Zirconia body and methods

Abstract

A translucent zirconia sintered body, a dental article comprising a shaped, translucent zirconia body, a zirconia green body, and methods of making a translucent zirconia sintered body, methods of making a dental article comprising a shaped, translucent zirconia body, and methods of making a zirconia green body are described.

1 . A translucent zirconia sintered body comprised of primary particles and having a density of at least 99 percent of full density, the primary particles having:
 a major phase which is tetragonal zirconium oxide, and   a size no greater than 100 nm; and   
       wherein the diameter of any pores which are present in the zirconia sintered body is not more than about 25 nm. 
     
     
         2 . The translucent zirconia sintered body of  claim 1  wherein the primary particle size is no greater than 50 nm. 
     
     
         3 . (canceled) 
     
     
         4 . The translucent zirconia sintered body of  claim 1  wherein the percent light transmittance through a 1 mm thickness of the zirconia sintered body is at least 60% at 350-700 nm. 
     
     
         5 - 6 . (canceled) 
     
     
         7 . The translucent zirconia sintered body of  claim 1  wherein the major phase which is tetragonal zirconium oxide comprises at least 70 percent of the zirconium oxide in the primary particles. 
     
     
         8 . (canceled) 
     
     
         9 . A dental article comprising a shaped, translucent zirconia sintered body comprised of primary particles and having a density of at least 99 percent of full density, the primary particles having:
 a major phase which is tetragonal zirconium oxide, and   a size no greater than 100 nm; and   
       wherein the diameter of any pores which are present in the translucent zirconia sintered body is not more than about 25 nm. 
     
     
         10 . The dental article of  claim 9  wherein the primary particle size is no greater than 50 nm. 
     
     
         11 - 14 . (canceled) 
     
     
         15 . The dental article of  claim 9  wherein the major phase which is tetragonal zirconium oxide comprises at least 70 percent of the zirconium oxide in the primary particles. 
     
     
         16 - 21 . (canceled) 
     
     
         22 . A method of making a translucent zirconia sintered body comprising:
 providing a zirconia green body comprised of primary particles and having a density of at least 50 percent of full density, the primary particles having:
 a major phase which is tetragonal zirconium oxide, and 
 a size no greater than 50 nm; and 
   
       wherein the diameter of any pores which are present in the green body is not more than about 30 nm; and
 sintering the zirconia green body at a temperature no greater than 1200° C. to provide a translucent zirconia sintered body comprised of primary particles and having a density of at least 99 percent of full density, the primary particles having:
 a major phase which is tetragonal zirconium oxide, and 
 a size no greater than 100 nm; and 
 
 
       wherein the diameter of any pores which are present in the translucent zirconia sintered body is not more than about 25 nm. 
     
     
         23 . The method of  claim 22  further comprising:
 providing a zirconia sol comprising zirconia particles having an average primary particle size no greater than 50 nm; and   drying the zirconia sol to provide the zirconia green body.   
     
     
         24 - 27 . (canceled) 
     
     
         28 . The method of  claim 23  wherein the zirconia particles have a dispersion index of 1 to 3, a ratio of intensity-average particle size to volume-average particle size no greater than 3.0, and a crystal structure that is at least 70 percent tetragonal. 
     
     
         29 . (canceled) 
     
     
         30 . The method of  claim 23  further including a sintering additive with the zirconia sol, wherein the sintering additive is selected from the group consisting of aluminum, niobium, calcium, and oxides thereof. 
     
     
         31 . (canceled) 
     
     
         32 . The method of  claim 23  wherein drying the zirconia sol is carried out in a mold. 
     
     
         33 - 35 . (canceled) 
     
     
         36 . The method of  claim 23  wherein drying the zirconia sol is carried out by spray drying to form a powder, and compacting the powder at an elevated temperature to form the green body. 
     
     
         37 - 39 . (canceled) 
     
     
         40 . The method of  claim 22 , wherein a temperature no greater than 1000° C. is used during sintering. 
     
     
         41 - 47 . (canceled) 
     
     
         48 . A method of making a dental article comprising:
 providing a translucent zirconia sintered body comprised of primary particles and having a density of at least 99 percent of full density, the primary particles having:   a major phase which is tetragonal zirconium oxide, and   a size no greater than 100 nm; and   
       wherein the diameter of any pores which are present is not more than about 25 nm; and
 shaping the translucent zirconia sintered body to provide a dental article. 
 
     
     
         49 - 53 . (canceled) 
     
     
         54 . The method of  claim 48  wherein the major phase which is tetragonal zirconium oxide comprises at least 70 percent of the zirconium oxide in the primary particles. 
     
     
         55 . (canceled) 
     
     
         56 . The method of  claim 48  wherein shaping the translucent zirconia sintered body is carried out by milling. 
     
     
         57 - 58 . (canceled) 
     
     
         59 . A method of making a dental article comprising:
 providing a zirconia green body comprised of primary particles and having a density of at least 50 percent of full density, the primary particles having:   a major phase which is tetragonal zirconium oxide, and   a size no greater than 50 nm; and   wherein the diameter of any pores which are present in the zirconia green body is not more than about 30 nm;   sintering the zirconia green body at a temperature no greater than 1200° C. and for a time sufficient to form a partially sintered zirconia green body;   shaping the partially sintered zirconia green body; and   sintering the shaped, partially-sintered zirconia green body to provide a dental article comprising a shaped, translucent zirconia sintered body comprised of primary particles and having a density of at least 99 percent of full density, the primary particles having:   a major phase which is tetragonal zirconium oxide, and   a size no greater than 100 nm; and   wherein the diameter of any pores which are present in the shaped, translucent zirconia sintered body is not more than about 25 nm.   
     
     
         60 - 62 . (canceled) 
     
     
         63 . The method of  claim 59  wherein sintering the zirconia green body is carried out at a temperature no greater than 1000° C. and for a time sufficient to form a partially-sintered zirconia green body; 
     
     
         64 - 71 . (canceled) 
     
     
         72 . The method of  claim 59  wherein the major phase which is tetragonal zirconium oxide comprises at least 70 percent of the zirconium oxide in the primary particles of the translucent zirconia sintered body. 
     
     
         73 - 74 . (canceled)