Marking liquid

Abstract

A liquid electrostatographic toner or liquid ink jet ink prepared by the steps of heating a marking particle mix of particles of a resin and a colourant blend in a carrier liquid to a temperature between about the first softening point of the resin and about the second softening point of the resin, maintaining the temperature of the heated marking particle mix for a selected period of time, cooling the marking particle mix to room temperature, and mixing the marking particle mix with high shear. The particle mix can be produced by coarse grinding in a ball mill. The resultant toner or ink has an improved Newtonian like flow behaviour, improved electrical properties, reduced sedimentation and agglomeration and significantly improved optical density and reduced background.

1 . A liquid electrostatographic toner or liquid ink jet ink prepared by a method including the steps of,
 a) preparing a resin system comprising a resin or resins with optionally a colorant,   b) coarse grinding the resin system,   c) milling the coarse ground resin system with a carrier liquid to produce a liquid marking particle mix,   d) heating the liquid marking particle mix to a temperature about or greater than the first softening point of the resin system of the marking particle mix to less than about the second softening point of the resin system,   e) maintaining the temperature of the heated marking particle mix for a selected period of time,   f) cooling the marking particle mix to room temperature, and   g) mixing the marking particle mix with high shear.   
     
     
         2 . A liquid electrostatographic toner or liquid ink jet ink as in  claim 1  wherein the resin system comprises;
 0 to 60% of the colourant; and 
 resin or resins to 100% 
 
     
     
         3 . A liquid electrostatographic toner or liquid ink jet ink as in  claim 2  wherein the resin system further comprises a plasticiser in a range of from 0 to 20%. 
     
     
         4 . A liquid electrostatographic toner or liquid ink jet ink as in  claim 1  comprising:
 1 to 60 percent marking particle mix by weight, 
 0.01 to 5 percent charge control agent, 
 0.1 to 20 percent dispersion agent, and 
 carrier liquid to 100 percent. 
 
     
     
         5 . A liquid electrostatographic toner or liquid ink jet ink as in  claim 1  wherein the selected period of time is from several minutes to several days depending upon the type of heating applied and the method of applying that heat. 
     
     
         6 . A liquid electrostatographic toner or liquid ink jet ink as in  claim 1  wherein the heating is provided by convection, conduction or radiation. 
     
     
         7 . A liquid electrostatographic toner or liquid ink jet ink as in  claim 3  wherein the plasticiser is selected from the group comprising sulfonamides, adipates, sebacates and phthalates. 
     
     
         8 . A liquid electrostatographic toner or liquid ink jet ink as in  claim 1  wherein the step of milling the resin system includes milling with additives selected from one or both of the group comprising charge control agents and dispersion agents. 
     
     
         9 . A liquid electrostatographic toner or liquid ink jet ink as in  claim 1  wherein the resin is selected from one or more of the group comprising ethyl cellulose, oil modified alkyd resin, acrylic ester resin, methacrylic ester resin, polystyrene, silicone-acryl copolymer, silicone resin, silicone-(meth)acryl copolymer, block polymer or graft polymer, polyolefin copolymer, poly(vinyl chloride) resin, chlorinated polypropylene, polyamide resin, coumarone-indene resin, rosin-modified resin, alkylphenol-modified xylene resin, synthetic polyesters; polypropylene or modified polypropylene; alkylated poly vinyl pyrrolidones; natural waxes, montan wax, candelilla wax, sugar cane wax, beeswax; natural resins, ester gum and hardened rosin; natural-resin-modified cured resins, natural resin-modified maleic acid resins, natural resin-modified phenol resins, natural resin-modified polyester resins, natural resin-modified pentaerythritol resins and epoxy resins. 
     
     
         10 . A liquid electrostatographic toner or liquid ink jet ink as in  claim 1  wherein the colourant when present is selected from one or more of inorganic pigments selected from carbon blacks, silica, alumina, titanium dioxide, magnetic iron oxide, or organic pigments selected from phthalocyanine blue, alkali and reflex blue, phthalocyanine green, diarylide yellow, arylamide yellow, azo and diazo yellow, azo red, rubine toner, quinacridone red, basic dye complexes, lake red, or fluorescent pigments and dyestuffs selected from basic dyes and spirit soluble dyes or combinations thereof. 
     
     
         11 . A liquid electrostatographic toner or liquid ink jet ink as in  claim 1  wherein the carrier liquid is selected from the group comprising isoparaffinic-hydrocarbons, silicone fluids of straight chained configuration, silicone fluids of cyclic configuration, silicone fluid of branched configuration, vegetable oils, synthetic oils or polybutenes or blends thereof. 
     
     
         12 . A liquid electrostatographic toner or liquid ink jet ink as in  claim 4  wherein the charge control agent is selected from the group comprising metallic soaps, fatty acids, lecithin, organic phosphorus compounds, succinimides and sulphosuccinates. 
     
     
         13 . A liquid electrostatographic toner or liquid ink jet ink as in  claim 4  wherein the dispersion agent is selected from the group comprising polymeric hyperdispersants, amino-silicones, polymeric petroleum additives, polymeric oil additives and multi-functional pigment dispersing agents. 
     
     
         14 . A liquid electrostatographic toner or liquid ink jet ink prepared by a method including the steps of,
 a) preparing a resin system comprising a resin or resins with a colorant and a plasticiser, the resin system comprising;
 1 to 60% of the colourant; 
 1 to 20% plasticiser; and 
 resin or resins to 100% 
   b) coarse grinding the resin system,   c) milling the coarse ground resin system with a carrier liquid to produce a liquid marking particle mix,   d) heating the liquid marking particle mix to a temperature about or greater than the first softening point of the resin system of the marking particle mix to less than about the second softening point of the resin system,   e) maintaining the temperature of the heated marking particle mix for a selected period of time,   f) cooling the marking particle mix to room temperature, and   g) mixing the marking particle mix with high shear;   wherein the liquid electrostatographic toner or liquid ink jet ink comprises;
 1 to 60 percent marking particle mix by weight, 
 0.01 to 5 percent charge control agent, 
 0.1 to 20 percent dispersion agent, and 
 carrier liquid to 100 percent.