Lyocell Method Comprising an Adjustment of the Processing Duration Based on the Degree of Polymerization

Abstract

The invention relates to a method and a device for producing Lyocell fibres which are extruded from a cellulose solution of water, cellulose and tertiary amine oxide in a spinning head ( 25 ). The cellulose solution is obtained in a number of process steps directly from the cellulose ( 3, 4 ) or with the formation of a cellulose suspension. Since the degree of polymerisation decreases in the course of processing the cellulose through to its extrusion in the cellulose solution, with the processing of celluloses with a low degree of polymerisation there is the risk that the endless moulded bodies ( 2 ) extruded in the spinning head ( 25 ) exhibit defective quality. In order to also be able to process celluloses ( 3, 4 ) with a low degree of polymerisation without having to accept reduced quality, according to the invention, the residence time of the cellulose from its introduction into the device ( 1 ) through to the extrusion of the cellulose ( 3, 4 ) in the cellulose solution is set in dependence of the degree of polymerisation of the cellulose, of the cellulose suspension and/or of the cellulose solution.

1 . A method for producing Lyocell fibers comprising
 a cellulose with a predetermined degree of polymerization is introduced   producing a cellulose solution, or initially a cellulose suspension and from this then the cellulose solution, from the cellulose with the addition of a treatment medium;   extruding the cellulose solution to form endless molded bodies;   monitoring the degree of polymerization of the cellulose, the cellulose suspension, the cellulose solution or combination thereof; and   setting the residence time of the cellulose from its introduction through to its extrusion dependence of the measured degree of polymerization.   
   
   
       2 . The method according to  claim 1 , wherein the cellulose suspension is subjected to an enzymatic pretreatment. 
   
   
       3 . The method according to  claim 2 , wherein the duration of the enzymatic pretreatment is adjusted in dependence of the degree of polymerization of the introduced cellulose. 
   
   
       4 . The method according to  claim 3 , wherein the enzymatic pretreatment for a cellulose with a lower degree of polymerization is carried out over a shorter time than for a cellulose with a higher degree of polymerization. 
   
   
       5 . The method according to  claim 2 , wherein the enzymatic pretreatment is set between 20 minutes and 80 minutes. 
   
   
       6 . The method according to  claim 2 , wherein for the enzymatic pretreatment at least one cellulase enzyme complex is added to the cellulose suspension. 
   
   
       7 . The method according to  claim 1 , wherein the cellulose solution is conveyed through a heated pipe system for extrusion and that the conveying speed of the cellulose solution in the pipe system is set in dependence of the degree of polymerization. 
   
   
       8 . The method according to  claim 7 , wherein during the processing of a cellulose with a lower degree of polymerization in the cellulose solution the conveying speed of the cellulose solution is set higher than the conveying speed during the processing of a cellulose in the cellulose solution with a higher degree of polymerization. 
   
   
       9 . The method according to  claim 1 , wherein the residence duration of the cellulose from its introduction through to its extrusion in the cellulose solution is at most two hours. 
   
   
       10 . The method according to  claim 1 , wherein the residence time of the cellulose from its introduction through to its extrusion in the cellulose solution is at least five minutes. 
   
   
       11 . The method according to  claim 1 , wherein the conveying speed of the pump arrangement conveying the cellulose suspension, the cellulose solution or combination thereof is set in dependence of the degree of polymerization in the cellulose, the cellulose suspension, the cellulose solution or combination thereof. 
   
   
       12 . The method according to  claim 1 , wherein the degree of polymerization of the cellulose solution shortly before the extrusion is set to a DP value of at least 450 DP to 550 DP. 
   
   
       13 . The method according to  claim 1 , wherein the duration of an enzymatic pretreatment of the cellulose is set such that its DP value is at least 500 immediately after termination of the enzymatic pretreatment. 
   
   
       14 . The method according to  claim 1 , wherein the power of an agitating machine is monitored as a representative quantity for the degree of polymerization of the cellulose suspension. 
   
   
       15 . A device for the production of Lyocell fibers, comprising
 a mixing device, to which a cellulose can be fed and in which a cellulose solution directly or with the formation of a cellulose suspension can be processed with the addition of a treatment medium,   a spinning head through which the cellulose solution can be extruded to form endless molded bodies,   a conveying device through which the cellulose suspension cellulose solution or combination thereof can be conveyed from the mixing device to the spinning head,   a monitoring device, through which a degree of polymerization of the cellulose, of the cellulose suspension, of the cellulose solution or combination thereof can be monitored during the operation of the device, and   a control device, through which the processing duration from the introduction of the cellulose through to the extrusion in the spinning head can be set in dependence of the measured degree of polymerization.   
   
   
       16 . The device according to  claim 15 , wherein the conveying capacity of the conveying device is designed to be controlled by the control unit in dependence of the degree of polymerization. 
   
   
       17 . The device according to  claim 15 , wherein a sensor is provided through which the power of an agitating machine can be monitored.