Ultra low residual reflection, low stress lens coating

Abstract

A method is provided for coating optical lenses and other optical articles with anti-reflection (AR) coatings. The lenses have low reflectivity, provide a substantially white light reflection and have a low stress AR coating and are ideally suited for optical lenses made using a molding procedure which provides a low stress lens substrate. In one aspect the method uses special coating compositions with one being a high index of refraction composition and the other being a low index of refraction composition. In another aspect a method is also disclosed using an optical monitor in conjunction with a conventional vapor deposition apparatus whereby an optical reference lens is used and a particular light frequency of reflected light is measured and this measurement is then used to determine when the desired optical coating is achieved. In a still further aspect the method also preferably calculates the optical thickness of each layer using a specific ratio of blue to green to red colors in the reflected light. The stress of the AR coating is also controlled by adjusting the optical thickness for each layer, if necessary, to minimize the difference in the tensile stresses and compressive stresses between low index/high index layers.

1 .- 10 . (canceled)  
   
   
       11 . An optical article made by the method comprising the steps of: 
 supplying one or more optical lens and an optical reference lens:    positioning the lens and the optical reference lens in a vacuum deposition chamber in the same coating plane, the vacuum deposition chamber having an optical monitor communicating with the optical reference lens;    providing in the chamber at least one source of a high index of refraction AR coating composition and at least one low index of refraction AR coating composition:    applying a layer of the high index of refraction composition on the lens until the desired optical thickness coating is obtained as determined by the optical monitor;    applying a layer of the low index of refraction composition on the lens until the desired optical thickness coating is obtained as determined by the optical monitor; and    repeating the AR application steps until the desired AR coating is applied:    wherein the optical monitor comprises means for directing an on/off beam of light into the chamber at the optical reference lens, measuring the reflected light from the reference lens at a particular frequency and using this measurement to determine when the desired optical coating thickness is achieved.    
   
   
       12 . An optical article made by the method comprising the steps of: 
 supplying an optical lens;    positioning the lens in a vacuum chamber of a vacuum deposition apparatus;    providing in the vacuum chamber a source of at least one high index of refraction AR composition and at least low index of refraction AR composition wherein one of the high index materials comprises a mixture of cerium and titanium oxides and one of the low index materials comprises SiO 2 :    applying a layer of the high index material on the lens until the desired optical thickness coating is applied;    applying a layer of the low index material on the lens until the desired optical thickness coating is applied; and    repeating the application steps until the desired anti-reflection coating is applied.    
   
   
       13 .- 14 . (canceled)  
   
   
       15 . An optical article made by the method comprising the steps of: 
 supplying an optical lens:    positioning the lens in a vacuum chamber of a vacuum deposition apparatus:    providing in the vacuum chamber a source of at least one high index of    refraction AR composition and at least low index of refraction AR composition;    applying a layer of the high index material on the lens until the desired optical thickness coating is applied;    applying a layer of the low index material on the lens until the desired optical thickness coating is applied; and    repeating the application steps until the desired anti-reflection coating is applied;    with the proviso that the reflected light off the anti-reflection coating be controlled so that the ratio of blue light to green light to red light provides a substantially white reflected light.    
   
   
       16 .- 18 . (canceled)