Arrangement for Reducing Nitrogen Oxides in Exhaust Gases

Abstract

An arrangement and method for reducing the nitrogen oxide content in the exhaust gas of an internal combustion engine with the aid of ammonia and/or ammonia-releasing reduction agents, whereby ammonia and/or ammonia-containing reduction agent is added to the exhaust gas stream upstream of a catalyst combination composed of an SCR catalyst and a subsequent NH 3 -oxidation catalyst in such a way that a homogeneous mixture of exhaust gas and ammonia is present upstream of the SCR catalyst. To optimize the reaction or conversion of nitrogen oxides, disposed downstream of the combination of a first SCR catalyst and a first NH 3 -oxidation catalyst is at least one second catalyst having SCR activity in order in this way to reduce the nitrogen oxides formed at the first NH 3 -oxidation catalyst due to insufficient selectivity of the catalyst to nitrogen with not yet oxidized NH 3 .

1 . An arrangement for reducing the nitrogen oxide content in the exhaust gas of an internal combustion engine with the aid of ammonia and/or ammonia-releasing reduction agents, comprising:
 a catalyst combination composed of a first SCR catalyst ( 5 ,  5 ′,  5 ″,  5 ″′), an NH 3 -oxidation catalyst ( 6 ,  6 ′,  6 ″,  6 ″′) disposed downstream of said first SCR catalyst, and at least one second SCR catalyst ( 7 ,  7 ′,  7 ″,  7 ″′) disposed downstream of said NH 3 -oxidation catalyst; and   means for adding ammonia and/or ammonia-containing reduction agent to an exhaust gas stream upstream of said catalyst combination such that a mixture of exhaust gas and ammonia is present upstream of said first SCR catalyst ( 5 ,  5 ′,  5 ″,  5 ″′).   
   
   
       2 . An arrangement according to  claim 1 , wherein at least one second NH 3 -oxidation catalyst ( 8 ,  8 ′,  8 ″) is disposed downstream of said second SCR catalyst ( 7 ,  7 ′,  7 ″,  7 ″′). 
   
   
       3 . An arrangement according to  claim 2 , wherein at least one further SCR catalyst ( 9 ), or further SCR catalyst ( 9 ) and NH 3 -oxidation catalyst ( 10 ) in alternating sequence, are disposed downstream of said second NH 3 -oxidation catalyst ( 8 ′), and wherein such arrangement ends with an SCR catalyst or an NH 3 -oxidation catalyst. 
   
   
       4 . An arrangement according to  claim 1 , wherein the combinations of the respective SCR catalysts ( 5 ,  7  or  5 ′,  7 ′ or  5 ″,  7 ″,  9  or  5 ″′,  7 ″′) differ along a direction of flow of the exhaust gas. 
   
   
       5 . An arrangement according to  claim 1 , wherein the combinations of the respective NH 3 -oxidation catalysts ( 6 ′,  8  or  6 ″,  8 ′,  10  or  6 ″′,  8 ″) differ along a direction of flow of the exhaust gas. 
   
   
       6 . An arrangement according to  claim 1 , wherein a first combination of SCR catalyst ( 5 ,  5 ′,  5 ″,  5 ″′) and NH 3 -oxidation catalyst ( 6 ,  6 ′,  6 ″,  6 ″′) is optimized to selectivity by the selective active catalyst materials, and wherein subsequent further SCR catalysts ( 7 ,  7 ′,  7 ″,  7 ″′,  9 ) and NH 3 -oxidation catalysts ( 8 ,  8 ′,  8 ″,  10 ) are optimized to high conversion rates by the selected active catalyst materials. 
   
   
       7 . An arrangement according to  claim 1 , wherein at least a portion of the SCR catalysts ( 5 ,  5 ′,  5 ″,  5 ″′,  7 ,  7 ′,  7 ″,  7 ″′,  9 ) contain V 2 O 5  as active substituents. 
   
   
       8 . An arrangement according to  claim 1 , wherein at least a portion of the SCR catalysts ( 5 ,  5 ′,  5 ″,  5 ″′,  7 ,  7 ′,  7 ″,  7 ″′,  9 ) contain iron and/or copper and/or cobalt-containing zeolites. 
   
   
       9 . An arrangement according to  claim 8 , wherein the zeolites are at least one of the types ZSM-5, OSI, EPI, AEN, MFI, FAU and BEA. 
   
   
       10 . An arrangement according to  claim 1 , wherein the NH 3 -oxidation catalysts ( 6 ,  6 ′,  6 ″,  6 ″′,  8 ,  8 ′,  8 ″,  10 ) contain at least one of the group consisting of platinum, palladium, rhodium, iridium, and their oxides as active components. 
   
   
       11 . An arrangement according to  claim 1 , wherein at least one of the SCR catalysts ( 5 ,  5 ′,  5 ″,  5 ″′,  7 ,  7 ′,  7 ″,  7 ″′,  9 ) and the NH 3 -oxidation catalysts ( 6 ,  6 ′,  6 ″,  6 ″′,  8 ,  8 ′,  8 ″,  10 ) are solid catalysts or coated catalysts on metal or ceramic supports or substrates. 
   
   
       12 . An arrangement according to  claim 1 , wherein the SCR catalysts ( 5 ″′,  7 ″′) and the NH 3 -oxidation catalysts ( 6 ″′,  8 ″) are applied to a common support or substrate. 
   
   
       13 . A method of producing the catalyst arrangement of  claim 1 , wherein the various catalyst combinations are applied by immersing a support or substrate into various solutions containing the catalysts, are dried, and are subsequently calcined; or wherein the various catalyst combinations are produced by impregnating a catalyst layer already applied to a support or substrate or by impregnating a solid catalyst; or wherein the various catalyst combinations are produced by using metal foils as supports or substrates, prior to rolling the individual foils up, coating them by spraying, subjecting them to a finishing treatment that includes a drying process, and only then rolling them up to form a honeycomb body.