Epoxy-Functional Polysiloxanes, Silicone Composition, and Coated

Abstract

Epoxy-functional polysiloxanes containing epoxy groups and hydrocarbyl groups free of aliphatic unsaturation, a silicone composition containing a polysiloxane selected from the aforementioned epoxy-functional polysiloxanes, a cured polysiloxane prepared by exposing the silicone composition to ultraviolet radiation, a coated optical fiber containing a cured polysiloxane, and a method of preparing a coated optical fiber.

1 . An epoxy-functional polysiloxane having the formula:
   R 7 R 1   2 SiO(R 1   2 SiO) m (R 1 R 4 SiO) n (R 1 R 6 SiO) p SiR 1   2 R 7      
     wherein R 1  is C 1  to C 3  alkyl or phenyl; R 4  is —CH 2 —CHR 2 R 3 , wherein R 2  is C 2  to C 10  hydrocarbyl free of aliphatic unsaturation and R 3  is R 1  or H; R 6  is —CH 2 —CHR 3 R 5 , wherein R 5  is an epoxy group; R 7  is R 1 , R 4 , or R 6 ; m is from 0.1 to 0.9; n is from 0.1 to 0.5; p is from 0.1 to 0.6; and m+n+p=1. 
   
   
       2 . An epoxy-functional polysiloxane having the formula:
   (R 7 R 1   2 SiO 1/2 ) v (R 1   2 SiO 2/2 ) w (R 4 SiO 3/2 ) x (R 6 SiO 3/2 ) y (SiO 4/2 ) z      
     wherein R 1  is C 1  to C 3  alkyl or phenyl; R 4  is —CH 2 —CHR 2 R 3 , wherein R 2  is C 2  to C 10  hydrocarbyl free of aliphatic unsaturation and R 3  is R 1  or H; R 6  is —CH 2 —CHR 3 R 5 , wherein R 5  is an epoxy group; R 7  is R 1 , R 4 , or R 6 ; v is from 0 to 0.5; w is from 0.1 to 0.9; x is from 0.1 to 0.7; y is from 0.1 to 0.5; z is from 0 to 0.5; and v+w+x+y+z=1. 
   
   
       3 . A silicone composition, comprising:
 (A) a polysiloxane selected from (i) at least one epoxy-functional polysiloxane having the formula R 7 R 1   2 SiO(R 1   2 SiO) m (R 1 R 4 SiO) n (R 1 R 6 SiO) p SiR 1   2 R 7  (I), (ii) at least one epoxy-functional polysiloxane having the formula (R 7 R 1   2 SiO 1/2 ) v (R 1   2 SiO 2/2 ) w (R 4 SiO 3/2 ) x (R 6 SiO 3/2 ) y (SiO 4/2 ) z  (II), and (iii) a mixture comprising (i) and (ii), wherein R 1  is C 1  to C 3  alkyl or phenyl, R 4  is —CH 2 —CHR 2 R 3 , wherein R 2  is C 2  to C 10  hydrocarbyl free of aliphatic unsaturation and R 3  is R 1  or H, R 6  is —CH 2 —CHR 3 R 5 , wherein R 5  is an epoxy group, R 7  is R 1 , R 4 , or R 6 , m is from 0.1 to 0.9, n is from 0.1 to 0.5, p is from 0.1 to 0.6, m+n+p=1, v is from 0 to 0.5, w is from 0.1 to 0.9, x is from 0.1 to 0.7, y is from 0.1 to 0.5, z is from 0 to 0.5, and v+w+x+y+z=1; and   (B) a cationic photoinitiator.   
   
   
       4 . A cured polysiloxane prepared by exposing the silicone composition according to  claim 3  to ultraviolet radiation. 
   
   
       5 . A coated optical fiber comprising:
 an optical fiber comprising a glass fiber core and a cladding surrounding the core, wherein the cladding has a refractive index less than the refractive index of the core; and   a silicone coating surrounding the optical fiber, wherein the coating comprises a cured polysiloxane prepared by applying the silicone composition of the present invention on the optical fiber to form a film and exposing the film to ultraviolet radiation.   
   
   
       6 . A method of preparing a coated optical fiber, the method comprising the steps of:
 applying the silicone composition of the instant invention on an optical fiber to form a film, wherein the optical fiber comprises a glass fiber core and a cladding surrounding the core and the cladding has a refractive index less than the refractive index of the core; and   exposing the film to ultraviolet radiation to form a silicone coating.   
   
   
       7 . The method according to  claim 6 , further comprising writing at least one Bragg grating in the glass fiber core.