Scorch-Retarding Polymer Composition

Abstract

The present invention relates to crosslinkable polymer composition, comprising an unsaturated polyolefin having a total amount of carbon-carbon double bonds/1000 carbon atoms of at least 0.1, at least one scorch retarder, and at least one crosslinking agent.

1 . A crosslinkable polymer composition, comprising
 (i) an unsaturated polyolefin having a total amount of carbon-carbon double bonds/1000 carbon atoms of at least 0.1,   (ii) at least one scorch retarder, and   (iii) at least one crosslinking agent.   
   
   
       2 . The polymer composition according to  claim 1 , wherein the unsaturated polyolefin has a total amount of carbon-carbon double bonds/1000 carbon atoms of at least 0.35. 
   
   
       3 . The polymer composition according to  claim 1 , wherein at least some of the carbon-carbon double bonds are vinyl groups. 
   
   
       4 . The polymer composition according to  claim 3 , wherein the unsaturated polyolefin has a total amount of vinyl groups/1000 carbon atoms of at least 0.04. 
   
   
       5 . The polymer composition according to  claim 1 , wherein the unsaturated polyolefin is prepared by copolymerizing an olefin monomer and at least one polyunsaturated comonomer. 
   
   
       6 . The polymer composition according to  claim 5 , wherein the unsaturated polyolefin has an amount of vinyl groups/1000 carbon atoms which originate from the polyunsaturated comonomer, of at least 0.03. 
   
   
       7 . The polymer composition according to  claim 5 , wherein at least one polyunsaturated comonomer is a diene. 
   
   
       8 . The polymer composition according to  claim 7 , wherein the diene is selected from 1,7-octadiene, 1,9-decadiene, 1,11-dodecadiene, 1,13-tetradecadiene, 7-methyl-1,6-octadiene, 9-methyl-1,8-decadiene, or mixtures thereof. 
   
   
       9 . The polymer composition according to  claim 7 , wherein the diene is selected from siloxanes having the following formula:
   CH 2 ═CH—[Si(CH 3 ) 2 —O] n —Si(CH 3 ) 2 —CH═CH 2 ,   
     wherein n=1 or higher. 
   
   
       10 . The polymer composition according to  claim 1 , wherein at least one crosslinking agent is a peroxide. 
   
   
       11 . The polymer composition according to  claim 5 , wherein the olefin monomer is ethylene. 
   
   
       12 . The polymer composition according to  claim 11 , wherein the unsaturated polyethylene is produced by high pressure radical polymerisation. 
   
   
       13 . The polymer composition according to  claim 5 , wherein the unsaturated polyolefin has an ash content of less than 0.030 wt.-%. 
   
   
       14 . The polymer composition according to  claim 1 , wherein the amount of scorch retarder is from 0.005 to 1 wt.-%, based on the weight of the polymer composition. 
   
   
       15 . The polymer composition according to  claim 1 , wherein the scorch retarder is selected from 2,4-diphenyl-4-methyl-1-pentene, substituted or unsubstituted diphenylethylene, quinone derivatives, hydroquinone derivatives, monofunctional vinyl containing esters and ethers, or mixtures thereof. 
   
   
       16 . A crosslinked polymer composition, prepared by treatment of the polymer composition according to  claim 1  under crosslinking conditions. 
   
   
       17 . The crosslinked polymer composition according to  claim 16 , wherein the percentage level of removable volatiles remaining in the crosslinked polymer composition is less than or equal to 0.5 wt % of the crosslinked polymer composition after a period of time which is at least 10% shorter compared to the period of time which is necessary to decrease the level of volatiles in a reference material to the same value, wherein the reference material is a crosslinked polymer composition prepared from an unsaturated polyolefin having a total amount of carbon-carbon double bonds/1000 carbon atoms of 0.37 and a crosslinking agent but without a scorch retarder. 
   
   
       18 . The crosslinked polymer composition according to  claim 16 , having a total weight change between 0-30 minutes at 175° C. of less than 1.12 wt.-% as measured according to HD632 A:1 1998, part 2 on a plaque having a thickness of 1.8 mm. 
   
   
       19 . A process for the preparation of a crosslinked polymer composition, wherein the crosslinkable polymer composition according to  claim 1  is provided, followed by treatment of the polymer composition under crosslinking conditions. 
   
   
       20 . The process according, to  claim 19 , wherein the crosslinkable polymer composition is subjected to a temperature sufficient to effect at least partial crosslinking. 
   
   
       21 . A multilayered article, having at least one layer comprising the crosslinkable polymer composition according to  claim 1 . 
   
   
       22 . The multilayered article according to  claim 21 , wherein the article is a power cable. 
   
   
       23 . A crosslinked multilayered article, having at least one layer comprising the crosslinked polymer composition according to  claim 16 . 
   
   
       24 . The crosslinked multilayered article according to  claim 23 , wherein the article is a power cable. 
   
   
       25 . A process for the production of a multilayered article, wherein the crosslinkable polymer composition according to  claim 1  is applied as one or more layers onto a substrate by extrusion. 
   
   
       26 . The process according to  claim 25 , wherein extrusion is effected at a temperature satisfying the following relationship: 
     ti (19517/(273.15 +T ))-1 n t≦ 43.55 
     wherein
 T: extrusion temperature in ° C., and 
 t: time in minutes it takes at the extrusion temperature T from the start of the torque measurement to reach an increase in torque of 1 dNm from the minimum value in the torque curve. 
 
   
   
       27 . The process according to  claim 25  wherein the unsaturated polyolefin, the crosslinking agent and the scorch retarder are blended in a single step, followed by feeding the obtained mixture into the extruder. 
   
   
       28 . The process according to  claim 25 , wherein the crosslinkable polymer composition is prepared by blending the unsaturated polyolefin with the scorch retarder first, followed by blending the obtained mixture with the crosslinking agent, and feeding the final mixture into the extruder. 
   
   
       29 . The process according to  claim 25 , wherein a melt of the unsaturated polyolefin is provided in the extruder, followed by adding the scorch retarder and the crosslinking agent in the hopper or to the melt, either simultaneously or in subsequent steps. 
   
   
       30 . The process according to  claim 25 , wherein the multilayered article is a power cable and the crosslinkable polymer composition is applied onto the metallic conductor and/or at least one coating layer thereof. 
   
   
       31 . The process according to  claim 25 , wherein the crosslinkable polymer composition is treated under crosslinking conditions. 
   
   
       32 . The process according to  claim 25 , wherein after the crosslinking step a degassing step is carried out to remove volatile products. 
   
   
       33 . A process for producing the crosslinkable composition of  claim 1  which includes the use of a scorch retarder for extrusion of an unsaturated polyolefin having a total amount of carbon-carbon double bonds/1000 carbon atoms of at least 0.1.