Soft Polypropylene-Based Nonwovens

Abstract

Disclosed herein is a nonwoven fabric comprising within the range of from 1 to 49 wt %, by weight of the fabric, of a reactor grade propylene-α-olefin copolymer possessing; within the range of from 5 to 35 wt %, by weight of the copolymer, of units derived from one or more of ethylene and/or C 4 to C 12 α-olefins; a melt flow rate (230° C./2.16 kg) within the range of from 600 to 7500 g/10 min; and a weight average molecular weight of less than 200,000; and a second polypropylene having a melting point, T m , of greater than 110° C. and a melt flow rate (230° C./2.16 kg) within the range of from 20 to 7500 g/10 min; wherein the fabric has a Handle value of less than 60% (measuring the fabric of 35 g/m 2 basis weight). The fabric can be used in structures comprising one or more layers of the fabric described herein, and can include any number of other fabric layers made from other materials.

1 . A nonwoven fabric comprising:
 (a) within the range of from 1 to 49 wt %, by weight of the fabric, of a reactor grade propylene-α-olefin copolymer possessing;
 (i) within the range of from 5 to 35 wt %, by weight of the copolymer, of units derived from one or more of ethylene and/or C 4  to C 12  α-olefins; 
 (ii) a melt flow rate (230° C./2.16 kg) within the range of from 260 to 7260 g/10 min and a weight average molecular weight of less than 200,000; and 
 (iii) a heat of fusion, ΔH f , within the range of from 0.5 to 75 J/g; and 
   (b) a second polypropylene having a melting point, T m , of greater than 110° C. and
 a melt flow rate (230° C./2.16 kg) within the range of from 20 to 7500 g/10 min; 
   wherein the fabric has a Handle value of less than 60% (measuring the fabric of 35 g/m 2  basis weight).   
     
     
         2 . The nonwoven fabric of  claim 1 , wherein the fabric consists essentially of the reactor grade propylene-α-olefin copolymer and the second polypropylene. 
     
     
         3 . The nonwoven fabric of  claim 1 , wherein a weight average molecular weight of the reactor grade propylene-α-olefin copolymer is within the range of from 10,000 to 200,000. 
     
     
         4 . The nonwoven fabric of  claim 1 , wherein the reactor grade propylene-α-olefin copolymer has a melting point T m  of less than 80° C. 
     
     
         5 . The nonwoven fabric of  claim 1 , wherein chain scissioning byproducts are substantially absent from the reactor grade propylene-α-olefin copolymer. 
     
     
         6 . The nonwoven fabric of  claim 1 , wherein the reactor grade propylene-α-olefin copolymer is prepared by reacting propylene, ethylene and a metallocene catalyst composition. 
     
     
         7 . The nonwoven fabric of  claim 1 , wherein the fabric has been annealed at a temperature within the range of from 70 to 130° C. for 1 to 10 seconds. 
     
     
         8 . The nonwoven fabric of  claim 7 , wherein the fabric has an MD Elongation value within the range of from 5 to 40%, and a CD Elongation value within the range of from 5 to 60% (measuring the fabric of 35 g/m 2  basis weight for both). 
     
     
         9 . The nonwoven fabric of  claim 7 , wherein the fabric has a Hydrostatic Head value of greater than 50 mbar (measuring the fabric of 35 g/m 2  basis weight). 
     
     
         10 . The nonwoven fabric of  claim 7 , wherein the fabric has an Air Permeability value of greater than 30 ft 3 /ft 2 /min (9.1 m 3 /m 2 /min) (measuring the fabric of 35 g/m 2  basis weight). 
     
     
         11 . The nonwoven fabric of  claim 1 , wherein the fabric comprises from 10 to 40 wt %, by weight of the composition, of the reactor grade propylene-α-olefin copolymer. 
     
     
         12 . The nonwoven fabric of  claim 1 , wherein the reactor grade propylene-α-olefin copolymer comprises within the range of from 8 to 18 wt %, by weight of the copolymer, of ethylene-derived units. 
     
     
         13 . The nonwoven fabric of  claim 1 , wherein the second polypropylene is a propylene homopolymer or propylene copolymer comprising from 0.01 to 5 wt % comonomer, wherein the second polypropylene has a melting point of 110° C. or more. 
     
     
         14 . A structure comprising two or more layers of fabric comprising at least one layer of the fabric of  claim 1 . 
     
     
         15 . A method of forming a nonwoven fabric comprising:
 (a) reacting propylene with an α-olefin selected from ethylene and C 4  to C 12  α-olefins and a bridged metallocene catalyst composition at a temperature within the range of from 80 to 120° C.;   (b) isolating a reactor grade propylene-α-olefin copolymer possessing a melt flow rate within the range of from 260 to 7260 g/10 min and a weight average molecular weight of less than 200,000;   (c) blending within the range of from 1 to 49 wt %, by weight of the fabric, of the reactor grade propylene-α-olefin copolymer and a second polypropylene to form a composition; and   (d) meltblowing the composition to form a nonwoven fabric, wherein the fabric has a Handle value of less than 60% (measuring the fabric of 35 g/m 2  basis weight).   
     
     
         16 . The method of  claim 15  further comprising the step of annealing the fibers or fabric at a temperature within the range of from 70 to 130° C. for 1 to 10 seconds. 
     
     
         17 . The method of  claim 15  wherein the α-olefin is selected from ethylene, 1-butene. 1-octene and 1-hexene. 
     
     
         18 . The method of  claim 15  blending within the range of from 5 to 40 wt %, by weight of the fabric, of the reactor grade propylene-α-olefin copolymer. 
     
     
         19 . The method of  claim 15  wherein chain scissioning byproducts are substantially absent from the reactor grade propylene-α-olefin copolymer. 
     
     
         20 . The method of  claim 15 , wherein the fabric has an MD Elongation value within the range of from 2 to 40%, and a CD Elongation value within the range of from 5 to 60% (measuring the fabric of 35 g/m 2  basis weight for both). 
     
     
         21 . The method of  claim 15 , wherein the fabric has a Hydrostatic Head value of greater than 50 mbar (measuring the fabric of 35 g/m 2  basis weight). 
     
     
         22 . The method of  claim 15 , wherein the fabric has an Air Permeability value of greater than 30 ft 3 /ft 2 /min (9.1 m 3 /m 2 /min) (measuring the fabric of 35 g/m 2  basis weight). 
     
     
         23 . The method of  claim 15  wherein the composition is meltblown at a melt temperature within the range of from 230 to 280° C. and a throughput within the range of from 0.2 to 2.0 g/hole/min.