US2009165365A1PendingUtilityA1

Residual fuel oil additive

Individually held — no corporate assignee on recordPriority: Dec 21, 2005Filed: Dec 21, 2006Published: Jul 2, 2009
Est. expiryDec 21, 2025(expired)· nominal 20-yr term from priority
C10L 9/10C10L 1/305C10L 1/10C10L 1/1241C10L 1/1802C10L 1/1886C10L 9/12C10L 10/02Y02E50/10Y02E50/30
53
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Claims

Abstract

Fuel additives are disclosed for high-asphaltene carbonaceous fuels such as residual fuel oil or coal. Such additives provide improved combustion characteristics. Such improved combustion characteristics include one or both of improved efficiency and decreased emissions of pollutants. In particular, the fuel additives include an extract from a plant such as fescue, alfeque, or alfalfa, and optionally, an organometallic compound. The use of a fuel additive including both a plant extract and an organometallic compound is particularly useful in improving the combustion characteristics of fuels with particularly high asphaltene content.

Claims

exact text as granted — not AI-modified
1 . A fuel additive for improving the combustion characteristics of a high-asphaltene carbonaceous fuel, the fuel additive comprising:
 a plant extract; and   an organometallic compound.   
     
     
         2 . The fuel additive of  claim 1  wherein the plant extract is an extract of a plant from the Leguminosae family. 
     
     
         3 . The fuel additive of  claim 2  wherein the plant extract is selected from the group consisting of fescue extract, alfeque extract, alfalfa extract, and combinations thereof. 
     
     
         4 . The fuel additive of  claim 3  wherein the organometallic compound is a hydrocarbon-soluble organometallic compound containing at least one metal selected from the first and second row transition metals. 
     
     
         5 . The fuel additive of  claim 4  wherein the metal of the organometallic compound is iron 
     
     
         6 . The fuel additive of  claim 5  wherein the organometallic compound is selected from the group consisting of iron pentacarbonyl, iron naphthenate, ferrocene, and combinations thereof. 
     
     
         7 . The fuel additive of  claim 1  wherein the organometallic compound is a hydrocarbon-soluble organometallic compound containing at least one metal selected from the first and second row transition metals. 
     
     
         8 . The fuel additive of  claim 7  wherein the metal of the organometallic compound is iron 
     
     
         9 . The fuel additive of  claim 8  wherein the organometallic compound is selected from the group consisting of iron pentacarbonyl, iron naphthenate, ferrocene, and combinations thereof. 
     
     
         10 . The fuel additive of  claim 1  further comprising an oil-soluble carrier. 
     
     
         11 . The fuel additive of  claim 10  wherein the oil-soluble carrier is an aromatic solvent. 
     
     
         12 . The fuel additive of  claim 10  wherein the plant extract is provided in an amount from about 0.01 wt. % to about 10 wt. % of the fuel additive. 
     
     
         13 . The fuel additive of  claim 12  wherein the plant extract is provided in an amount from about 0.05 wt. % to about 5 wt. % of the fuel additive. 
     
     
         14 . The fuel additive of  claim 13  wherein the plant extract is provided in an amount of about 0.5 wt. % of the fuel additive. 
     
     
         15 . The fuel additive of  claim 1  further comprising a material selected from meadowfoam oil, a carotenoid, an anti-oxidant, and combinations thereof. 
     
     
         16 . The fuel additive of  claim 1  further comprising meadowfoam oil, a carotenoid, and an anti-oxidant. 
     
     
         17 . The fuel additive of  claim 16  wherein the carotenoid comprises β-carotene. 
     
     
         18 . The fuel additive of  claim 16  wherein the anti-oxidant comprises a dihydroquinoline. 
     
     
         19 . The fuel additive of  claim 18  wherein the dihydroquinoline comprises 2,2,4-trimethyl-6-ethoxy-1,2-dihydroquinoline. 
     
     
         20 . The fuel additive of  claim 1  wherein the plant extract is extracted by a hydrocarbon-soluble polar or nonpolar solvent. 
     
     
         21 . A method of improving the combustion characteristics of a high-asphaltene carbonaceous fuel comprising adding a fuel additive to the high-asphaltene carbonaceous fuel, the fuel additive comprising:
 a plant extract; and   an organometallic compound.   
     
     
         22 . The method of  claim 21  wherein the plant extract is an extract of a plant from the Leguminosae family. 
     
     
         23 . The method of  claim 22  wherein the plant extract is selected from the group consisting of fescue extract, alfeque extract, alfalfa extract, and combinations thereof. 
     
     
         24 . The method of  claim 23  wherein the organometallic compound is a hydrocarbon-soluble organometallic compound with a metal selected from the first and second row transition metals. 
     
     
         25 . The method of  claim 24  wherein the metal of the organometallic compound is iron. 
     
     
         26 . The method of  claim 25  wherein the organometallic compound is selected from the group consisting of iron pentacarbonyl, iron naphthenate, ferrocene, and combinations thereof. 
     
     
         27 . The method of  claim 21  wherein the organometallic compound is a hydrocarbon-soluble organometallic compound with a metal selected from the first and second row transition metals. 
     
     
         28 . The method of  claim 27  wherein the metal of the organometallic compound is iron. 
     
     
         29 . The method of  claim 28  wherein the organometallic compound is selected from the group consisting of iron pentacarbonyl, iron naphthenate, ferrocene, and combinations thereof. 
     
     
         30 . The method of  claim 21  wherein the fuel additive further comprises an oil-soluble carrier. 
     
     
         31 . The method of  claim 21  wherein the oil-soluble carrier is an aromatic solvent. 
     
     
         32 . The method of  claim 21  wherein the high-asphaltene carbonaceous fuel is selected from residual fuel oil and coal. 
     
     
         33 . The method of  claim 32  wherein the plant extract is provided in an amount from about 0.5 ppm to about 10,000 ppm of the amount of high-asphaltene carbonaceous fuel. 
     
     
         34 . The method of  claim 33  wherein the plant extract is provided in an amount from about 200 ppm to about 2000 ppm of the amount of high-asphaltene carbonaceous fuel. 
     
     
         35 . The method of  claim 34  wherein the plant extract is provided in an amount of about 800 ppm of the amount of high-asphaltene carbonaceous fuel. 
     
     
         36 . The method of  claim 21  wherein the fuel additive further comprises a material selected from meadowfoam oil, a carotenoid, an anti-oxidant, and combinations thereof. 
     
     
         37 . The method of  claim 21  wherein the fuel additive further comprises meadowfoam oil, a carotenoid, and an anti-oxidant. 
     
     
         38 . The method of  claim 37  wherein the carotenoid comprises β-carotene. 
     
     
         39 . The method of  claim 37  wherein the anti-oxidant comprises a dihydroquinoline. 
     
     
         40 . The method of  claim 39  wherein the dihydroquinoline comprises 2,2,4-trimethyl-6-ethoxy-1,2-dihydroquinoline. 
     
     
         41 . The method of  claim 21  wherein the plant extract is extracted by a hydrocarbon-soluble polar or nonpolar solvent. 
     
     
         42 . A fuel comprising a high-asphaltene carbonaceous fuel and a fuel additive, the fuel additive comprising:
 a plant extract; and   an organometallic compound.   
     
     
         43 . The fuel of  claim 42  wherein the plant extract is an extract of a plant from the Leguminosae family. 
     
     
         44 . The fuel of  claim 43  wherein the plant extract is selected from the group consisting of fescue extract, alfeque extract, alfalfa extract, and combinations thereof. 
     
     
         45 . The fuel of  claim 42  wherein the organometallic compound is a hydrocarbon-soluble organometallic compound with a metal selected from the first and second row transition metals. 
     
     
         46 . The fuel of  claim 45  wherein the organometallic compound is selected from the group consisting of iron pentacarbonyl, iron naphthenate, ferrocene, and combinations thereof. 
     
     
         47 . The fuel of  claim 42  wherein high-asphaltene carbonaceous fuel is selected from residual fuel oil and coal. 
     
     
         48 . The fuel of  claim 47  wherein the plant extract is provided in an amount from about 0.5 ppm to about 10,000 ppm of the high-asphaltene carbonaceous fuel. 
     
     
         49 . The fuel of  claim 48  wherein the plant extract is provided in an amount from about 200 ppm to about 2000 ppm of the high-asphaltene carbonaceous fuel. 
     
     
         50 . The fuel of  claim 49  wherein the plant extract is provided in an amount of about 800 ppm of the high-asphaltene carbonaceous fuel 
     
     
         51 . The fuel of  claim 42  further comprising a material selected from meadowfoam oil, a carotenoid, an anti-oxidant, and combinations thereof 
     
     
         52 . The fuel of  claim 42  further comprising meadowfoam oil, a carotenoid, and an anti-oxidant. 
     
     
         53 . The fuel of  claim 52  wherein the carotenoid comprises β-carotene. 
     
     
         54 . The fuel of  claim 52  wherein the anti-oxidant comprises a dihydroquinoline. 
     
     
         55 . The fuel of  claim 54  wherein the dihydroquinoline comprises 2,2,4-trimethyl-6-ethoxy-1,2-dihydroquinoline. 
     
     
         56 . The fuel of  claim 42  wherein the plant extract is extracted by a hydrocarbon-soluble polar or nonpolar solvent.

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