Transparent polymer articles of low thickness

Abstract

The novel transparent polyolefin, polyester or polyamide article disclosed is stabilized against the effects of light, oxygen, heat and agressive chemicals by addition of 0.005-0.30% by weight the polymeric substrate of a hydroxyphenyl triazine UV absorber, and is characterized by its thickness between 1 and 500 μm. Preferred polyolefin articles thus stabilized are agricultural films containing as further stabilizer a sterically hindered amine. The novel compositions act as selective UV filter especially useful in agriculture.

1 . Transparent polyolefin, polyester or polyamide article having a thickness between 1 and 200 μm, which is stabilized against the effects of light, oxygen, heat and/or agressive chemicals by addition of 0.005-0.30% by weight, based on the polyolefin, polyester or polyamide, of a hydroxyphenyl triazine UV absorber, and which article further contains a sterically hindered amine stabilizer in an amount of 0.01-6% by weight of the polyolefin, polyester or polyamide. 
   
   
       2 . Transparent polyolefin article of  claim 1 . 
   
   
       3 . Transparent polyolefin, polyester or polyamide article of  claim 1  wherein the weight ratio sterically hindered amine:hydroxyphenyl triazine UV absorber ranges from 2:1 to 20:1. 
   
   
       4 . Transparent polyolefin, polyester or polyamide article of  claim 1  wherein the sterically hindered amine belongs to the class of hydroxylamine ethers. 
   
   
       5 . Transparent polyolefin, polyester or polyamide article of  claim 1  wherein the hydroxyphenyl triazine UV absorber conforms to the formula I 
     
       
         
         
             
             
         
       
       wherein 
       R 1  is H or OR 7 ; 
       R 2  and R 3  independently are H, C 1 -C 8 alkyl, 
     
     
       
         
         
             
             
         
       
       OR 9 ; 
       R 4  and R 5  independently are H, C 1 -C 8 alkyl, OR 10 ; 
       R 6  is H, C 1 -C 18 alkyl, C 5 -C 12 cycloalkyl, C 7 -C 12 phenylalkyl, C 7 -C 12 alkylphenyl, C 3 -C 12 alkenyl, halogen, OH, OR 9 ; 
       R 8  is H; halogen; C 1 -C 12 alkoxy; C 1 -C 12 alkyl; C 3 -C 24 alkyl interrupted by oxygen and/or substituted by OH; or is NH—CO—R 14  or NH—COO—R 12 ; 
       R 7 , R 9  and R 10  independently are H; C 1 -C 24 alkyl; C 3 -C 12 alkenyl; C 3 -C 24 alkyl interrupted by oxygen and/or substituted by OH; or is C 5 -C 12 cycloalkyl, C 7 -C 12 phenylalkyl, C 7 -C 12 alkylphenyl; CH 2 CH(OH)CH 2 OR 11 ; C 1 -C 12 alkyl substituted by COOR 12 , CONR 13 R 14 , OCOR 15 , OH or halogen; or R 7  is a polymeric hydrocarbon residue of 10 to 1000 carbon atoms; 
       and R 7  also embraces a residue of formula II 
     
     
       
         
         
             
             
         
       
       wherein X is C 2 -C 24 alkylene; —CH 2 CH(OH)CH 2 —; —CH 2 CH(OH)CH 2 O-D-OCH 2 CH(OH)CH 2 ; 
       (C 1 -C 18 alkylene)-CO—O-D-O—CO—(C 1 -C 18 alkylene); CO; CO—(C 2 -C 24 alkylene)-CO; 
       C 3 -C 24 alkylene interrupted by oxygen; 
       D is C 2 -C 12 alkylene; C 4 -C 50 alkylene interrupted by O; phenylene; biphenylene or phenylene-E-phenylene; 
       E is O, S, SO 2 ; CH 2 ; CO or —C(CH 3 ) 2 —; 
       R 11  is H, C 1 -C 12 alkyl; phenyl; phenyl substituted by 1-3 C 1 -C 4 alkyl; C 5 -C 12 cycloalkyl; C 7 -C 12 phenylalkyl; C 3 -C 12 alkenyl; 
       R 12  is H; C 1 -C 24 alkyl; C 3 -C 12 alkenyl; C 3 -C 36 alkyl interrupted by oxygen and/or substituted by OH; or is C 5 -C 12 cycloalkyl, C 7 -C 12 phenylalkyl, C 7 -C 12 alkylphenyl; phenyl; 
       R 13  and R 14  independently are H, C 1 -C 18 alkyl; phenyl; phenyl substituted by 1-3 C 1 -C 4 alkyl and/or C 1 -C 4 alkoxy; C 5 -C 12 cycloalkyl; C 3 -C 12 alkenyl; 
       R 15  is C 1 -C 12 alkyl; phenyl; phenyl substituted by 1-3 C 1 -C 4 alkyl and/or C 1 -C 4 alkoxy; C 5 -C 12 cycloalkyl; C 3 -C 12 alkenyl; C 1 -C 12 alkoxy; or is NR 13 R 14 . 
     
   
   
       6 . Transparent polyolefin, polyester or polyamide article of  claim 5 , where in the hydroxyphenyl triazine UV absorber of formula I
 R 2  and R 3  independently are H, methyl,   
     
       
         
         
             
             
         
       
     
     OR 9 ;
 R 4  and R 5  independently are H or methyl; 
 R 6  is H; 
 R 8  is H; C 1 -C 8 alkoxy; C 1 -C 8 alkyl; 
 R 7 , R 9  independently are H; C 1 -C 18 alkyl; C 3 -C 12 alkenyl; C 3 -C 24 alkyl interrupted by oxygen and/or substituted by OH; or is C 5 -C 12 cycloalkyl, C 7 -C 12 phenylalkyl, C 7 -C 12 alkylphenyl; C 1 -C 12 alkyl substituted by COOR 12 , OCOR 15 , OH; or R 7  is a polymeric hydrocarbon residue of 20 to 500 carbon atoms; 
 and R 7  also embraces a residue of formula II, wherein X is C 2 -C 18 alkylene; 
 —CH 2 CH(OH)CH 2 —; —CH 2 CH(OH)CH 2 O-D-OCH 2 CH(OH)CH 2 ; 
 (C 1 -C 4 alkylene)-CO—O-D-O—CO—(C 1 -C 4 alkylene); CO; CO—(C 2 -C 18 alkylene)-CO; 
 C 3 -C 18 alkylene interrupted by oxygen; D is C 2 -C 12 alkylene; 
 R 12  is H; C 1 -C 24 alkyl; C 3 -C 12 alkenyl; C 3 -C 24 alkyl interrupted by oxygen and/or substituted by OH; or is C 5 -C 12 cycloalkyl, C 7 -C 12 phenylalkyl, C 7 -C 12 alkylphenyl; phenyl; 
 R 15  is C 1 -C 12 alkyl; C 5 -C 12 cycloalkyl; C 3 -C 12 alkenyl. 
 
   
   
       7 . Transparent polyolefin, polyester or polyamide article of  claim 1  which is a film, fiber, ribbon or stretched tape. 
   
   
       8 . Transparent polyolefin article of  claim 1 , wherein the polyolefin is polyethylene or polypropylene. 
   
   
       9 . Transparent polyolefin, polyester or polyamide article of  claim 1  additionally containing a further component selected from the group consisting of processing stabilizers, fillers, clarifiers, modifiers, acid scavengers, flame retardants and further light stabilizers. 
   
   
       10 . Transparent polyolefin article of  claim 1  which is a polyolefin agricultural film. 
   
   
       11 . Transparent polyolefin, polyester or polyamide article of  claim 1  wherein the sterically hindered amine is selected from
 bis(2,2,6,6-tetramethyl-4-piperidyl)sebacate,   bis(2,2,6,6-tetramethyl-4-piperidyl)succinate,   bis(1,2,2,6,6-pentamethyl-4-piperidyl)sebacate,   bis(1,2,2,6,6-pentamethyl-4-piperidyl) n-butyl-3,5-di-tert-butyl-4-hydroxybenzylmalonate,   the condensate of 1-(2-hydroxyethyl)-2,2,6,6-tetramethyl-4-hydroxypiperidine and succinic acid,   linear or cyclic condensates of N,N′-bis(2,2,6,6-tetramethyl-4-piperidyl)-hexamethylenediamine and 4-tert-octylamino-2,6-dichloro-1,3,5-triazine,   tris(2,2,6,6-tetramethyl-4-piperidyl)nitrilotriacetate,   tetrakis(2,2,6,6-tetramethyl-4-piperidyl)-1,2,3,4-butanetetracarboxylate,   1,1′-(1,2-ethanediyl)-bis(3,3,5,5-tetramethylpiperazinone),   4-benzoyl-2,2,6,6-tetramethylpiperidine,   4-stearyloxy-2,2,6,6-tetramethylpiperidine,   bis(1,2,2,6,6-pentamethylpiperidyl)-2-n-butyl-2-(2-hydroxy-3,5-di-tert-butylbenzyl)malonate,   3-n-octyl-7,7,9,9-tetramethyl-1,3,8-triazaspiro[4.5]decane-2,4-dione,   linear or cyclic condensates of N,N′-bis(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine and 4-morpholino-2,6-dichloro-1,3,5-triazine,   the condensate of 2-chloro-4,6-bis(4-n-butylamino-2,2,6,6-tetramethylpiperidyl)-1,3,5-triazine and 1,2-bis(3-aminopropylamino)ethane,   the condensate of 2-chloro-4,6-di-(4-n-butylamino-1,2,2,6,6-pentamethylpiperidyl)-1,3,5-triazine and 1,2-bis(3-aminopropylamino)ethane,   8-acetyl-3-dodecyl-7,7,9,9-tetramethyl-1,3,8-triazaspiro[4.5]decane-2,4-dione,   3-dodecyl-1-(2,2,6,6-tetramethyl-4-piperidyl)pyrrolidine-2,5-dione,   3-dodecyl-1-(1,2,2,6,6-pentamethyl-4-piperidyl)pyrrolidine-2,5-dione,   a mixture of 4-hexadecyloxy- and 4-stearyloxy-2,2,6,6-tetramethylpiperidine,   a condensate of N,N′-bis(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine and 4-cyclohexylamino-2,6-dichloro-1,3,5-triazine,   a condensate of 1,2-bis(3-aminopropylamino)ethane and 2,4,6-trichloro-1,3,5-triazine as well as 4-butylamino-2,2,6,6-tetramethylpiperidine;   a condensate of 1,6-hexanediamine and 2,4,6-trichloro-1,3,5-triazine as well as N,N-dibutylamine and 4-butylamino-2,2,6,6-tetramethylpiperidine;   N-(2,2,6,6-tetramethyl-4-piperidyl)-n-dodecylsuccinimide,   N-(1,2,2,6,6-pentamethyl-4-piperidyl)-n-dodecylsuccinimide,   2-undecyl-7,7,9,9-tetramethyl-1-oxa-3,8-diaza-4-oxo-spiro[4,5]decane,   a reaction product of 7,7,9,9-tetramethyl-2-cycloundecyl-1-oxa-3,8-diaza-4-oxospiro-[4,5]decane and epichlorohydrin,   1,1-bis(1,2,2,6,6-pentamethyl-4-piperidyloxycarbonyl)-2-(4-methoxyphenyl)ethene,   N,N′-bis-formyl-N,N′-bis(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine,   a diester of 4-methoxymethylenemalonic acid with 1,2,2,6,6-pentamethyl-4-hydroxypiperidine,   poly[methylpropyl-3-oxy-4-(2,2,6,6-tetramethyl-4-piperidyl)]siloxane,   a reaction product of maleic acid anhydride-α-olefin copolymer with 2,2,6,6-tetramethyl-4-aminopiperidine or 1,2,2,6,6-pentamethyl-4-aminopiperidine;   N,N′,N″,N′″-Tetrakis(4,6-bis(butyl-(N-methyl-2,2,6,6-tetramethylpiperidin-4-yl)amino)triazin-2-yl)-4,7-diazadecane-1,10-diamine;   
     
       
         
         
             
             
         
       
       where n is from the range 3-5; 
       sterically hindered hydroxylamine ethers, and mixtures of these compounds; 
       and contained in an amount of 0.01 to 6% by weight of the polyolefin, polyester or polyamide. 
     
   
   
       12 . Transparent polyolefin, polyester or polyamide article of  claim 1 , where the article contains from 0.005 to 0.15% by weight, based on the polyolefin, polyester or polyamide, of a hydroxyphenyl triazine UV absorber. 
   
   
       13 . Transparent polyolefin, polyester or polyamide article of  claim 1 , where the article contains from 0.005 to 0.06% by weight, based on the polyolefin, polyester or polyamide, of a hydroxyphenyl triazine UV absorber. 
   
   
       14 . Transparent polyolefin, polyester or polyamide article of  claim 1 , where the article contains from 0.01 to 0.06% by weight, based on the polyolefin, polyester or polyamide, of a hydroxyphenyl triazine UV absorber. 
   
   
       15 . Transparent polyolefin, polyester or polyamide article of  claim 1 , where the article contains a further component selected from the group consisting of hindered phenolic antioxidants, hydroxyphenylbenzotriazole or hydroxybenzophenone UV absorbers, phosphites or phosphonites, hydroxylamines and benzofuranones.