Pneumatic Tire

Abstract

The present invention relates to a pneumatic tire having a component comprising at least one elastomer containing olefinic unsaturation; and compound of formula I wherein: R 1 , R 3 , R 4 , R 5 , R 6 , and R 8 are each independently hydrogen, alkyl, aryl, halogen, or substituted or unsubstituted oxygen, nitrogen or sulfur atoms; R 2 is hydrogen, alkyl, aryl, or is absent; R 7 is substituted or unsubstituted oxygen, nitrogen, sulfur, or halogen; R 9 , R 10 , R 11 and R 12 are each independently hydrogen, alkyl, aryl, halogen, nitro or substituted or unsubstituted oxygen, nitrogen or sulfur atoms; and X is oxygen, sulfur, or nitrogen.

1 . A pneumatic tire having a component comprising at least one elastomer containing olefinic unsaturation, and a compound of formula I 
     
       
         
         
             
             
         
       
       wherein: R 1 , R 3 , R 4 , R 5 , R 6 , and R 8  are each independently hydrogen, alkyl, aryl, halogen, or substituted or unsubstituted oxygen, nitrogen or sulfur atoms; 
       R 2  is hydrogen, alkyl, aryl, or is absent; 
       R 7  is substituted or unsubstituted oxygen, nitrogen, sulfur, or halogen; 
       R 9 , R 10 , R 11  and R 12  are each independently hydrogen, alkyl, aryl, halogen, nitro or substituted or unsubstituted oxygen, nitrogen or sulfur atoms; 
       and X is oxygen, sulfur, or nitrogen. 
     
   
   
       2 . The pneumatic tire of  claim 1 , wherein R 2  is absent, R 4 , R 5 , R 9 , R 10 , R 11  and R 12  are each hydrogen, X is oxygen, and the other substituents are selected from the group consisting of:
 R 1  and R 8  are each hydrogen, R 3  and R 6  are each n-hexyl and R 7  is benzyloxy;   R 1  and R 8  are each hydrogen, R 3  and R 6  are each n-hexyl and R 7  is ethoxy;   R 1  and R 8  are each hydrogen, R 3  and R 6  are each ethyl and R 7  is benzyloxy;   R 1  and R 8  are each hydrogen, R 3  and R 6  are each n-hexyl and R 7  is ethoxy;   R 1  and R 8  are each methyl, R 3  and R 6  are each hydrogen and R 7  is benzyloxy;   R 1  and R 8  are each methyl, R 3  and R 6  are each hydrogen and R 7  is 2-methoxyethoxy;   R 1  and R 8  are each hydrogen, R 3  and R 6  are each ethyl and R 7  is 3-methylbut-1-oxy;   R 1  and R 8  are each hydrogen, R 3  and R 6  are each ethyl and R 7  is 2-methylbenzyloxy;   R 1  and R 8  are each hydrogen, R 3  and R 6  are each ethyl and R 7  is 3-methylbenzyloxy;   R 1  and R 8  are each hydrogen, R 3  and R 6  are each benzyl and R 7  is benzyloxy;   R 1  and R 8  are each hydrogen, R 3  and R 6  are each propyl, and R 7  is benzyloxy; and   R 1  and R 8  are each hydrogen, R 3  and R 6  are each benzyl and R 7  is 3-methylbut-1-oxy.   
   
   
       3 . The pneumatic tire of  claim 1 , wherein R 2  is absent; R 4 , R 5 , R 6 , R 8 , R 9 , R 10 , R 11  and R 12  are each hydrogen; X is oxygen; and the other substituents are selected from the group consisting of:
 R 1  is hydrogen, R 3  is bromine and R 7  is phenylamino;   R 1  is hydrogen, R 3  is bromine and R 7  is N-ethyl-N-phenylamino;   R 1  is hydrogen, R 3  is bromine and R 7  is N-butyl-N-phenylamino;   R 1  is hydrogen, R 3  is bromine and R 7  is N-hexyl-N-phenylamino;   R 1  is hydrogen, R 3  is bromine and R 7  is N-benzyl-N-phenylamino;   R 1  is hydrogen, R 3  is bromine and R 7  is N,N-diphenylamino;   R 1  is methyl, R 3  is bromine and R 7  is N-hexyl-N-phenylamino;   R 1  is methyl, R 3  is bromine and R 7  is N-indolinyl; and   R 1  is methyl, R 3  is bromine and R 7  is N-hexadecyl-N-phenylamino.   
   
   
       4 . The pneumatic tire of  claim 1 , wherein R 1 , R 3 , R 4 , R 5 , R 6 , and R 8  are each hydrogen; X is nitrogen; and the other substituents are selected from the group consisting of:
 R 2  is phenyl, R 7  is phenylamino, and R 9 , R 10 , R 11  and R 12  are each hydrogen;   R 2  is 2-methylphenyl, R 7  is 2-methylphenylamino, and R 9 , R 10 , R 11  and R 12  are each hydrogen;   R 2  is 2-ethylphenyl, R 7  is 2-ethylphenylamino, and R 9 , R 10 , R 11  and R 12  are each hydrogen;   R 2  is 2,4,6-trimethylphenyl, R 7  is 2,4,6-trimethylphenylamino, and R 9 , R 10 , R 11  and R 12  are each hydrogen;   R 2  is 2-chlorophenyl, R 7  is 2-chlorophenylamino, and R 9 , R 10 , R 11  and R 12  are each hydrogen; and   R 2  is 2-methyl-4-octadecyloxyphenyl, R 7  is N-indolinyl, and R 9 , R 10 , R 11  and R 12  are each fluorine.   
   
   
       5 . The pneumatic tire of  claim 1  wherein the elastomer is selected from the group consisting of natural rubber (NR), epoxidized natural rubber (ENR), synthetic polyisoprene (IR), polychloroprene rubber (CR), polybutadiene (BR), styrene-butadiene rubber (SBR), isoprene-butadiene rubber (IBR), styrene-isoprene-butadiene rubber (SIBR), ethylene-propylene-diene rubber (EPDM), isobutylene-isoprene rubber (IIR, butyl rubber), isobutylene-isoprene rubber-chlorinated (CIIR, chlorobutyl rubber), isobutylene-isoprene rubber-brominated (BIIR, bromobutyl rubber), acrylonitrile-isoprene rubber (NIIR), acrylonitrile-butadiene rubber (NBR), urethane rubber (EU), and methysilicone rubbers (MQ, VMQ, PVMQ, FMQ). 
   
   
       6 . The pneumatic tire of  claim 1 , wherein the component is selected from the group consisting of a tire tread and sidewall component 
   
   
       7 . The pneumatic tire of  claim 1 , wherein the component is selected from the group consisting of a sidewall stripe or indicial marking.