US2010294472A1PendingUtilityA1

Use of a duplex stainless steel in a phosphoric acid production system

Assignee: SANDVIK INTELLECTUAL PROPERTYPriority: Oct 26, 2007Filed: Oct 24, 2008Published: Nov 25, 2010
Est. expiryOct 26, 2027(~1.2 yrs left)· nominal 20-yr term from priority
F28F 21/08C22C 38/58C22C 38/54C22C 38/52C22C 38/44C22C 38/42F28F 21/083C22C 38/001
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Claims

Abstract

The present disclosure relates to the use of a duplex stainless steel as heat exchanger material in a phosphoric acid production system using the wet method. The steel has the following composition in percent by weight: C max 0.03 Si max 0.5 Mn max 3 Cr 26-29 Ni 4.9-10 Mo 3-5 N 0.35-0.5 B max 0.0030 Co max 3.5 W max 3 Cu max 2 Ru max 0.3 balance Fe and normal occurring impurities.

Claims

exact text as granted — not AI-modified
1 . Heat exchanger for use in environments containing phosphoric acid, said heat exchanger comprising at least one tube of a duplex stainless steel with the following composition in percent by weight: 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   C 
                   max 0.03 
                 
                     
                   Si 
                   max 0.5 
                 
                     
                   Mn 
                   max 3 
                 
                     
                   Cr 
                     26-29 
                 
                     
                   Ni 
                    4.9-10 
                 
                     
                   Mo 
                     3-5 
                 
                     
                   N 
                   0.35-0.5 
                 
                     
                   B 
                   max 0.0030 
                 
                     
                   Co 
                   max 3.5 
                 
                     
                   W 
                   max 3 
                 
                     
                   Cu 
                   max 2 
                 
                     
                   Ru 
                   max 0.3 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         balance Fe and normal occurring impurities. 
       
     
     
         2 . Heat exchanger according to  claim 1  wherein the tube is a seamless tube. 
     
     
         3 . Heat exchanger according to  claim 1  wherein the duplex stainless steel comprises 26.5-28% Cr. 
     
     
         4 . Heat exchanger according to  claim 1  wherein the duplex stainless steel comprises max 1.2% Cu. 
     
     
         5 . Heat exchanger according to  claim 1  wherein the duplex stainless steel comprises 0.5-3.5% Co. 
     
     
         6 . Heat exchanger according to  claim 1  wherein [wt-% Cr]+3.3([wt-% Mo]+0.5[wt-% W])+16[wt-% N] is at least 45. 
     
     
         7 . Heat exchanger according to  claim 1  wherein it is adapted to be in direct contact with a process solution containing phosphoric acid. 
     
     
         8 . Phosphoric acid production system comprising an evaporator having a heat exchanger, said heat exchanger comprising at least one tube of a duplex stainless steel with the following composition in percent by weight: 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   C 
                   max 0.03 
                 
                     
                   Si 
                   max 0.5 
                 
                     
                   Mn 
                   max 3 
                 
                     
                   Cr 
                     26-29 
                 
                     
                   Ni 
                    4.9-10 
                 
                     
                   Mo 
                     3-5 
                 
                     
                   N 
                   0.35-0.5 
                 
                     
                   B 
                   max 0.0030 
                 
                     
                   Co 
                   max 3.5 
                 
                     
                   W 
                   max 3 
                 
                     
                   Cu 
                   max 2 
                 
                     
                   Ru 
                   max 0.3 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         balance Fe and normal occurring impurities. 
       
     
     
         9 . Phosphoric acid production system according to  claim 8  wherein the heat exchanger is adapted to be in direct contact with a process solution containing phosphoric acid. 
     
     
         10 . Phosphoric acid production system according to  claim 8  wherein the tube is a seamless tube. 
     
     
         11 . Phosphoric acid production system according to  claim 8  wherein the duplex stainless steel comprises 26.5-28% Cr. 
     
     
         12 . Phosphoric acid production system according to  claim 8  wherein the duplex stainless steel comprises max 1.2% Cu. 
     
     
         13 . Phosphoric acid production system according to  claim 8  wherein the duplex stainless steel comprises 0.5-3.5% Co. 
     
     
         14 . Phosphoric acid production system according to  claim 8  wherein [wt-% Cr]+3.3([wt-% Mo]+0.5[wt-% W])+16[wt-% N] is at least 45. 
     
     
         15 . Use of a duplex stainless steel with the following composition in percent by weight: 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   C 
                   max 0.03 
                 
                     
                   Si 
                   max 0.5 
                 
                     
                   Mn 
                   max 3 
                 
                     
                   Cr 
                     26-29 
                 
                     
                   Ni 
                    4.9-10 
                 
                     
                   Mo 
                     3-5 
                 
                     
                   N 
                   0.35-0.5 
                 
                     
                   B 
                   max 0.0030 
                 
                     
                   Co 
                   max 3.5 
                 
                     
                   W 
                   max 3 
                 
                     
                   Cu 
                   max 2 
                 
                     
                   Ru 
                   max 0.3 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         balance Fe and normal occurring impurities in environments containing phosphoric acid. 
       
     
     
         16 . Use of a duplex stainless steel with the following composition in percent by weight 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   C 
                   max 0.03 
                 
                     
                   Si 
                   max 0.5 
                 
                     
                   Mn 
                   max 3 
                 
                     
                   Cr 
                     26-29 
                 
                     
                   Ni 
                    4.9-10 
                 
                     
                   Mo 
                     3-5 
                 
                     
                   N 
                   0.35-0.5 
                 
                     
                   B 
                   max 0.0030 
                 
                     
                   Co 
                   max 3.5 
                 
                     
                   W 
                   max 3 
                 
                     
                   Cu 
                   max 2 
                 
                     
                   Ru 
                   max 0.3 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         balance Fe and normal occurring impurities as a tube in a heat exchanger in environments containing phosphoric acid. 
       
     
     
         17 . Use according to  claim 16  wherein the heat exchanger is a heat exchanger in an evaporator in a phosphoric acid production system using the wet method. 
     
     
         18 . Use according to  claim 15  in environments containing 30-80% H 3 PO 4 , up to 2000 ppm Cl″ and up to 2% F″. 
     
     
         19 . Use according to  claim 15  at temperatures up to 110° C. 
     
     
         20 . Use according to  claim 15  in fertilizer production plants.

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