US2008113117A1PendingUtilityA1

Light diffusing films, methods of making the same, and articles using the same

42
Assignee: COENJARTS CHRISTOPHER APriority: May 20, 2005Filed: Nov 7, 2007Published: May 15, 2008
Est. expiryMay 20, 2025(expired)· nominal 20-yr term from priority
G02B 5/02C08J 5/18C09K 2323/035G02B 5/0278C08L 63/00C09K 2323/00C08J 2369/00C08K 5/13C08L 33/04C08K 5/524C08K 3/22C08K 3/24Y10T428/25Y10T428/254C08K 5/005Y10T428/26C08L 69/00C08L 83/04G02B 5/0242C08L 2205/00C08L 25/14C09K 2323/03C08K 3/26
42
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Claims

Abstract

Disclosed herein are light diffusing films, methods of making the same and articles using the same. In one embodiment, a method of making a light-diffusing film comprises: mixing about 90 wt. % to about 99.999 wt. % of a powdered polycarbonate and about 0.001 wt. % to about 3 wt. % light-diffusing particles to form a mixture, wherein weight percents are based on a total weight of the light-diffusing film; melting the mixture to form a melt; and extruding the melt in the form of a sheet to form the light-diffusing film. The light-diffusing film comprises a hiding power of about 0 to 0.5 that is mathematically described by the following equation: Hiding   power   ( % ) =  1 - ∑ i = 1 n - 1  L i  ( on ) ∑ j = 1 n - 1  L j  ( off )  × 100 wherein: L i (on) is luminance above i th cold cathode fluorescent lamp, L j (off) is luminance at a midpoint between cold cathode fluorescent lamp j and cold cathode fluorescent lamp j+1, and n equals number of CCFL lamps.

Claims

exact text as granted — not AI-modified
1 . A method of making a light-diffusing film comprising:
 mixing about 90 wt. % to about 99.999 wt. % of a powdered polycarbonate and about 0.001 wt. % to about 3 wt. % light-diffusing particles to form a mixture, wherein weight percents are based on a total weight of the light-diffusing film;   melting the mixture to form a melt; and   extruding the melt in the form of a sheet to form the light-diffusing film;   wherein the light-diffusing film comprises a hiding power of about 0 to 0.5 that is mathematically described by the following equation:   
       
         
           
             
               
                 Hiding 
                  
                 
                     
                 
                  
                 power 
                  
                 
                     
                 
                  
                 
                   ( 
                   % 
                   ) 
                 
               
               = 
               
                 
                    
                   
                     1 
                     - 
                     
                       
                         
                           ∑ 
                           
                             i 
                             = 
                             1 
                           
                           
                             n 
                             - 
                             1 
                           
                         
                          
                         
                           
                             L 
                             i 
                           
                            
                           
                             ( 
                             on 
                             ) 
                           
                         
                       
                       
                         
                           ∑ 
                           
                             j 
                             = 
                             1 
                           
                           
                             n 
                             - 
                             1 
                           
                         
                          
                         
                           
                             L 
                             j 
                           
                            
                           
                             ( 
                             off 
                             ) 
                           
                         
                       
                     
                   
                    
                 
                 × 
                 100 
               
             
           
         
       
       wherein: L i (on) is luminance above i th  cold cathode fluorescent lamp, L j (off) is luminance at a midpoint between cold cathode fluorescent lamp j and cold cathode fluorescent lamp j+1, and n equals number of CCFL lamps; and
 wherein the light-diffusing film comprises a 13 points average luminance that is greater than a polycarbonate film 13 points average luminance, as determined by a 13 points test using a Topcon BM-7 instrument, wherein at the polycarbonate film comprises about 3.5 wt % acrylate particles based on a total weight of the polycarbonate film, and the polycarbonate film has a thickness of 2 millimeters and a transmission of 50.4% as determined in accordance with ASTM D1003-00 and as measured with instrument Macbeth 7000A, D65 light source illuminant, 100 observer. 
 
     
     
         2 . A method of making a light-diffusing film comprising:
 mixing a powdered polycarbonate and light-diffusing particles to form a mixture;   melting the mixture to form a melt; and   extruding the melt in the form of a sheet to form the light-diffusing film;   wherein the light-diffusing film comprises a light transmission of about 45% to about 65% as measured according to ASTM D1003-00;   wherein the light-diffusing film comprises a hiding power of about 0 to 0.5 that is mathematically described by the following equation:   
       
         
           
             
               
                 Hiding 
                  
                 
                     
                 
                  
                 power 
                  
                 
                     
                 
                  
                 
                   ( 
                   % 
                   ) 
                 
               
               = 
               
                 
                    
                   
                     1 
                     - 
                     
                       
                         
                           ∑ 
                           
                             i 
                             = 
                             1 
                           
                           
                             n 
                             - 
                             1 
                           
                         
                          
                         
                           
                             L 
                             i 
                           
                            
                           
                             ( 
                             on 
                             ) 
                           
                         
                       
                       
                         
                           ∑ 
                           
                             j 
                             = 
                             1 
                           
                           
                             n 
                             - 
                             1 
                           
                         
                          
                         
                           
                             L 
                             j 
                           
                            
                           
                             ( 
                             off 
                             ) 
                           
                         
                       
                     
                   
                    
                 
                 × 
                 100 
               
             
           
         
       
       wherein: L i (on) is luminance above i th  cold cathode fluorescent lamp, L j (off) is luminance at a midpoint between cold cathode fluorescent lamp j and cold cathode fluorescent lamp j+1, and n equals number of CCFL lamps; and
 wherein the light-diffusing film comprises a 13 points average luminance that is greater than a polycarbonate film 13 points average luminance, as determined by a 13 points test using a Topcon BM-7 instrument, wherein at the polycarbonate film comprises about 3.5 wt % acrylate particles based on a total weight of the polycarbonate film, and the polycarbonate film has a thickness of 2 millimeters and a transmission of 50.4% as determined in accordance with ASTM D1003-00 and as measured with instrument Macbeth 7000A, D65 light source illuminant, 100 observer. 
 
     
     
         3 . The method of  claim 2 , wherein the polycarbonate comprises a yellowness index of about 0.8 to about 1.5 as measured in accordance with ASTM E313-73 (D1925). 
     
     
         4 . The method of  claim 3 , wherein the yellowness index is about 0.8 to about 1.3. 
     
     
         5 - 18 . (canceled)

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