Compositions and methods for wastewater treatment

Abstract

Methods and compositions utilizing aluminum, magnesium, and calcium-based additives for the treatment and neutralization of wastewater are described for removing contaminants from wastewater, including reducing phosphorous-containing compounds, total suspended solids (TSS), biological oxygen demand (BOD), fats, oils, and greases (FOG), and total Kjedahl nitrogen (TKN) are described. Methods and compositions to control pH, sulfur and sodium loads present in wastewater and precipitatable solids are described. Concentrations of aluminum, magnesium, and calcium-based additives are maintained at mass action concentrations to the wastewater component levels present in the wastewater and bracketed approximately +/−0.5 pH units about the pK value of the soluble, buffering species.

1 . A composition for treating wastewater comprising:
 an effective amount of a magnesium additive for adding to the wastewater, wherein the magnesium additive includes at least one of magnesium oxide and magnesium hydroxide, and   an effective amount of an aluminum additive for adding to the wastewater having the magnesium additive, wherein the aluminum additive includes at least one of potassium aluminate and sodium aluminate,   wherein the effective amounts are combinable to form a composition comprising an alkaline formula capable of being added to the wastewater to control at least one of pH, solids settling, and solids compaction in the wastewater.   
     
     
         2 . A composition for treating wastewater comprising:
 an effective amount of a magnesium additive having at least one of magnesium oxide and magnesium hydroxide, and   an effective amount of an aluminum additive having at least one of potassium aluminate and sodium aluminate blended with the magnesium additive,   wherein the effective amounts are combinable to form a composition comprising an alkaline formula capable of being added to the wastewater to control at least one of pH, solids settling, and solids compaction in the wastewater.   
     
     
         3 . A composition for treating wastewater comprising:
 water;   an effective amount of a magnesium additive added to the water, wherein the magnesium additive includes at least one of magnesium oxide and magnesium hydroxide, and   an effective amount of an aluminum additive added to the water having the magnesium additive, wherein the aluminum additive includes at least one of potassium aluminate and sodium aluminate,   wherein the effective amounts are combined to form a composition comprising an alkaline formula capable of being added to the wastewater to control at least one of pH, solids settling, and solids compaction in the wastewater.   
     
     
         4 . The composition of  claim 3 , wherein the aluminum additive further includes at least one of potassium aluminate, sodium aluminate and aluminum trihydroxide. 
     
     
         5 . The composition of  claim 3 , further comprising effective amounts of an alkali having at least one at least one selected from the group consisting of calcium hydroxide, lime, hydrated lime, dolime, hydrated dolime, sodium hydroxide, potassium hydroxide, soda ash, and potash to maintain the wastewater pH within an approximate range between pH 4 and pH 11. 
     
     
         6 . The composition of  claim 3 , wherein the composition is formulated in a form of at least one of a solid and a liquid. 
     
     
         7 . The composition of  claim 3 , wherein the composition further includes a dispersant. 
     
     
         8 . The composition of  claim 7 , wherein the dispersant includes at least one selected from the group consisting of maleic acid, maleic anhydride, acrylic acid, methacrylic acid, crotonic acid, itaconic acid, mesaconic acid, fumaric acid, vinylphosphonic acid, vinylsulfonic acid citraconic acid, vinylacetic acid, acryloxypropionic acid, vinylsulfonic acid, styrenesulfonic acid, 2-acrylamido-2-methylpropanesulfonic acid, allylsulfonic acid, allylphosphonic acid, vinylphosphonic acid, vinylsulfonic acid, acrylic acid, methacrylic acid, and salts thereof. 
     
     
         9 . The composition of  claim 3 , wherein the composition is formulated in a form selected from the group consisting of a solid, a liquid and a viscosity-modifying agent. 
     
     
         10 . The composition of  claim 9 , wherein the viscosity-modifying agent includes at least one selected from the group consisting of formic acid, acetic acid, propionic acid, butyric acid, HCl, HNO 3 , HClO 4 , and any aluminum, ferric, magnesium, and any calcium and barium salts thereof. 
     
     
         11 . The composition of  claim 10 , wherein the viscosity-modifying agent includes at least one selected from the group consisting of mannitol, mono-, di- and trisaccharides, including sucrose and lactose, any manufacturing byproducts containing sugar-based organics substances, calcium oxide, and calcium hydroxide. 
     
     
         12 . The composition of  claim 3 , wherein the composition is formulated in a form selected from the group consisting of a solid, a liquid, a dispersant and a viscosity-modifying agent. 
     
     
         13 . The composition of  claim 3 , wherein the alkaline formula further includes effective amounts of the composition added to the wastewater to control the sulfate solubility and phosphate perceptibility in the wastewater. 
     
     
         14 . A method for treating wastewater to remove phosphorus-containing wastewater contaminants comprising:
 treating the wastewater with a composition comprising effective amounts of at least one of an aluminum-based additive and a magnesium-based additive,   wherein the effective amounts are added to the wastewater to control at least one of pH, solids settling, solids compaction in the wastewater, and phosphorous precipitability.   
     
     
         15 . The method of  claim 14 , wherein the magnesium-based additive comprises at least one selected from the group consisting of lime, dolime, sodium hydroxide, potassium hydroxide, soda ash, and potash. 
     
     
         16 . The method of  claim 14 , wherein the magnesium-based additive is formulated to be in a slurry. 
     
     
         17 . The method of  claim 16 , wherein the slurry includes a dispersant. 
     
     
         18 . The method of  claim 17 , wherein the dispersant includes at least one selected from the group consisting of homopolymers, copolymers, terpolymers having acid functionalities selected from the group consisting of maleic acid, maleic anhydride, acrylic acid, methacrylic acid, crotonic acid, itaconic acid, mesaconic acid, fumaric acid, vinylphosphonic acid, vinylsulfonic acid citraconic acid, vinylacetic acid, acryloxypropionic acid, vinylsulfonic acid, styrenesulfonic acid, 2-acrylamido-2-methylpropanesulfonic acid, allylsulfonic acid, allylphosphonic acid, vinylphosphonic acid, vinylsulfonic acid, acrylic acid, methacrylic acid, and salts thereof. 
     
     
         19 . The method of  claim 14 , wherein the slurry includes a viscosity-modifying agent. 
     
     
         20 . The method of  claim 19 , wherein the viscosity-modifying agent includes at least one selected from the consisting of formic acid, acetic acid, propionic acid, butyric acid, HCl, HNO 3 , HClO 4 , and any aluminum, ferric, magnesium, and any calcium and barium salts thereof. 
     
     
         21 . The method of  claim 19 , wherein the viscosity-modifying agent includes at least one selected from the consisting of mannitol, mono-, di- and trisaccharides, including sucrose and lactose, any manufacturing byproducts containing sugar-based organics substances, calcium oxide, and calcium hydroxide. 
     
     
         22 . The method of  claim 14 , wherein the slurry includes a dispersant and a viscosity-modifying agent. 
     
     
         23 . The method of  claim 14 , wherein the pH of the wastewater is adjusted to be between approximately pH 4 and pH 11.