Multilayer Plastic Container

Abstract

A multilayer thermoplastic container for storing and transporting liquid contents, especially combustible or explosive contents, is made of at least three superimposed layers and includes at least one layer for discharging an electric charge. The innermost layer of the container in contact with the liquid content is made of virgin material. A second integrated inner layer which is covered by the innermost virgin material layer is electrically conductive as a result of incorporated additives, e.g. conductive carbon black and is covered on the outside by another electrically non-conductive layer. Electric charge carriers that accumulate on the surface of the thin inner layer due to the friction with the content are “suctioned through” large areas of the inner, electrically non-conductive layer by the second, electrically conductive layer and discharged.

1 .- 10 . (canceled) 
   
   
       11 . A multilayer thermoplastic container for storing and transporting a liquid bulk material, comprising:
 at least two insulating high-density polyethylene (HDPE) plastic layers forming an inner and an outer layer, each of the at least two layers having a thickness of less than 2.5 mm, and   an intermediate layer made of electrically conductive or permanently antistatic HDPE plastic material and disposed at least in a wall of the container intermediate between the inner layer and the outer layer.   
   
   
       12 . The plastic container of  claim 11 , wherein the inner layer in contact with the liquid bulk material is made of HDPE virgin material, an outer layer is an electrically non-conductive or insulating HDPE layer, and the intermediate layer in contact with the inner layer comprises an additive which renders the intermediate layer electrically conductive. 
   
   
       13 . The plastic container of  claim 12 , wherein the additive is conductive carbon black. 
   
   
       14 . The plastic container of  claim 12 , wherein the outer layer is interrupted by a narrow, vertically extending plastic strip made of an electrically conductive plastic material which has a radial thickness substantially identical to a radial thickness of the outer layer, and is electrically connected with the intermediate layer. 
   
   
       15 . The plastic container of  claim 11 , further comprising a fourth layer made of electrically conductive HDPE plastic material and externally covering the outer layer. 
   
   
       16 . The plastic container of  claim 15 , wherein the inner layer and the outer layer each have a radial thickness of no more than 2.5 mm, not to exceed about 45% of a total container wall thickness, and the intermediate layer and the fourth layer each have a radial wall thickness of no more than 5% of the total container wall thickness. 
   
   
       17 . The plastic container of  claim 15 , further comprising at least one narrow, vertically extending plastic strip made of electrically conductive plastic material and introduced in the fourth layer and the outer layer, wherein the strip has a radial thickness substantially identical to a radial thickness of the combined fourth and outer layer, and is electrically connected with the intermediate layer. 
   
   
       18 . The plastic container of  claim 11 , further comprising at least one narrow, vertically extending plastic strip made of electrically conductive plastic material and introduced in the inner layer, wherein the strip has a radial thickness substantially identical to a radial thickness of the inner layer and is electrically connected with the intermediate layer. 
   
   
       19 . The plastic container of  claim 11 , further comprising a barrier layer construction made of a polyamide PA or ethyl vinyl alcohol (EVOH) layer sandwiched between two layers having a bonding agent, wherein the barrier layer construction is arranged between the intermediate layer and the outer layer. 
   
   
       20 . The plastic container of  claim 11 , wherein the outer layer is made of virgin material or regrind material, or both. 
   
   
       21 . The plastic container of  claim 19 , further comprising
 at least one first contact strip made of electrically conductive plastic material and introduced in the inner layer for providing electric contact between the intermediate layer and the bulk material in the container, and   at least one additional contact strip made of electrically conductive plastic material that does not contain carbon black, wherein the at least one additional contact strip is introduced in the barrier layer construction for providing electric contact between intermediate layer and the outer layer.   
   
   
       22 . The plastic container of  claim 11 , wherein the content comprises flammable or explosive content. 
   
   
       23 . A method for producing a multilayer plastic container, comprising the steps of:
 supplying three different plastic materials from at least three extruders to a peripheral distributor,   forming an at least three-layer tubular preform having an inner layer, an outer layer and an intermediate layer disposed between the inner layer and the outer layer, wherein the inner layer and the outer layer are made of an electrically non-conductive plastic material, and the intermediate layer is made of an electrically conductive plastic material, and   expanding the tubular preform in a blow mold into a hollow plastic body.   
   
   
       24 . The method of  claim 23 , wherein the intermediate layer comprises carbon black as an additive. 
   
   
       25 . The method of  claim 23 , wherein the inner layer comprises HDPE virgin material.