Novel whitening agents for cellulosic substrates

Abstract

This invention relates to novel whitening agents for cellulosic substrates. The whitening agents are comprised of at least two components: at least one chromophore component and at least one polymeric component. Suitable chromophore components generally fluoresce blue, red, violet, or purple color when exposed to ultraviolet light, or they may absorb light to reflect these same shades. The whitening agents are further characterized by having a dispersion component value of the Hansen Solubility Parameter of less than or equal to about 17 MPa 0.5 . This invention also relates to laundry care compositions including but not limited to liquid and/or powder laundry detergent formulations and rinse added fabric softening (RAFS) compositions that comprise such whitening agents.

1 . A laundry care composition comprising a laundry care ingredient and a whitening agent, said whitening agent comprising:
 (a) at least one chromophore component that comprises a thiophene colorant, and   (b) at least one polymeric component;   wherein the whitening agent is characterized by the following structure:   
       
         
           
           
               
               
           
         
       
       Wherein R 1  and R 2  can independently be selected from:
 a) [(CH 2 CR′HO) x (CH 2 CR″HO) y H]
 wherein R′ is selected from the group consisting of H, CH 3 , CH 2 O(CH 2 CH 2 O) z H, and mixtures thereof; wherein R″ is selected from the group consisting of H, CH 2 O(CH 2 CH 2 O) z H, and mixtures thereof; wherein x+y≦5; wherein y≧1; and wherein z=0 to 5; 
 
 b) R 1 =alkyl, aryl or aryl alkyl and R 2 =[(CH 2 CR′HO) x (CH 2 CR″HO) y H]
 wherein R′ is selected from the group consisting of H, CH 3 , CH 2 O(CH 2 CH 2 O) z H, and mixtures thereof; wherein R″ is selected from the group consisting of H, CH 2 O(CH 2 CH 2 O) z H, and mixtures thereof; wherein x+y≦10; wherein y≧1; and wherein z=0 to 5; 
 
 c) R 1 =[CH 2 CH 2 (OR 3 )CH 2 OR 4 ] and R 2 =[CH 2 CH 2 (OR 3 )CH 2 OR 4 ]
 wherein R 3  is selected from the group consisting of H, (CH 2 CH 2 O) z H, and mixtures thereof; and wherein z=0 to 10; 
 wherein R 4  is selected from the group consisting of (C 1 -C 16 )alkyl, aryl groups, and mixtures thereof; and 
 
 d) wherein R1 and R2 can independently be selected from the amino addition product of styrene oxide, glycidyl methyl ether, isobutyl glycidyl ether, isopropylglycidyl ether, t-butyl glycidyl ether, 2-ethylhexylgycidyl ether, and glycidylhexadecyl ether, followed by the addition of from 1 to 10 alkylene oxide units. 
 
     
     
         2 . The laundry care composition of  claim 1 , wherein the whitening agent comprises a polyoxyalkylene chain having from 2 to about 20 repeating units. 
     
     
         3 . The laundry care composition of  claim 1 , wherein the whitening agent comprises at least two hydroxyl groups. 
     
     
         4 . The laundry care composition of  claim 3 , wherein the hydroxyl groups are primary hydroxyl moieties. 
     
     
         5 . The laundry care composition of  claim 1 , wherein the whitening agent comprises an alkoxylated thiophene polymeric colorant. 
     
     
         6 . The laundry care composition of  claim 1 , wherein the whitening agent possesses a dispersion component value of the Hansen Solubility Parameter of less than or equal to about 17 MPa 0.5 . 
     
     
         7 . The laundry care composition of  claim 6 , wherein the whitening agent possesses a dispersion component value of the Hansen Solubility Parameter from about 12 to about 17 MPa 0.5 . 
     
     
         8 . The laundry care composition of  claim 1 , wherein the whitening agent's chromophore exhibits an absorbance spectrum in water of from about 520 nanometers to about 640 nanometers. 
     
     
         9 . The laundry care composition of  claim 1 , wherein the whitening agent's chromophore exhibits an emission spectrum in water of from about 400 nanometers to about 480 nanometers. 
     
     
         10 . A laundry care composition comprising a laundry care ingredient and a whitening agent, said whitening agent comprising:
 (a) at least one chromophore component that comprises a thiophene or triphenylmethane colorant, and   (b) at least one polymeric component; wherein the whitening agent possesses a dispersion component value of the Hansen Solubility Parameter of less than or equal to about 17 MPa 0.5 .   
     
     
         11 . The laundry care composition of  claim 10 , wherein the whitening agent possesses a dispersion component value of the Hansen Solubility Parameter from about 12 to about 17 MPa 0.5 . 
     
     
         12 . The laundry care composition of  claim 10 , wherein the whitening agent comprises a polyoxyalkylene chain having from 2 to about 20 repeating units. 
     
     
         13 . The laundry care composition of  claim 10 , wherein the whitening agent comprises at least two hydroxyl groups. 
     
     
         14 . The laundry care composition of  claim 13 , wherein the hydroxyl groups are primary hydroxyl moieties. 
     
     
         15 . The laundry care composition of  claim 10 , wherein the whitening agent comprises an alkoxylated triphenylmethane polymeric colorant. 
     
     
         16 . The laundry care composition of  claim 10 , wherein the whitening agent comprises an alkoxylated thiophene polymeric colorant. 
     
     
         17 . The laundry care composition of  claim 10 , wherein the whitening agent's chromophore exhibits an absorbance spectrum in water of from about 520 nanometers to about 640 nanometers. 
     
     
         18 . The laundry care composition of  claim 10 , wherein the whitening agent's chromophore exhibits an emission spectrum in water of from about 400 nanometers to about 480 nanometers. 
     
     
         19 . A laundry care composition comprising a laundry care ingredient and a whitening agent, said whitening agent comprising:
 (a) at least one chromophore component that comprises a thiophene colorant, and   (b) at least one polymeric component;   wherein the whitening agent is characterized by the following structure:   
       
         
           
           
               
               
           
         
       
       wherein R′ is selected from the group consisting of H, CH 3 , CH 2 O(CH 2 CH 2 O) z H, and mixtures thereof; wherein R″ is selected from the group consisting of H, CH 2 O(CH 2 CH 2 O) z H, and mixtures thereof; wherein x+y≦5; wherein y≧1; and wherein z=0 to 5. 
     
     
         20 . The laundry care composition of  claim 19 , wherein the whitening agent comprises a polyoxyalkylene chain having from 2 to about 20 repeating units. 
     
     
         21 . The laundry care composition of  claim 2 , wherein the whitening agent comprises a polyoxyalkylene chain having from about 4 to about 6 repeating units.