Chemical softening composition for paper products

Abstract

A chemical softening composition includes an amide-substituted quaternary imidazolinium salt, a nonionic surfactant, and a polyhydroxy compound for use in treating cellulosic materials including papers, textiles and fabrics. The chemical softening composition can be applied to papermaking fibers during a papermaking process to provide a softened paper web and product possessed of sufficient tensile strength for its regular employment. A chemical softening composition according to the invention can also be applied to fabric to soften the fabric, provide easier handling of the fabric, and also reduce the tendency of the fabric to generate and store static electricity.

1 . A softened paper product produced by a method comprising: 
 (a) providing a paper product; and    (b) contacting the paper product with a composition comprising: 
 i) an amide-substituted quaternary imidazolinium salt present in an amount from about 0.25% to about 20.00% by weight based upon the total weight of the composition;  
   ii) a nonionic surfactant in an amount between 20.00% and 90.00% based on the total weight of the composition; and    iii) a polyhydroxy compound having an average molecular weight which is any molecular weight in the range of 92 to 4000 in an amount from about 1.00% to about 10.00% by weight based on the total weight of the composition,    wherein the amide-substituted quaternary imidazolinium salt comprises a cation having a structure:                          wherein each R 1  is independently selected from the group consisting of: hydrogen and a hydrocarbyl group comprising any number of carbon atoms between 8 to 22 and wherein, R 2  is selected from the group consisting of: hydrogen, and any C 1  to C 12  hydrocarbyl group, including mixtures of cations thereof.    
   
   
       2 . The product according to  claim 1  wherein the nonionic surfactant comprises an ethylene oxide moiety.  
   
   
       3 . The product according to  claim 1  wherein the paper product is selected from the group consisting of: a paper towel, a tissue paper, a paper napkin, and a feminine hygiene product.  
   
   
       4 . The product according to  claim 1  wherein the amide-substituted quaternary imidazolinium salt is present in the amount from about 3.00% to about 15.00%.  
   
   
       5 . The product according to  claim 1  wherein the amide-substituted quaternary imidazolinium salt is present in the amount from about 5.00% to about 10.00%.  
   
   
       6 . The product according to  claim 1  wherein the non-ionic surfactant is polyethylene glycol dioleate, polyethylene glycol dilaurate, polypropylene glycol dioleate, polypropylene glycol dilaurate, polyethylene glycol monooleate, polyethylene glycol monolaurate, polypropylene glycol monooleate and polypropylene glycol monolaurate, and mixtures thereof.  
   
   
       7 . The product according to  claim 1  wherein the nonionic surfactant comprises about 40% by weight polyethylene glycol 400 dioleate and about 50% by weight polyethylene glycol 200 dilaurate.  
   
   
       8 . The product according to  claim 1  wherein the polyhydroxy compound is present in the amount from about 1.00% to about 5.00%.  
   
   
       9 . The product according to  claim 1  wherein the polyhydroxy compounds is glycerine and polyalkylene glycols.  
   
   
       10 . A softened fabric product produced by a method comprising: 
 (a) providing a fabric product; and    (b) contacting the fabric product with a composition comprising: 
 i) an amide-substituted quaternary imidazolinium salt present in an amount from about 0.25% to about 20.00% by weight based upon the total weight of the composition;  
 ii) a nonionic surfactant in an amount between 20.00% and 90.00% based on the total weight of the composition; and  
 iii) a polyhydroxy compound having an average molecular weight which is any molecular weight in the range of 92 to 4000 in an amount from about 1.00% to about 10.00% by weight based on the total weight of the composition,  
 wherein the amide-substituted quaternary imidazolinium salt comprises a cation having a structure:  
                     
 wherein each R 1  is independently selected from the group consisting of: hydrogen and a hydrocarbyl group comprising any number of carbon atoms between 8 to 22 and wherein, R 2  is selected from the group consisting of: hydrogen, and any C 1  to C 12  hydrocarbyl group, including mixtures of cations thereof.  
   
   
   
       11 . The product according to  claim 10  wherein the nonionic surfactant comprises an ethylene oxide moiety.  
   
   
       12 . The product according to  claim 10  wherein the amide-substituted quaternary imidazolinium salt is present in the amount from about 3.00% to about 15.00%.  
   
   
       13 . The product according to  claim 10  wherein the amide-substituted quaternary imidazolinium salt is present in the amount from about 5.00% to about 10.00%.  
   
   
       14 . The product according to  claim 10  wherein the non-ionic surfactant is polyethylene glycol dioleate, polyethylene glycol dilaurate, polypropylene glycol dioleate, polypropylene glycol dilaurate, polyethylene glycol monooleate, polyethylene glycol monolaurate, polypropylene glycol monooleate and polypropylene glycol monolaurate, and mixtures thereof.  
   
   
       15 . The product according to  claim 10  wherein the nonionic surfactant comprises about 40% by weight polyethylene glycol 400 dioleate and about 50% by weight polyethylene glycol 200 dilaurate.  
   
   
       16 . The product according to  claim 10  wherein the polyhydroxy compound is present in the amount from about 1.00% to about 5.00%.  
   
   
       17 . The product according to  claim 10  wherein the polyhydroxy compounds is glycerine and polyalkylene glycols.  
   
   
       18 . A process for softening a fabric product comprising: 
 (a) providing a fabric product; and    (b) contacting the fabric product with a composition comprising: 
 i) an amide-substituted quaternary imidazolinium salt present in an amount from about 0.25% to about 20.00% by weight based upon the total weight of the composition;  
 ii) a nonionic surfactant in an amount between 20.00% and 90.00% based on the total weight of the composition; and  
 iii) a polyhydroxy compound having an average molecular weight which is any molecular weight in the range of 92 to 4000 in an amount from about 1.00% to about 10.00% by weight based on the total weight of the composition,  
 wherein the amide-substituted quaternary imidazolinium salt comprises a cation having a structure:  
                     
 wherein each R 1  is independently selected from the group consisting of: hydrogen and a hydrocarbyl group comprising any number of carbon atoms between 8 to 22 and wherein, R 2  is selected from the group consisting of: hydrogen, and any C 1  to C 12  hydrocarbyl group, including mixtures of cations thereof.  
   
   
   
       19 . The process according to  claim 18  wherein the nonionic surfactant comprises an ethylene oxide moiety.  
   
   
       20 . The process according to  claim 18  wherein the amide-substituted quaternary imidazolinium salt is present in the amount from about 3.00% to about 15.00%.