US2009156671A1PendingUtilityA1

Deuterium-enriched oxybutynin

Assignee: PROTIA LLCPriority: Jun 1, 2007Filed: Feb 10, 2009Published: Jun 18, 2009
Est. expiryJun 1, 2027(~0.9 yrs left)· nominal 20-yr term from priority
A61P 13/10A61K 31/21
59
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Claims

Abstract

The present application describes deuterium-enriched oxybutynin, pharmaceutically acceptable salt forms thereof, and methods of treating using the same.

Claims

exact text as granted — not AI-modified
1 . A method for treating overactive bladder comprising: administering, to a patient in need thereof, a therapeutically effective amount of a deuterium-enriched compound of formula I or a pharmaceutically acceptable salt thereof: 
     
       
         
         
             
             
         
       
     
     wherein R 1 -R 31  are independently selected from H and D; and the abundance of deuterium in R 1 -R 31  is at least 3% provided that the compound is other than:
 (a) a compound where each of R 22 -R 31  is D or 
 (b) a compound where each of R 20 -R 21  is D. 
 
   
   
       2 . The method of  claim 1 , wherein the abundance of deuterium in R 1 -R 31  is selected from at least 3%, at least 6%, at least 13%, at least 19%, at least 26%, at least 32%, at least 39%, at least 45%, at least 52%, at least 58%, at least 65%, at least 71%, at least 77%, at least 84%, at least 90%, at least 97%, and 100%. 
   
   
       3 . The method of  claim 1 , wherein the abundance of deuterium in R 1  is 100%. 
   
   
       4 . The method of  claim 1 , wherein the abundance of deuterium in R 1 , R 20 -R 21 , and R 22 -R 31  is selected from at least 8%, at least 15%, at least 23%, at least 31%, at least 38%, at least 46%, at least 54%, at least 62%, at least 69%, at least 77%, at least 85%, at least 92%, and 100%. 
   
   
       5 . The method of  claim 1 , wherein the abundance of deuterium in R 20 -R 21  and R 22 -R 31  is selected from at least 8%, at least 17%, at least 25%, at least 33%, at least 42%, at least 50%, at least 58%, at least 67%, at least 75%, at least 83%, at least 92%, and 100%. 
   
   
       6 . The method of  claim 1 , wherein the abundance of deuterium in R 2 -R 6  is selected from at least 20%, at least 40%, at least 60%, at least 80%, and 100%. 
   
   
       7 . The method of  claim 1 , wherein the abundance of deuterium in R 7 -R 17  is selected from at least 9%, at least 18%, at least 27%, at least 36%, at least 45%, at least 56%, at least 64%, at least 73%, at least 82%, at least 91%, and 100%. 
   
   
       8 . The method of  claim 1 , wherein the compound is selected from compounds 1-8 of Table 1: 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
   
   
       9 . The method of  claim 1 , wherein the compound is selected from compounds 9-16 of Table 2: 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
   
   
       10 . A method for treating overactive bladder comprising: administering, to a patient in need thereof, a therapeutically effective amount of a compound of formula I or a pharmaceutically acceptable salt thereof: 
     
       
         
         
             
             
         
       
     
     wherein R 1 -R 31  are independently selected from H and D; and the abundance of deuterium in R 1 -R 31  is at least 3% provided that the compound is other than:
 (a) a compound where each of R 22 -R 31  is D or 
 (b) a compound where each of R 20 -R 21  is D. 
 
   
   
       11 . The method of  claim 10 , wherein the abundance of deuterium in R 1 -R 31  is selected from at least 3%, at least 6%, at least 13%, at least 19%, at least 26%, at least 32%, at least 39%, at least 45%, at least 52%, at least 58%, at least 65%, at least 71%, at least 77%, at least 84%, at least 90%, at least 97%, and 100%. 
   
   
       12 . The method of  claim 10 , wherein the abundance of deuterium in R 1  is 100%. 
   
   
       13 . The method  claim 10 , wherein the abundance of deuterium in R 1 , R 20 -R 21 , and R 22 -R 31  is selected from at least 8%, at least 15%, at least 23%, at least 31%, at least 38%, at least 46%, at least 54%, at least 62%, at least 69%, at least 77%, at least 85%, at least 92%, and 100%. 
   
   
       14 . The method of  claim 10 , wherein the abundance of deuterium in R 20 -R 21  and R 22 -R 31  is selected from at least 8%, at least 17%, at least 25%, at least 33%, at least 42%, at least 50%, at least 58%, at least 67%, at least 75%, at least 83%, at least 92%, and 100%. 
   
   
       15 . The method of  claim 10 , wherein the abundance of deuterium in R 2 -R 6  is selected from at least 20%, at least 40%, at least 60%, at least 80%, and 100%. 
   
   
       16 . The method of  claim 10 , wherein the abundance of deuterium in R 7 -R 17  is selected from at least 9%, at least 18%, at least 27%, at least 36%, at least 45%, at least 56%, at least 64%, at least 73%, at least 82%, at least 91%, and 100%. 
   
   
       17 . The method of  claim 10 , wherein the compound is selected from compounds 1-8 of Table 1: 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
   
   
       18 . The method of  claim 10 , wherein the compound is selected from compounds 9-16 of Table 2: 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
   
   
       19 . A method for treating overactive bladder comprising: administering, to a patient in need thereof, a therapeutically effective amount of a mixture of deuterium-enriched compounds of formula I or a pharmaceutically acceptable salt thereof: 
     
       
         
         
             
             
         
       
     
     wherein R 1 -R 31  are independently selected from H and D; and the abundance of deuterium in R 1 -R 31  is at least 3% provided that the compound is other than:
 (a) a compound where each of R 22 -R 31  is D or 
 (b) a compound where each of R 20 -R 21  is D. 
 
   
   
       20 . The method of  claim 19 , wherein the abundance of deuterium in R 1 -R 31  is selected from at least 3%, at least 6%, at least 13%, at least 19%, at least 26%, at least 32%, at least 39%, at least 45%, at least 52%, at least 58%, at least 65%, at least 71%, at least 77%, at least 84%, at least 90%, at least 97%, and 100%. 
   
   
       21 . The method of  claim 19 , wherein the abundance of deuterium in R 1  is 100%. 
   
   
       22 . The method of  claim 19 , wherein the abundance of deuterium in R 1 , R 20 -R 21 , and R 22 -R 31  is selected from at least 8%, at least 15%, at least 23%, at least 31%, at least 38%, at least 46%, at least 54%, at least 62%, at least 69%, at least 77%, at least 85%, at least 92%, and 100%. 
   
   
       23 . The method of  claim 19 , wherein the abundance of deuterium in R 20 -R 21  and R 22 -R 31  is selected from at least 8%, at least 17%, at least 25%, at least 33%, at least 42%, at least 50%, at least 58%, at least 67%, at least 75%, at least 83%, at least 92%, and 100%. 
   
   
       24 . The method of  claim 19 , wherein the abundance of deuterium in R 2 -R 6  is selected from at least 20%, at least 40%, at least 60%, at least 80%, and 100%. 
   
   
       25 . The method of  claim 19 , wherein the abundance of deuterium in R 7 -R 17  is selected from at least 9%, at least 18%, at least 27%, at least 36%, at least 45%, at least 56%, at least 64%, at least 73%, at least 82%, at least 91%, and 100%. 
   
   
       26 . The method of  claim 19 , wherein the compounds are selected from compounds I-8 of Table 1: 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
   
   
       27 . The method of  claim 19 , wherein the compounds are selected from compounds 9-16 of Table 2:

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