All-solid-state cell

Abstract

An all-solid-state cell contains a combination of an electrode active material and a solid electrolyte, and has a plate-shaped fired solid electrolyte body of a ceramic containing a solid electrolyte, a first electrode layer (e.g. a positive electrode) integrally formed on one surface of the fired solid electrolyte body by mixing and firing an electrode active material and a solid electrolyte, and a second electrode layer (e.g. a negative electrode) integrally formed on the other surface of the fired solid electrolyte body by mixing and firing an electrode active material and a solid electrolyte. The solid electrolyte materials added to the first electrode layer and the second electrode layer comprise an amorphous polyanion compound.

1 . An all-solid-state cell comprising positive and negative electrode portions containing an electrode active material, an electrolyte portion containing a solid electrolyte, and positive and negative collector portions, wherein
 the electrode active material and the solid electrolyte contain the same polyanion,   one or both of the positive and negative electrode portions contain a mixture of the electrode active material and the solid electrolyte, and   the electrode portion is formed by mixing and firing the electrode active material and a solid electrolyte material comprising an amorphous polyanion compound.   
   
   
       2 . An all-solid-state cell according to  claim 1 , wherein the electrode active material and the solid electrolyte material satisfy an inequality:
   Ty>Tz   
     wherein Ty is a temperature at which a capacity of the electrode active material is lowered by a reaction between the electrode active material and the solid electrolyte material, and Tz is a temperature at which the solid electrolyte material is shrunk by firing. 
   
   
       3 . An all-solid-state cell according to  claim 2 , wherein Tz is a temperature at which the relative density of the solid electrolyte material is increased to 70% or more of the theoretical density thereof due to the shrinkage by firing. 
   
   
       4 . An all-solid-state cell according to  claim 1 , wherein the one or both of the positive and negative electrode portions are formed by firing under an applied pressure. 
   
   
       5 . An all-solid-state cell according to  claim 1 , wherein one or both of the positive and negative electrode portions are formed from a paste for printing by firing it under an inert atmosphere. 
   
   
       6 . An all-solid-state cell comprising positive and negative electrode portions containing an electrode active material, an electrolyte portion containing a solid electrolyte, and positive and negative collector portions, wherein
 the electrode active material and the solid electrolyte comprise a phosphate compound,   one or both of the positive and negative electrode portions contains a mixture of the electrode active material and the solid electrolyte, and   the electrode portion is formed by mixing and firing the electrode active material and a solid electrolyte material comprising an amorphous phosphate compound.   
   
   
       7 . An all-solid-state cell according to  claim 6 , wherein the electrode active material and the solid electrolyte material satisfy an inequality:
   Ty>Tz   
     wherein Ty is a temperature at which a capacity of the electrode active material is lowered by a reaction between the electrode active material and the solid electrolyte material, and Tz is a temperature at which the solid electrolyte material is shrunk by firing. 
   
   
       8 . An all-solid-state cell according to  claim 7 , wherein Tz is a temperature at which the relative density of the solid electrolyte material is increased to 70% or more of the theoretical density thereof due to the shrinkage by firing. 
   
   
       9 . An all-solid-state cell according to  claim 6 , wherein the solid electrolyte material comprising the phosphate compound is of Nasicon type after the firing. 
   
   
       10 . An all-solid-state cell according to  claim 9 , wherein the phosphate compound of the solid electrolyte material is LAGP Li 1+x Al x Ge 2−x (PO 4 ) 3  (0≦x≦1). 
   
   
       11 . An all-solid-state cell according to  claim 9 , wherein the phosphate compound of the solid electrolyte material is LATP Li 1+x Al x Ti 2−x (PO 4 ) 3  (0≦x≦1). 
   
   
       12 . An all-solid-state cell according to  claim 6 , wherein the electrode active material is a Nasicon type material comprising a phosphate compound. 
   
   
       13 . An all-solid-state cell according to  claim 12 , wherein the phosphate compound of the electrode active material is LVP Li m V 2 (PO 4 ) 3  (1≦m≦5). 
   
   
       14 . An all-solid-state cell according to  claim 6 , wherein the electrode active material for the positive electrode portion is an olivine type positive electrode active material comprising a phosphate compound. 
   
   
       15 . An all-solid-state cell according to  claim 14 , wherein the phosphate compound of the positive electrode active material is LNP Li n NiPO 4 , LCP Li n CoPO 4 , LMP Li n MnPO 4  or LFP Li n FePO 4  (0≦n≦1). 
   
   
       16 . An all-solid-state cell according to  claim 6 , wherein both the solid electrolyte material and the electrode active material are of Nasicon type. 
   
   
       17 . An all-solid-state cell according to  claim 6 , wherein both the solid electrolyte material and the electrode active material are of Nasicon type after the firing, the solid electrolyte material comprises LAGP Li 1+x Al x Ge 2−x (PO 4 ) 3  (0≦x≦1), and the electrode active material comprises LVP Li m V 2 (PO 4 ) 3  (1≦m≦5) in both the positive and negative electrode portions, whereby the all-solid-state cell has a symmetrical structure. 
   
   
       18 . An all-solid-state cell according to  claim 6 , wherein the solid electrolyte in the electrolyte portion comprises an amorphous polyanion compound. 
   
   
       19 . An all-solid-state cell according to  claim 6 , wherein the solid electrolyte in the electrolyte portion comprises an amorphous phosphate compound. 
   
   
       20 . An all-solid-state cell according to  claim 6 , wherein the one or both of the positive and negative electrode portions are formed by firing under an applied pressure. 
   
   
       21 . An all-solid-state cell according to  claim 6 , wherein one or both of the positive and negative electrode portions are formed from a paste for printing by firing it under an inert atmosphere.