesium alloy is a step for producing a magnesium alloy casting product which contains Zn in an amount of “a” atomic % and Y in an amount of “b” atomic %, wherein “a” and “b” satisfy the following expressions (1) to (3): 0.5 ≦a≦ 5.0; (1) 1.0 ≦b≦ 5.0; and (2) 0.5 a≦b. (3)
60 . The method of producing a high strength and high toughness metal according to claim 57 ,
wherein said step for preparing a magnesium alloy is a step for producing a magnesium alloy casting product which contains Zn in an amount of “a” atomic % and at least one element selected from the group consisting of Dy, Ho and Er in a total amount of “b” atomic %, wherein “a” and “b” satisfy the following expressions (1) to (3): 0.2 ≦a≦ 5.0; (1) 0.2 ≦b≦ 5.0; and (2) 0.5 a− 0.5 ≦b. (3)
61 . The method of producing a high strength and high toughness metal according to claim 57 ,
wherein said step for preparing a magnesium alloy is a step for producing a magnesium alloy casting product which contains Zn in an amount of “a” atomic % and at least one element selected from the group consisting of Dy, Ho and Er in a total amount of “b” atomic %, wherein “a” and “b” satisfy the following expressions (1) to (3): 0.2 ≦a≦ 3.0; (1) 0.2 ≦b≦ 5.0; and (2) 2 a− 3 ≦b. (3)
62 . The method of producing a high strength and high toughness metal according to claim 60 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of Y, Gd, Tb, Tm and Lu in a total amount of “y” atomic %, wherein “y” satisfies the following expressions (4) to (5): 0 ≦y≦ 4.8; and (4) 0.2 ≦b+y≦ 5.0. (5)
63 . The method of producing a high strength and high toughness metal according to claim 59 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of Yb, Sm and Nd a total amount of “c” atomic %, wherein “c” satisfies the following expressions (4) to (5): 0 ≦c≦ 3.0; and (4) 0.2 ≦b+c≦ 6.0. (5)
64 . The method of producing a high strength and high toughness metal according to claim 60 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of Yb, Sm and Nd a total amount of “c” atomic %, wherein “c” satisfies the following expressions (4) to (5): 0≦ c≦ 3.0; and (4) 0.2 ≦b+c≦ 6.0. (5)
65 . The method of producing a high strength and high toughness metal according to claim 59 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “c” atomic %, wherein “c” satisfies the following expressions (4) to (5): 0≦ c≦ 2.0; and (4) 0.2 ≦b+c≦ 6.0. (5)
66 . The method of producing a high strength and high toughness metal according to claim 60 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “c” atomic %, wherein “c” satisfies the following expressions (4) to (5): 0≦ c≦ 2.0; and (4) 0.2 ≦b+c≦ 6.0. (5)
67 . The method of producing a high strength and high toughness metal according to claim 59 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of Yb, Sm and Nd in a total amount of “c” atomic % and at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “d” atomic %, wherein “c” and of “d” satisfy the following expressions (4) to (6): 0≦ c≦ 3.0; (4) 0≦ d≦ 2.0; and (5) 0.2 ≦b+c+d≦ 6.0. (6)
68 . The method of producing a high strength and high toughness metal according to claim 60 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of Yb, Sm and Nd in a total amount of “c” atomic % and at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “d” atomic %, wherein “c” and of “d” satisfy the following expressions (4) to (6): 0≦ c≦ 3.0; (4) 0≦ d≦ 2.0; and (5) 0.2 ≦b+c+d≦ 6.0. (6)
69 . A method of producing a high strength and high toughness metal comprising:
a step for preparing a magnesium alloy having a crystal structure having an hcp-Mg phase and a long-period stacking ordered structure phase, wherein at least a part of said long-period stacking ordered structure phase exists in a lamellar form with a 2H structure Mg phase; a step for cutting said magnesium alloy to form a chip-shaped cutting product; and a step for subjecting said chip-shaped cutting product to a plastic working to solidify and thereby to produce a plastically worked product keeping said lamellar structure existing in a lamellar form.
70 . A method of producing a high strength and high toughness metal comprising:
a step for preparing a magnesium alloy having a crystal structure having an hcp-Mg phase and a long-period stacking ordered structure phase; a step for cutting said magnesium alloy to produce a chip-shaped cutting product; and a step for subjecting said chip-shaped cutting product to a plastic working to solidify and thereby to produce a plastically worked product in which at least a part of said long-period stacking ordered structure phase is flexed or bend.
71 . The method of producing a high strength and high toughness metal according to claim 69 ,
wherein said step for preparing a magnesium alloy is a step for producing a magnesium alloy casting product which contains Zn in an amount of “a” atomic % and Y in an amount of “b” atomic %, wherein “a” and “b” satisfy the following expressions (1) to (3): 0.25 a≦ 5.0; (1) 0.5 ≦b≦ 5.0; and (2) 0.5 a≦b. (3)
72 . The method of producing a high strength and high toughness metal according to claim 69 ,
wherein said step for preparing a magnesium alloy is a step for producing a magnesium alloy casting product which contains Zn in an amount of “a” atomic % and at least one element selected from the group consisting of Dy, Ho and Er in a total amount of “b” atomic %, wherein “a” and “b” satisfy the following expressions (1) to (3): 0.1 ≦a≦ 5.0; (1) 0.1 ≦b≦ 5.0; and (2) 0.5 a− 0.5 ≦b. (3)
73 . The method of producing a high strength and high toughness metal according to claim 69 ,
wherein said step for preparing a magnesium alloy is a step for producing a magnesium alloy casting product which contains Zn in an amount of “a” atomic % and at least one element selected from the group consisting of Dy, Ho and Er in a total amount of “b” atomic %, wherein “a” and “b” satisfy the following expressions (1) to (3): 0.1 ≦a≦ 3.0; (1) 0.1 ≦b≦ 5.0; and (2) 2 a− 3 ≦b. (3)
74 . The method of producing a high strength and high toughness metal according to claim 72 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of Y, Gd, Tb, Tm and Lu in a total amount of “y” atomic %, wherein “y” satisfies the following expressions (4) to (5): 0 ≦y≦ 4.9; and (4) 0.1 ≦b+y≦ 5.0. (5)
75 . The method of producing a high strength and high toughness metal according to claim 71 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of Yb, Sm and Nd in a total amount of “c” atomic %, wherein “c” satisfies the following expressions (4) to (5): 0 ≦c≦ 3.0; and (4) 0.2 ≦b+c≦ 6.0. (5)
76 . The method of producing a high strength and high toughness metal according to claim 72 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of Yb, Sm and Nd in a total amount of “c” atomic %, wherein “c” satisfies the following expressions (4) to (5): 0 ≦c≦ 3.0; and (4) 0.2 ≦b+c≦ 6.0. (5)
77 . The method of producing a high strength and high toughness metal according to claim 71 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “c” atomic %, wherein “c” satisfies the following expressions (4) to (5): 0≦ c≦ 2.0; and (4) 0.1≦ b+c≦ 6.0. (5)
78 . The method of producing a high strength and high toughness metal according to claim 72 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “c” atomic %, wherein “c” satisfies the following expressions (4) to (5): 0 ≦c≦ 2.0; and (4) 0.1 ≦b+c≦ 6.0. (5)
79 . The method of producing a high strength and high toughness metal according to claim 71 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of Yb, Sm and Nd in a total amount of “c” atomic % and at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “d” atomic %, wherein “c” and “d” satisfy the following expressions (4) to (6): 0 ≦c≦ 3.0; (4) 0 ≦d≦ 2.0; and (5) 0.1 ≦b+c+d≦ 6.0. (6)
80 . The method of producing a high strength and high toughness metal according to claim 72 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of Yb, Sm and Nd in a total amount of “c” atomic % and at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “d” atomic %, wherein “c” and of “d” satisfy the following expressions (4) to (6): 0≦ c≦ 3.0; (4) 0≦ d≦ 2.0; and (5) 0.1 ≦b+c+d≦ 6.0. (6)
81 . The method of producing a high strength and high toughness metal according to claim 57 ,
wherein said step for preparing a magnesium alloy is a step for producing a magnesium alloy casting product which contains Zn in an amount of “a” atomic % and at least one element selected from the group consisting of Gd, Tb, Tm and Lu in a total amount of “b” atomic %, wherein “a” and “b” satisfy the following expressions (1) to (3): 0.2 ≦a≦ 5.0; (1) 0.5 ≦b≦ 5.0; and (2) 0.5 a− 0.5 ≦b; and, (3) the method further comprising: a step for subjecting said magnesium alloy to a heat treatment between said step for preparing a magnesium alloy casting product and said step for producing a plastically worked product.
82 . The method of producing a high strength and high toughness metal according to claim 57 ,
wherein said step for preparing a magnesium alloy is a step for producing a magnesium alloy casting product which contains Zn in an amount of “a” atomic % and at least one element selected from the group consisting of Gd, Tb, Tm and Lu in an amount of “b” atomic %, wherein “a” and “b” satisfy the following expressions (1) to (3): 0.2 ≦a≦ 3.0; (1) 0.5 ≦b≦ 5.0; and (2) 2 a− 3 ≦b; and, (3) the method further comprising: a step for subjecting said magnesium alloy to a heat treatment between said step for preparing a magnesium alloy casting product and said step for producing a plastically worked product.
83 . The method of producing a high strength and high toughness metal according to claim 81 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of Yb, Sm and Nd in a total amount of “c” atomic %, wherein “c” satisfies the following expressions (4) to (5): 0 ≦c≦ 3.0; and (4) 0.5 ≦b+c≦ 6.0. (5)
84 . The method of producing a high strength and high toughness metal according to claim 81 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “c” atomic %, wherein “c” satisfies the following expressions (4) to (5): 0≦ c≦ 2.0; and (4) 0.5 ≦b+c≦ 6.0 (5)
85 . The method of producing a high strength and high toughness metal according to claim 81 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of Yb, Sm and Nd in a total amount of “c” atomic % and at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “d” atomic %, wherein “c” and of “d” satisfy the following expressions (4) to (6): 0≦ c≦ 3.0; (4) 0≦ d≦ 2.0; and (5) 0.5 ≦b+c+d≦ 6.0. (6)
86 . The method of producing a high strength and high toughness metal according to claim 69 ,
wherein said step for preparing a magnesium alloy is a step for producing a magnesium alloy casting product which contains Zn in an amount of “a” atomic % and at least one element selected from the group consisting of Gd, Tb, Tm and Lu in a total amount of “b” atomic %, wherein “a” and “b” satisfy the following expressions (1) to (3): 0.1 ≦a≦ 5.0; (1) 0.25 ≦b≦ 5.0; and (2) 0.5 a− 0.5 ≦b; and, (3) the method further comprising: a step for subjecting said magnesium alloy to a heat treatment between said step for preparing a magnesium alloy casting product and said step for producing a chip-shaped cutting product, or, between said step for producing a chip-shaped cutting product and said step for producing a plastically worked product.
87 . The method of producing a high strength and high toughness metal according to claim 69 ,
wherein said step for preparing a magnesium alloy is a step for producing a magnesium alloy casting product which contains Zn in an amount of “a” atomic % and at least one element selected from the group consisting of Gd, Tb, Tm and Lu in a total amount of “b” atomic %, wherein “a” and “b” satisfy the following expressions (1) to (3): 0.1 ≦a≦ 3.0; (1) 0.25≦ b≦ 5.0; and (2) 2 a− 3 ≦b; and, (3) the method further comprising: a step for subjecting said magnesium alloy to a heat treatment between said step for preparing a magnesium alloy casting product and said step for producing a chip-shaped cutting product, or, between said step for producing a chip-shaped cutting product and said step for producing a plastically worked product.
88 . The method of producing a high strength and high toughness metal according to claim 86 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of Yb, Sm and Nd in a total amount of “c” atomic %, wherein “c” satisfies the following expressions (4) to (5): 0≦ c≦ 3.0; and (4) 0.25 ≦b+c≦ 6.0. (5)
89 . The method of producing a high strength and high toughness metal according to claim 86 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “c” atomic %, wherein “c” satisfies the following expressions (4) to (5): 0≦ c≦ 2.0; and (4) 0.25 ≦b+c≦ 6.0 (5)
90 . The method of producing a high strength and high toughness metal according to claim 86 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of Yb, Sm and Nd in a total amount of “c” atomic % and at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “d” atomic %, wherein “c” and of “d” satisfy the following expressions (4) to (6): 0 ≦c≦ 3.0; (4) 0 ≦d≦ 2.0; and (5) 0.25≦ b+c+d≦ 6.0. (6)
91 . The method of producing a high strength and high toughness metal according to claim 81 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of Gd, Tb, Tm and Lu in a total amount of less than 3 atomic %.
92 . The method of producing a high strength and high toughness metal according to claim 86 ,
wherein said magnesium alloy contains at least one element selected from the group consisting of Gd, Tb, Tm and Lu in a total amount of less than 3 atomic %.
93 . The method of producing a high strength and high toughness metal according to any one of claims 59 , 60 , 71 , 72 , 81 and 86 ,
wherein said step for preparing a magnesium alloy is a step for producing a magnesium alloy casting product which contains at least one element selected from the group consisting of Yb, Sm and Nd in a total amount of “c” atomic %, wherein “c” satisfies the following expressions (4) to (5): 0 ≦c≦ 3.0; and (4) 0.1 ≦b+c≦ 6.0. (5)
94 . The method of producing a high strength and high toughness metal according to claim 59 ,
wherein said step for preparing a magnesium alloy is a step for producing a magnesium alloy casting product which contains at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “c” atomic %, wherein “c” satisfies the following expressions (4) to (5): 0≦ c≦ 2.0; and (4) 0.1 ≦b+c≦ 6.0 (5)
95 . The method of producing a high strength and high toughness metal according to claim 60 ,
wherein said step for preparing a magnesium alloy is a step for producing a magnesium alloy casting product which contains at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “c” atomic %, wherein “c” satisfies the following expressions (4) to (5): 0≦ c≦ 2.0; and (4) 0.1 ≦b+c≦ 6.0 (5)
96 . The method of producing a high strength and high toughness metal according to claim 71 ,
wherein said step for preparing a magnesium alloy is a step for producing a magnesium alloy casting product which contains at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “c” atomic %, wherein “c” satisfies the following expressions (4) to (5): 0 ≦c≦ 2.0; and (4) 0.1 ≦b+c≦ 6.0 (5)
97 . The method of producing a high strength and high toughness metal according to claim 72 ,
wherein said step for preparing a magnesium alloy is a step for producing a magnesium alloy casting product which contains at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “c” atomic %, wherein “c” satisfies the following expressions (4) to (5): 0≦ c≦ 2.0; and (4) 0.1 ≦b+c≦ 6.0 (5)
98 . The method of producing a high strength and high toughness metal according to claim 81 ,
wherein said step for preparing a magnesium alloy is a step for producing a magnesium alloy casting product which contains at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “c” atomic %, wherein “c” satisfies the following expressions (4) to (5): 0≦ c≦ 2.0; and (4) 0.1 ≦b+c≦ 6.0 (5)
99 . The method of producing a high strength and high toughness metal according to claim 86 ,
wherein said step for preparing a magnesium alloy is a step for producing a magnesium alloy casting product which contains at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “c” atomic %, wherein “c” satisfies the following expressions (4) to (5): 0 ≦c≦ 2.0; and (4) 0.1 ≦b+c≦ 6.0 (5)
100 . The method of producing a high strength and high toughness metal according to claim 81 ,
wherein said step for preparing a magnesium alloy is a step for producing a magnesium alloy casting product which contains at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “c” atomic %, wherein “c” satisfies the following expressions (4) to (5): 0≦ c≦ 2.0; and (4) 0.1 ≦b+c≦ 6.0 (5)
101 . The method of producing a high strength and high toughness metal according to claim 86 ,
wherein said step for preparing a magnesium alloy is a step for producing a magnesium alloy casting product which contains at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “c” atomic %, wherein “c” satisfies the following expressions (4) to (5): 0 ≦c≦ 2.0; and (4) 0.1 ≦b+c≦ 6.0 (5)
102 . The method of producing a high strength and high toughness metal according to claim 59 ,
wherein said step for preparing a magnesium alloy is a step for producing a magnesium alloy casting product which contains at least one element selected from the group consisting of Yb, Sm and Nd in a total amount of “c” atomic % and at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “d” atomic %, wherein “c” and of “d” satisfy the following expressions (4) to (6): 0≦ c≦ 3.0; (4) 0 ≦d≦ 2.0; and (5) 0.1 ≦b+c+d≦ 6.0. (6)
103 . The method of producing a high strength and high toughness metal according to claim 60 ,
wherein said step for preparing a magnesium alloy is a step for producing a magnesium alloy casting product which contains at least one element selected from the group consisting of Yb, Sm and Nd in a total amount of “c” atomic % and at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “d” atomic %, wherein “c” and of “d” satisfy the following expressions (4) to (6): 0≦ c≦ 3.0; (4) 0≦ d≦ 2.0; and (5) 0.1 ≦b+c+d≦ 6.0. (6)
104 . The method of producing a high strength and high toughness metal according to claim 71 ,
wherein said step for preparing a magnesium alloy is a step for producing a magnesium alloy casting product which contains at least one element selected from the group consisting of Yb, Sm and Nd in a total amount of “c” atomic % and at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “d” atomic %, wherein “c” and of “d” satisfy the following expressions (4) to (6): 0≦ c≦ 3.0; (4) 0 ≦d≦ 2.0; and (5) 0.1 ≦b+c+d≦ 6.0. (6)
105 . The method of producing a high strength and high toughness metal according to claim 72 ,
wherein said step for preparing a magnesium alloy is a step for producing a magnesium alloy casting product which contains at least one element selected from the group consisting of Yb, Sm and Nd in a total amount of “c” atomic % and at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “d” atomic %, wherein “c” and of “d” satisfy the following expressions (4) to (6): 0≦ c≦ 3.0; (4) 0≦ d≦ 2.0; and (5) 0.1 ≦b+c+d≦ 6.0. (6)
106 . The method of producing a high strength and high toughness metal according to claim 81 ,
wherein said step for preparing a magnesium alloy is a step for producing a magnesium alloy casting product which contains at least one element selected from the group consisting of Yb, Sm and Nd in a total amount of “c” atomic % and at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “d” atomic %, wherein “c” and of “d” satisfy the following expressions (4) to (6): 0≦ c≦ 3.0; (4) 0≦ d≦ 2.0; and (5) 0.1 ≦b+c+d≦ 6.0. (6)
107 . The method of producing a high strength and high toughness metal according to claim 86 ,
wherein said step for preparing a magnesium alloy is a step for producing a magnesium alloy casting product which contains at least one element selected from the group consisting of Yb, Sm and Nd in a total amount of “c” atomic % and at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “d” atomic %, wherein “c” and of “d” satisfy the following expressions (4) to (6): 0≦ c≦ 3.0; (4) 0 ≦d≦ 2.0; and (5) 0.1 ≦b+c+d≦ 6.0. (6)
108 . The method of producing a high strength and high toughness metal according to claim 81 ,
wherein said step for preparing a magnesium alloy is a step for producing a magnesium alloy casting product which contains at least one element selected from the group consisting of Yb, Tb, Sm and Nd in a total amount of “c” atomic % and at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “d” atomic %, wherein “c” and of “d” satisfy the following expressions (4) to (6): 0≦ c≦ 3.0; (4) 0≦ d≦ 2.0; and (5) 0.1 ≦b+c+d≦ 6.0. (6)
109 . The method of producing a high strength and high toughness metal according to claim 86 ,
wherein said step for preparing a magnesium alloy is a step for producing a magnesium alloy casting product which contains at least one element selected from the group consisting of Yb, Tb, Sm and Nd in a total amount of “c” atomic % and at least one element selected from the group consisting of La, Ce, Pr, Eu and Mm in a total amount of “d” atomic %, wherein “c” and of “d” satisfy the following expressions (4) to (6): 0≦ c≦ 3.0; (4) 0 ≦d≦ 2.0; and (5) 0.1 ≦b+c+d≦ 6.0. (6)
110 . The method of producing a high strength and high toughness metal according to claim 59 ,
wherein said step for preparing a magnesium alloy is a step for producing a magnesium alloy casting product which contains at least one element selected from the group consisting of Al, Th, Ca, Si, Mn, Zr, Ti, Hf, Nb, Ag, Sr, Sc, B and C in a total amount of larger than 0 atomic % to 2.5 atomic % or less.
111 . The method of producing a high strength and high toughness metal according to claim 60 ,
wherein said step for preparing a magnesium alloy is a step for producing a magnesium alloy casting product which contains at least one element selected from the group consisting of Al, Th, Ca, Si, Mn, Zr, Ti, Hf, Nb, Ag, Sr, Sc, B and C in a total amount of larger than 0 atomic % to 2.5 atomic % or less.
112 . The method of producing a high strength and high toughness metal according to claim 71 ,
wherein said step for preparing a magnesium alloy is a step for producing a magnesium alloy casting product which contains at least one element selected from the group consisting of Al, Th, Ca, Si, Mn, Zr, Ti, Hf, Nb, Ag, Sr, Sc, B and C in a total amount of larger than 0 atomic % to 2.5 atomic % or less.
113 . The method of producing a high strength and high toughness metal according to claim 72 ,
wherein said step for preparing a magnesium alloy is a step for producing a magnesium alloy casting product which contains at least one element selected from the group consisting of Al, Th, Ca, Si, Mn, Zr, Ti, Hf, Nb, Ag, Sr, Sc, B and C in a total amount of larger than 0 atomic % to 2.5 atomic % or less.
114 . The method of producing a high strength and high toughness metal according to claim 81 ,
wherein said step for preparing a magnesium alloy is a step for producing a magnesium alloy casting product which contains at least one element selected from the group consisting of Al, Th, Ca, Si, Mn, Zr, Ti, Hf, Nb, Ag, Sr, Sc, Band C in a total amount of larger than 0 atomic % to 2.5 atomic % or less.
115 . The method of producing a high strength and high toughness metal according to claim 86 ,
wherein said step for preparing a magnesium alloy is a step for producing a magnesium alloy casting product which contains at least one element selected from the group consisting of Al, Th, Ca, Si, Mn, Zr, Ti, Hf, Nb, Ag, Sr, Sc, B and C in a total amount of larger than 0 atomic % to 2.5 atomic % or less.
116 . The method of producing a high strength and high toughness metal according to claim 81 ,
wherein said step for subjecting a magnesium alloy to a heat treatment is a step for subjecting said magnesium alloy to a heat treatment at temperatures of 300° C. to 550° C. for 10 minutes or more to shorter than 24 hours.
117 . The method of producing a high strength and high toughness metal according to claim 86 ,
wherein said step for subjecting a magnesium alloy to a heat treatment is a step for subjecting said magnesium alloy to a heat treatment at temperatures of 300° C. to 550° C. for 10 minutes or more to shorter than 24 hours.
118 . The method of producing a high strength and high toughness metal according to claim 59 ,
wherein said step for producing a magnesium alloy casting product comprises: a step for refining a mineral ore containing rare-earth elements to prepare a rare-earth alloy containing plural rare-earth elements; the rare-earth alloy is used as a part of starting material for casting to produce said magnesium alloy which contains the rare-earth elements in a total amount of 6.0 atomic % or less.
119 . The method of producing a high strength and high toughness metal according to claim 60 ,
wherein said step for producing a magnesium alloy casting product comprises: a step for refining a mineral ore containing rare-earth elements to prepare a rare-earth alloy containing plural rare-earth elements; the rare-earth alloy is used as a part of starting material for casting to produce said magnesium alloy which contains the rare-earth elements in a total amount of 6.0 atomic % or less.
120 . The method of producing a high strength and high toughness metal according to claim 71 ,
wherein said step for producing a magnesium alloy casting product comprises: a step for refining a mineral ore containing rare-earth elements to prepare a rare-earth alloy containing plural rare-earth elements; the rare-earth alloy is used as a part of starting material for casting to produce said magnesium alloy which contains the rare-earth elements in a total amount of 6.0 atomic % or less.
121 . The method of producing a high strength and high toughness metal according to claim 72 ,
wherein said step for producing a magnesium alloy casting product comprises: a step for refining a mineral ore containing rare-earth elements to prepare a rare-earth alloy containing plural rare-earth elements; the rare-earth alloy is used as a part of starting material for casting to produce said magnesium alloy which contains the rare-earth elements in a total amount of 6.0 atomic % or less.
122 . The method of producing a high strength and high toughness metal according to claim 81 ,
wherein said step for producing a magnesium alloy casting product comprises: a step for refining a mineral ore containing rare-earth elements to prepare a rare-earth alloy containing plural rare-earth elements; the rare-earth alloy is used as a part of starting material for casting to produce said magnesium alloy which contains the rare-earth elements in a total amount of 6.0 atomic % or less.
123 . The method of producing a high strength and high toughness metal according to claim 86 ,
wherein said step for producing a magnesium alloy casting product comprises: a step for refining a mineral ore containing rare-earth elements to prepare a rare-earth alloy containing plural rare-earth elements; the rare-earth alloy is used as a part of starting material for casting to produce said magnesium alloy which contains the rare-earth elements in a total amount of 6.0 atomic % or less.
124 . The method of producing a high strength and high toughness metal according to claim 57 ,
wherein said magnesium alloy before subjecting to said plastic working has a grain size of 100 nm to 500 μm.
125 . The method of producing a high strength and high toughness metal according to claim 69 ,
wherein said magnesium alloy before subjecting to said plastic working has a grain size of 100 nm to 500 μm.
126 . The method of producing a high strength and high toughness metal according to claim 57 ,
wherein said magnesium alloy after subjecting to said plastic working has an hcp-Mg phase having a dislocation density one-digit larger than a long-period stacking ordered structure phase.
127 . The method of producing a high strength and high toughness metal according to claim 69 ,
wherein said magnesium alloy after subjecting to said plastic working has an hcp-Mg phase having a dislocation density one-digit larger than a long-period stacking ordered structure phase.
128 . The method of producing a high strength and high toughness metal according to claim 57 ,
wherein said magnesium alloy is plastically worked at 250° C. or higher.
129 . The method of producing a high strength and high toughness metal according to claim 69 ,
wherein said magnesium alloy is plastically worked at 250° C. or higher.
130 . The method of producing a high strength and high toughness metal according to claim 57 ,
wherein said plastic working is carried out by at least one process in rolling, extrusion, ECAE, drawing, forging, cyclic working of these workings and FSW.
131 . The method of producing a high strength and high toughness metal according to claim 69 ,
wherein said plastic working is carried out by at least one process in rolling, extrusion, ECAE, drawing, forging, cyclic working of these workings and FSW.
132 . A method of producing a high strength and high toughness metal,
wherein a mineral ore containing rare-earth elements is refined to prepare a rare-earth alloy containing plural rare-earth elements; the rare-earth alloy is used as a part of starting material and made into liquid having a composition of general formula of Mg (100-x-y) Y x Zn y (1<x<5, 0.3<y<6; x and y represent atomic %); said liquid is rapidly solidified into powder, thin band or thin wire; and said powder, thin band or thin wire is solidified so as to be applied with shear.
133 . The method of producing a high strength and high toughness metal according to claim 118 ,
wherein said rare-earth alloy contains at least one element selected from the group consisting of Y, Gd, Tb, Dy, Ho, Er, Tm and Lu in a total amount of 50 atomic % or more and at least one rare-earth element other than Y, Gd, Tb, Dy, Ho, Er, Tm and Lu in a total amount of less than 50 atomic %.
134 . The method of producing a high strength and high toughness metal according to claim 132 ,
wherein said rare-earth alloy contains at least one element selected from the group consisting of Y, Gd, Tb, Dy, Ho, Er, Tm and Lu in a total amount of 50 atomic % or more and at least one rare-earth element other than Y, Gd, Tb, Dy, Ho, Er, Tm and Lu in a total amount of less than 50 atomic %.
135 . The high strength and high toughness metal according to any one of claims 1 , 2 , 4 and 5 ,
wherein said long-period stacking ordered structure phase has a density modulation.Cited by (0)
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