US2011044934A1PendingUtilityA1
Textiles treated with copolymers of epoxy compounds and amino silanes
Est. expiryNov 2, 2027(~1.3 yrs left)· nominal 20-yr term from priority
Inventors:Benjamin Falk
C08L 83/04C08C 19/40C08F 8/32C08F 8/42C08G 59/1477C08G 59/4085C08G 77/12C08G 77/14C08G 77/20C08G 77/26C08G 77/388C08G 77/46C08G 77/50C08G 77/54C08G 77/80C08L 63/00C09D 183/08D06M 15/6436D06M 15/65C07F 7/1804Y10T428/249921Y10T442/20
60
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Claims
Abstract
The present invention provides for treating textiles with a composition comprising the reaction product of a) an oxirane or oxetane compound comprising at least two oxirane or oxetane groups; and b) an amino silane having the formula: N(H)(R 1 )R 2 Si(OR 3 ) 3-a-b-c (OR 4 ) a (R 5 Si(OR 6 ) d (R 7 ) e ) b R 8 c with R 1 is chosen from the group consisting of H or a monovalent hydrocarbon radical containing one to 20 carbon atoms; R 2 and R 5 are independently selected from a group consisting of oxygen or a divalent linear or branched hydrocarbon radical consisting of 1-60 carbons; R 4 is a hydrocarbon radical that contains 3 to 200 carbon atoms; R 3 , R 6 , R 7 , and R 8 and are each independently selected from the group of monovalent linear or branched hydrocarbon radicals having from 1 to 200 carbon atoms; the subscript b is zero or a positive number and has a value ranging from 0 to 3; the subscripts a, and c are zero or positive and have a value ranging from 0 to 3 subject to the limitation that (a+b+c)≦3; the subscripts d and e are zero or positive and have a value ranging from 0 to 3 subject to the limitation that (d+e)≦3, to impart an enhanced response to water.
Claims
exact text as granted — not AI-modified1 . A textile treated with a composition comprising the reaction product of
a) an oxirane or oxetane compound comprising at least two oxirane or oxetane groups; and b) an amino silane having the formula:
N(H)(R 1 )R 2 Si(OR 3 ) 3-a-b-c (OR 4 ) a (R 5 Si(OR 6 ) d (R 7 ) e ) b R 8 c
with R 1 is chosen from the group consisting of H or a monovalent hydrocarbon radical containing one to 20 carbon atoms; R 2 is selected from a group consisting of a divalent linear or branched hydrocarbon radical consisting of 1-60 carbons; R 4 is a hydrocarbon radical that contains 3 to 200 carbon atoms; R 5 is selected from a group consisting of oxygen or a divalent linear or branched hydrocarbon radical consisting of 1-60 carbons; R 3 , R 6 , R 7 , and R 8 and are each independently selected from the group of monovalent linear or branched hydrocarbon radicals having from 1 to 200 carbon atoms; the subscript b is zero or a positive number and has a value ranging from 0 to 3; the subscripts a, and c are zero or positive and have a value ranging from 0 to 3 subject to the limitation that (a+b+c)≦3; the subscripts d and e are zero or positive and have a value ranging from 0 to 3 subject to the limitation that (d+e)≦3, wherein said textile has an enhanced response to water.
2 . The composition of claim 1 where the oxirane or oxetane compound is selected from the group consisting of siloxanes, hydrocarbons and polyethers.
3 . The composition of claim 2 where the oxirane or oxetane compound is a siloxane having the formula:
M f M E h M PE i M H j D k D E l D PE m D H n T o T E p T PE q T H r Q s with
M=R 9 R 10 R 11 SiO 1/2 ;
M H =R 12 R 13 HSiO 1/2 ;
M PE =R 12 R 13 (—CH 2 CH(R 14 )(R 15 ) t O(R 16 ) u (C 2 H 4 O) v (C 3 H 6 O) w (C 4 H 8 O) x R 17 )SiO 1/2 ;
M E =R 12 R 13 (R E )SiO 1/2
D=R 18 R 19 SiO 2/2 ; and
D H =R 20 HSiO 2/2
D PE =R 20 (—CH 2 CH(R 14 )(R 15 ) t O(R 16 ) u (C 2 H 4 O) v (C 3 H 6 O) w (C 4 H 8 O) x R 17 )SiO 2/2
D E =R 20 R E SiO 2/2 .
T=R 21 SiO 3/2 ;
T H =HSiO 3/2 ;
T PE =(—CH 2 CH(R 14 )(R 15 ) t O(R 16 ) u (C 2 H 4 O) v (C 3 H 6 O) w (C 4 H 8 O) x R 17 )SiO 3/2 ;
T E =R E SiO 3/2 ; and
Q=SiO 4/2 ;
where R 9 , R 10 , R 11 , R 12 , R 13 , R 18 , R 19 , R 20 , and R 21 are each independently selected from the group of monovalent hydrocarbon radicals having from 1 to 60 carbon atoms;
R 14 is H or a 1 to 6 carbon atom alkyl group; R 15 is a divalent alkyl radical of 1 to 6 carbons; R 16 is selected from the group of divalent radicals consisting of —C 3 H 6 O—, and —C 4 H 8 O—; R 17 is selected from the group consisting of H, monofunctional hydrocarbon radicals of 1 to 6 carbons, and acetyl;
R E is independently a monovalent hydrocarbon radical containing one or more oxirane or oxetane moieties having from one to sixty carbon atoms;
the subscript f may be zero or positive subject to the limitation that when the subscript f is zero, h must be positive;
the subscript h is zero or positive subject to the limitations that when h is zero, the subscript f is positive, and that the sum of the subscripts h, l and p is positive;
the subscript k is zero or positive and has a value ranging from about 0 to about 1,000;
the subscript l is zero or positive and has a value ranging from about 0 to about 400 subject to the limitation that the sum of the subscripts h, l and p is positive;
the subscript o is zero or positive and has a value ranging from 0 to about 50;
the subscript p is zero or positive and has a value ranging from 0 to about 30 subject to the limitation that the sum of the subscripts h, l and p is positive;
the subscript s is zero or positive and has a value ranging from 0 to about 20;
the subscript i is zero or positive and has a value ranging from 0 to about 20;
the subscript m is zero or positive and has a value ranging from 0 to about 200;
the subscript q is zero or positive and has a value ranging from 0 to about 30;
the subscript j is zero or positive and has a value ranging from 0 to about 2;
the subscript n is zero or positive and has a value ranging from 0 to about 20;
the subscript r is zero or positive and has a value ranging from 0 to about 30;
the subscript t is zero or one;
the subscript u is zero or one;
the subscript v is zero or positive and has a value ranging from 0 to about 100 subject to the limitation that (v+w+x)>0;
the subscript w is zero or positive and has a value ranging from 0 to about 100 subject to the limitation that (v+w+x)>0;
the subscript x is zero or positive and has a value ranging from 0 to about 100 subject to the limitation that (v+w+x)>0;
4 . The composition of claim 1 where the oxirane or oxetane compound is a hydrocarbon having the formula:
R 22 y (R 23 ) z (R 24 α )(R 25 ) β
where R 22 and R 25 are independently a monovalent hydrocarbon radical containing one or more oxirane or oxetane moieties having from 3 to 12 carbon atoms;
R 23 and R 24 are each selected from the group consisting of H or a linear or branched monovalent hydrocarbon radical of 1 to 1000 carbons;
the subscripts y, z, α, β are zero or positive ranging from zero to four subject to the limitation that (y+β)>2.
5 . The composition of claim 2 where the oxirane or oxetane compound is a polyether having the formula:
R 26 O(R 27 ) γ (C 2 H 4 O) δ (C 3 H 6 O) ε (C 4 H 8 O) ζ R 28
where R 26 and R 28 are independently a monovalent hydrocarbon radical containing one or more oxirane or oxetane moieties having from 3 to 12 carbon atoms;
R 27 is selected from the group of divalent radicals consisting of —C 2 H 4 O—, —C 3 H 6 O—, and —C 4 H 8 O—;
the subscript γ is zero or 1;
the subscript δ is zero or positive and has a value ranging from 0 to about 100 subject to the limitation that (δ+εαζ)>0;
the subscript ε is zero or positive and has a value ranging from 0 to about 100 subject to the limitation that (δ+εαζ)>0;
the subscript ζ is zero or positive and has a value ranging from 0 to about 100 subject to the limitation that (δ+εαζ)>0.
6 . The reaction product of claim 1 further comprising the reaction product of a compound having the formula:
R 29 (R 30 ) κ Si(OR 31 ) 3-η-θ (R 32 ) η (OR 33 ) θ
where R 29 is a monovalent hydrocarbon radical containing one or more oxirane or oxetane moieties having from 3 to 12 carbon atoms;
R 30 is a divalent hydrocarbon radical consisting of 1-60 carbons and the subscript κ has a value of zero or 1; R 31 and R 32 are independently selected from the group of monovalent linear or branched hydrocarbon radicals having from 1 to 60 carbon atoms;
the subscript η is zero or positive and has a value ranging from 0 to 3;
the subscript θ is greater than 0 and less than or equal to 3, subject to the limitation that 3-η-θ is greater than or equal to zero;
R 33 is a hydrocarbon radical that contains 3 to 200 carbon atoms.
7 . The reaction product of claim 1 wherein
R 1 has from one to ten carbon atoms;
R 2 has from one to ten carbon atoms;
R 4 has from three to ten carbon atoms;
R 3 , R 6 , R 7 , and R 8 each independently have from one to twenty carbon atoms;
the subscript a ranges from 1 to 3;
the subscript b ranges from 0 to 25 more;
the subscript c ranges from 0 to 3;
R 9 , R 10 , R 11 , R 12 , R 13 , R 18 , R 19 , R 20 , and R 21 each independently have from one to four carbon atoms;
the subscripts f, l, m, n, o, p, q, r, each independently range from 0 to 200;
the subscript k ranges from 0-500;
the subscripts v, w, and x each independently range from 0 to 50;
R 23 and R 24 each independently have from five to one thousand carbon atoms;
subscripts δ, ε, ζ each independently range from 0 to 50;
R 31 and R 32 each independently have from one to ten carbon atoms and
R 33 has from three to one hundred carbon atoms.
8 . The reaction product of claim 1 wherein
R 1 has from one to five carbon atoms;
R 2 has from two to eight carbon atoms;
R 4 has from three to eight carbon atoms;
R 3 , R 6 , R 7 , and R 8 each independently have from one to fifteen carbon atoms;
the subscript a ranges from 2 to 3;
the subscript b ranges from 0 to 15 more;
the subscript c ranges from 0 to 2;
R 9 , R 10 , R 11 , R 12 , R 13 , R 18 , R 19 , R 20 , and R 21 each independently have from one to three carbon atoms;
the subscripts f, l, m, n, o, p, q, r, each independently range from 0 to 100;
the subscript k ranges from 5-250;
the subscripts v, w, and x each independently range from 0 to 35;
R 23 and R 24 each independently have from ten to five hundred carbon atoms;
subscripts δ, ε, ζ each independently range from 0 to 30;
R 31 and R 32 each independently have from one to eight carbon atoms and
R 33 has from three to fifty carbon atoms.
9 . The reaction product of claim 1 wherein
R 1 is hydrogen;
R 2 has from two to five carbon atoms;
R 4 has from three to five carbon atoms;
R 3 , R 6 , R 7 , and R 8 each independently have from two to eight carbon atoms;
the subscript a is 0 or 1;
the subscript b is 3;
the subscript c is 0 or 1;
R 9 , R 10 , R 11 , R 12 , R 13 , R 18 , R 19 , R 20 , and R 21 each independently methyl;
the subscripts f, l, m, n, o, p, q, r, each independently range from 0 to 50;
the subscript k ranges from 5 to 150;
the subscripts v, w, and x each independently range from 0 to 25;
R 23 and R 24 each independently have from five to one thousand carbon atoms;
subscripts δ, ε, ζ each independently range from 0 to 15;
R 31 and R 32 each independently have from one to four carbon atoms and
R 33 has from three to ten carbon atoms.
10 . The reaction product of claim 6 wherein
R 1 has from one to ten carbon atoms;
R 2 has from one to ten carbon atoms;
R 4 has from three to ten carbon atoms;
R 3 , R 6 , R 7 , and R 8 each independently have from one to twenty carbon atoms;
the subscript a ranges from 1 to 3;
the subscript b ranges from 0 to 25 more;
the subscript c ranges from 0 to 3;
R 9 , R 10 , R 11 , R 12 , R 13 , R 18 , R 19 , R 20 , and R 21 each independently have from one to four carbon atoms;
the subscripts f, l, m, n, o, p, q, r, each independently range from 0 to 200;
the subscript k ranges from 0-500;
the subscripts v, w, and x each independently range from 0 to 50;
R 23 and R 24 each independently have from five to one thousand carbon atoms more preferred 10-500 most preferred 10-300;
subscripts δ, ε, ζ each independently range from 0 to 50;
R 31 and R 32 each independently have from one to ten carbon atoms and
R 33 has from three to one hundred carbon atoms.
11 . An aqueous emulsion where the discontinuous phase comprises water and the emulsion comprises the composition of claim 1 .
12 . An aqueous emulsion where the discontinuous phase comprises water and the emulsion comprises the composition of claim 2 .
13 . An aqueous emulsion where the discontinuous phase comprises water and the emulsion comprises the composition of claim 3 .
14 . An aqueous emulsion where the discontinuous phase comprises water and the emulsion comprises the composition of claim 4 .
15 . An aqueous emulsion where the discontinuous phase comprises water and the emulsion comprises the composition of claim 5 .
16 . An aqueous emulsion where the discontinuous phase comprises water and the emulsion comprises the composition of claim 6 .
17 . An aqueous emulsion where the discontinuous phase comprises water and the emulsion comprises the composition of claim 7 .
18 . An aqueous emulsion where the discontinuous phase comprises water and the emulsion comprises the composition of claim 8 .
19 . An aqueous emulsion where the discontinuous phase comprises water and the emulsion comprises the composition of claim 9 .
20 . An aqueous emulsion where the discontinuous phase comprises water and the emulsion comprises the composition of claim 10 .
21 . An aqueous emulsion where the continuous phase comprises water and the emulsion comprises the composition of claim 1 .
22 . An aqueous emulsion where the continuous phase comprises water and the emulsion comprises the composition of claim 2 .
23 . An aqueous emulsion where the continuous phase comprises water and the emulsion comprises the composition of claim 3 .
24 . An aqueous emulsion where the continuous phase comprises water and the emulsion comprises the composition of claim 4 .
25 . An aqueous emulsion where the continuous phase comprises water and the emulsion comprises the composition of claim 5 .
26 . An aqueous emulsion where the continuous phase comprises water and the emulsion comprises the composition of claim 6 .
27 . An aqueous emulsion where the continuous phase comprises water and the emulsion comprises the composition of claim 7 .
28 . An aqueous emulsion where the continuous phase comprises water and the emulsion comprises the composition of claim 8 .
29 . An aqueous emulsion where the continuous phase comprises water and the emulsion comprises the composition of claim 9 .
30 . An aqueous emulsion where the continuous phase comprises water and the emulsion comprises the composition of claim 10 .
31 . An non-aqueous emulsion where the discontinuous phase comprises a non-aqueous hydroxylic solvent and the emulsion comprises the composition of claim 1 .
32 . An non-aqueous emulsion where the discontinuous phase comprises a non-aqueous hydroxylic organic solvent and the emulsion comprises the composition of claim 2 .
33 . An non-aqueous emulsion where the discontinuous phase comprises a non-aqueous hydroxylic organic solvent and the emulsion comprises the composition of claim 3 .
34 . An non-aqueous emulsion where the discontinuous phase comprises a non-aqueous hydroxylic organic solvent and the emulsion comprises the composition of claim 4 .
35 . An non-aqueous emulsion where the discontinuous phase comprises a non-aqueous hydroxylic organic solvent and the emulsion comprises the composition of claim 5 .
36 . An non-aqueous emulsion where the discontinuous phase comprises a non-aqueous hydroxylic organic solvent and the emulsion comprises the composition of claim 6 .
37 . An non-aqueous emulsion where the discontinuous phase comprises a non-aqueous hydroxylic organic solvent and the emulsion comprises the composition of claim 7 .
38 . An non-aqueous emulsion where the discontinuous phase comprises a non-aqueous hydroxylic organic solvent and the emulsion comprises the composition of claim 8 .
39 . An non-aqueous emulsion where the discontinuous phase comprises a non-aqueous hydroxylic organic solvent and the emulsion comprises the composition of claim 9 .
40 . An non-aqueous emulsion where the discontinuous phase comprises a non-aqueous hydroxylic organic solvent and the emulsion comprises the composition of claim 10 .
41 . A non-aqueous emulsion where the continuous phase comprises a non-aqueous hydroxylic organic solvent and the emulsion comprises the composition of claim 1 .
42 . An non-aqueous emulsion where the continuous phase comprises a non-aqueous hydroxylic organic solvent and the emulsion comprises the composition of claim 2 .
43 . An non-aqueous emulsion where the continuous phase comprises a non-aqueous hydroxylic organic solvent and the emulsion comprises the composition of claim 3 .
44 . An non-aqueous emulsion where the continuous phase comprises a non-aqueous hydroxylic organic solvent and the emulsion comprises the composition of claim 4 .
45 . An non-aqueous emulsion where the continuous phase comprises a non-aqueous hydroxylic organic solvent and the emulsion comprises the composition of claim 5 .
46 . An non-aqueous emulsion where the continuous phase comprises a non-aqueous hydroxylic organic solvent and the emulsion comprises the composition of claim 6 .
47 . An non-aqueous emulsion where the continuous phase comprises a non-aqueous hydroxylic organic solvent and the emulsion comprises the composition of claim 7 .
48 . An non-aqueous emulsion where the continuous phase comprises a non-aqueous hydroxylic organic solvent and the emulsion comprises the composition of claim 8 .
49 . An non-aqueous emulsion where the continuous phase comprises a non-aqueous hydroxylic organic solvent and the emulsion comprises the composition of claim 9 .
50 . An non-aqueous emulsion where the continuous phase comprises a non-aqueous hydroxylic organic solvent and the emulsion comprises the composition of claim 10 .
51 . Method for treating a textile, comprising the steps of
(i) applying to the textile, a composition comprising the reaction product of
(a) an oxirane or oxetane compound comprising at least two oxirane or oxetane groups; and
(b) an amino silane having the formula:
N(H)(R 1 )R 2 Si(OR 3 ) 3-a-b-c (OR 4 ) a (R 5 Si(OR 6 ) d (R 7 ) e ) b R 8 c
with R 1 is chosen from the group consisting of H or a monovalent hydrocarbon radical containing one to 20 carbon atoms; R 2 is selected from a group consisting of a divalent linear or branched hydrocarbon radical consisting of 1-60 carbons; R 4 is a hydrocarbon radical that contains 3 to 200 carbon atoms; R 5 is selected from a group consisting of oxygen or a divalent linear or branched hydrocarbon radical consisting of 1-60 carbons; R 3 , R 6 , R 7 , and R 8 and are each independently selected from the group of monovalent linear or branched hydrocarbon radicals having from 1 to 200 carbon atoms; the subscript b is zero or a positive number and has a value ranging from 0 to 3; the subscripts a, and c are zero or positive and have a value ranging from 0 to 3 subject to the limitation that (a+b+c)≦3; the subscripts d and e are zero or positive and have a value ranging from 0 to 3 subject to the limitation that (d+e)≦3, wherein said textile has an enhanced response to water, and (ii) curing.
52 . The method of claim 51 wherein the oxirane or oxetane compound is selected from the group consisting of siloxanes, hydrocarbons and polyethers.
53 . The method of claim 52 wherein the oxirane or oxetane compound is a siloxane having the formula:
M f M E h M PE i M H j D k D E l D PE m D H n T o T E p T PE q T H r Q s with
M=R 9 R 10 R 11 SiO 1/2 ;
M H =R 12 R 13 HSiO 1/2 ;
M PE =R 12 R 13 (—CH 2 CH(R 14 )(R 15 ) t O(R 16 ) u (C 2 H 4 O) v (C 3 H 6 O) w (C 4 H 8 O) x R 17 )SiO 1/2 ;
M E =R 12 R 13 (R E )SiO 1/2
D=R 18 R 19 SiO 2/2 ; and
D H =R 20 HSiO 2/2
D PE =R 20 (—CH 2 CH(R 14 )(R 15 ) t O(R 16 ) u (C 2 H 4 O) v (C 3 H 6 O) w (C 4 H 8 O) x R 17 )SiO 2/2
D E =R 20 R E SiO 2/2 .
T=R 21 SiO 3/2 ;
T H =HSiO 3/2 ;
T PE =(—CH 2 CH(R 14 )(R 15 ) t O(R 16 ) u (C 2 H 4 O) v (C 3 H 6 O) w (C 4 H 8 O) x R 17 )SiO 3/2 ;
T E =R E SiO 3/2 ; and
Q=SiO 4/2 ;
where R 9 , R 10 , R 11 , R 12 , R 13 , R 18 , R 19 , R 20 , and R 21 are each independently selected from the group of monovalent hydrocarbon radicals having from 1 to 60 carbon atoms;
R 14 is H or a 1 to 6 carbon atom alkyl group; R 15 is a divalent alkyl radical of 1 to 6 carbons; R 16 is selected from the group of divalent radicals consisting of —C 2 H 4 O—, —C 3 H 8 O—, and —C 4 H 8 O—; R 17 is selected from the group consisting of H, monofunctional hydrocarbon radicals of 1 to 6 carbons, and acetyl;
R E is independently a monovalent hydrocarbon radical containing one or more oxirane or oxetane moieties having from one to sixty carbon atoms;
the subscript f may be zero or positive subject to the limitation that when the subscript f is zero, h must be positive;
the subscript h is zero or positive subject to the limitations that when h is zero, the subscript f is positive, and that the sum of the subscripts h, l and p is positive;
the subscript k is zero or positive and has a value ranging from about 0 to about 1,000;
the subscript l is zero or positive and has a value ranging from about 0 to about 400 subject to the limitation that the sum of the subscripts h, l and p is positive;
the subscript o is zero or positive and has a value ranging from 0 to about 50;
the subscript p is zero or positive and has a value ranging from 0 to about 30 subject to the limitation that the sum of the subscripts h, l and p is positive;
the subscript s is zero or positive and has a value ranging from 0 to about 20;
the subscript i is zero or positive and has a value ranging from 0 to about 20;
the subscript m is zero or positive and has a value ranging from 0 to about 200;
the subscript q is zero or positive and has a value ranging from 0 to about 30;
the subscript j is zero or positive and has a value ranging from 0 to about 2;
the subscript n is zero or positive and has a value ranging from 0 to about 20;
the subscript r is zero or positive and has a value ranging from 0 to about 30;
the subscript t is zero or one;
the subscript u is zero or one;
the subscript v is zero or positive and has a value ranging from 0 to about 100 subject to the limitation that (v+w+x)>0;
the subscript w is zero or positive and has a value ranging from 0 to about 100 subject to the limitation that (v+w+x)>0;
the subscript x is zero or positive and has a value ranging from 0 to about 100 subject to the limitation that (v+w+x)>0;
54 . The method of claim 51 wherein the oxirane or oxetane compound is a hydrocarbon having the formula:
R 22 y (R 23 ) z (R 24 α )(R 25 ) β
where R 22 and R 25 are independently a monovalent hydrocarbon radical containing one or more oxirane or oxetane moieties having from 3 to 12 carbon atoms;
R 23 and R 24 are each selected from the group consisting of H or a linear or branched monovalent hydrocarbon radical of 1 to 1000 carbons;
the subscripts y, z, α, β are zero or positive ranging from zero to four subject to the limitation that (y+β)>2.
55 . The method of claim 52 wherein the oxirane or oxetane compound is a polyether having the formula:
R 26 O(R 27 ) γ (C 2 H 4 O) δ (C 3 H 6 O) ε (C 4 H 8 O) ζ R 28
where R 26 and R 28 are independently a monovalent hydrocarbon radical containing one or more oxirane or oxetane moieties having from 3 to 12 carbon atoms;
R 27 is selected from the group of divalent radicals consisting of —C 2 H 4 O—, —C 3 H 6 O—, and —C 4 H 8 O—;
the subscript γ is zero or 1;
the subscript δ is zero or positive and has a value ranging from 0 to about 100 subject to the limitation that (δ+ε+ζ)>0;
the subscript ε is zero or positive and has a value ranging from 0 to about 100 subject to the limitation that (δ+ε+ζ)>0;
the subscript ζ is zero or positive and has a value ranging from 0 to about 100 subject to the limitation that (δ+ε+ζ)>0.
56 . The method of claim 51 , wherein the composition is an emulsion having a continuous phase comprising the reaction product and a discontinuous phase comprising water.
57 . The method of claim 51 , wherein the composition is an emulsion having a discontinuous phase comprising the reaction product and a continuous phase comprising water.
58 . Method of treating with a pesticide comprising adding to the pesticide, a composition comprising the reaction product of
(ii) an oxirane or oxetane compound comprising at least two oxirane or oxetane groups; and (iii) an amino silane having the formula:
N(H)(R 1 )R 2 Si(OR 3 ) 3-a-b-c (OR 4 ) a (R 5 Si(OR 6 ) d (R 7 ) e ) b R 8 c
with R 1 is chosen from the group consisting of H or a monovalent hydrocarbon radical containing one to 20 carbon atoms; R 2 is selected from a group consisting of a divalent linear or branched hydrocarbon radical consisting of 1-60 carbons; R 4 is a hydrocarbon radical that contains 3 to 200 carbon atoms; R 5 is selected from a group consisting of oxygen or a divalent linear or branched hydrocarbon radical consisting of 1-60 carbons; R 3 , R 6 , R 7 , and R 8 and are each independently selected from the group of monovalent linear or branched hydrocarbon radicals having from 1 to 200 carbon atoms; the subscript b is zero or a positive number and has a value ranging from 0 to 3; the subscripts a, and c are zero or positive and have a value ranging from 0 to 3 subject to the limitation that (a+b+c)≦3; the subscripts d and e are zero or positive and have a value ranging from 0 to 3 subject to the limitation that (d+e)≦3, wherein said textile has an enhanced response to water.
59 . The method of claim 58 wherein the oxirane or oxetane compound is selected from the group consisting of siloxanes, hydrocarbons and polyethers.
60 . The method of claim 59 wherein the oxirane or oxetane compound is a siloxane having the formula:
M f M E h M PE i M H j D k D E l D PE m D H n T o T E p T PE q T H r Q s with
M=R 9 R 10 R 11 SiO 1/2 ;
M H =R 12 R 13 HSiO 1/2 ;
M PE =R 12 R 13 (—CH 2 CH(R 14 )(R 15 ) t O(R 16 ) u (C 2 H 4 O) v (C 3 H 6 O) w (C 4 H 8 O) x R 17 )SiO 1/2 ;
M E =R 12 R 13 (R E )SiO 1/2
D=R 18 R 19 SiO 2/2 ; and
D H =R 20 HSiO 2/2
D PE =R 20 (—CH 2 CH(R 14 )(R 15 ) t O(R 16 ) u (C 2 H 4 O) v (C 3 H 6 O) w (C 4 H 8 O) x R 17 )SiO 2/2
D E =R 20 R E SiO 2/2 .
T=R 21 SiO 3/2 ;
T H =HSiO 3/2 ;
T PE =(—CH 2 CH(R 14 )(R 15 ) t O(R 16 ) u (C 2 H 4 O) v (C 3 H 6 O) w (C 4 H 8 O) x R 17 )SiO 3/2 ;
T E =R E SiO 3/2 ; and
Q=SiO 4/2 ;
where R 9 , R 10 , R 11 , R 12 , R 13 , R 18 , R 19 , R 20 , and R 21 are each independently selected from the group of monovalent hydrocarbon radicals having from 1 to 60 carbon atoms;
R 14 is H or a 1 to 6 carbon atom alkyl group; R 15 is a divalent alkyl radical of 1 to 6 carbons; R 16 is selected from the group of divalent radicals consisting of —C 3 H 6 O—, and —C 4 H 8 O—; R 17 is selected from the group consisting of H, monofunctional hydrocarbon radicals of 1 to 6 carbons, and acetyl;
R E is independently a monovalent hydrocarbon radical containing one or more oxirane or oxetane moieties having from one to sixty carbon atoms;
the subscript f may be zero or positive subject to the limitation that when the subscript f is zero, h must be positive;
the subscript h is zero or positive subject to the limitations that when h is zero, the subscript f is positive, and that the sum of the subscripts h, l and p is positive;
the subscript k is zero or positive and has a value ranging from about 0 to about 1,000;
the subscript l is zero or positive and has a value ranging from about 0 to about 400 subject to the limitation that the sum of the subscripts h, l and p is positive;
the subscript o is zero or positive and has a value ranging from 0 to about 50;
the subscript p is zero or positive and has a value ranging from 0 to about 30 subject to the limitation that the sum of the subscripts h, l and p is positive;
the subscript s is zero or positive and has a value ranging from 0 to about 20;
the subscript i is zero or positive and has a value ranging from 0 to about 20;
the subscript m is zero or positive and has a value ranging from 0 to about 200;
the subscript q is zero or positive and has a value ranging from 0 to about 30;
the subscript j is zero or positive and has a value ranging from 0 to about 2;
the subscript n is zero or positive and has a value ranging from 0 to about 20;
the subscript r is zero or positive and has a value ranging from 0 to about 30;
the subscript t is zero or one;
the subscript u is zero or one;
the subscript v is zero or positive and has a value ranging from 0 to about 100 subject to the limitation that (v+w+x)>0;
the subscript w is zero or positive and has a value ranging from 0 to about 100 subject to the limitation that (v+w+x)>0;
the subscript x is zero or positive and has a value ranging from 0 to about 100 subject to the limitation that (v+w+x)>0;
61 . The method of claim 59 wherein the oxirane or oxetane compound is a hydrocarbon having the formula:
R 22 y (R 23 ) z (R 24 α )(R 25 ) β
where R 22 and R 25 are independently a monovalent hydrocarbon radical containing one or more oxirane or oxetane moieties having from 3 to 12 carbon atoms;
R 23 and R 24 are each selected from the group consisting of H or a linear or branched monovalent hydrocarbon radical of 1 to 1000 carbons;
the subscripts y, z, α, β are zero or positive ranging from zero to four subject to the limitation that (y+β)>2.
62 . The method of claim 59 wherein the oxirane or oxetane compound is a polyether having the formula:
R 26 O(R 27 ) γ (C 2 H 4 O) δ (C 3 H 6 O) ε (C 4 H 8 O) ζ R 28
where R 26 and R 28 are independently a monovalent hydrocarbon radical containing one or more oxirane or oxetane moieties having from 3 to 12 carbon atoms;
R 27 is selected from the group of divalent radicals consisting of —C 2 H 4 O—, —C 3 H 6 O—, and —C 4 H 8 O—;
the subscript γ is zero or 1;
the subscript δ is zero or positive and has a value ranging from 0 to about 100 subject to the limitation that (δ+ε+ζ)>0;
the subscript ε is zero or positive and has a value ranging from 0 to about 100 subject to the limitation that (δ+ε+ζ)>0;
the subscript ζ is zero or positive and has a value ranging from 0 to about 100 subject to the limitation that (δ+ε+ζ)>0.
63 . The method of claim 58 , wherein the composition is an emulsion having a continuous phase comprising the reaction product and a discontinuous phase comprising water.
64 . The method of claim 58 , wherein the composition is an emulsion having a discontinuous phase comprising the reaction product and a continuous phase comprising water.
65 . Method of apply a coating, comprising adding to the coating, a composition comprising the reaction product of
(iv) an oxirane or oxetane compound comprising at least two oxirane or oxetane groups; and (v) an amino silane having the formula:
N(H)(R 1 )R 2 Si(OR 3 ) 3-a-b-c (OR 4 ) a (R 5 Si(OR 6 ) d (R 7 ) e ) b R 8 c
with R 1 is chosen from the group consisting of H or a monovalent hydrocarbon radical containing one to 20 carbon atoms; R 2 is selected from a group consisting of a divalent linear or branched hydrocarbon radical consisting of 1-60 carbons; R 4 is a hydrocarbon radical that contains 3 to 200 carbon atoms; R 5 is selected from a group consisting of oxygen or a divalent linear or branched hydrocarbon radical consisting of 1-60 carbons; R 3 , R 6 , R 7 , and R 8 and are each independently selected from the group of monovalent linear or branched hydrocarbon radicals having from 1 to 200 carbon atoms; the subscript b is zero or a positive number and has a value ranging from 0 to 3; the subscripts a, and c are zero or positive and have a value ranging from 0 to 3 subject to the limitation that (a+b+c)≦3; the subscripts d and e are zero or positive and have a value ranging from 0 to 3 subject to the limitation that (d+e)≦3, wherein said textile has an enhanced response to water.
66 . The method of claim 65 wherein the oxirane or oxetane compound is selected from the group consisting of siloxanes, hydrocarbons and polyethers.
67 . The method of claim 66 wherein the oxirane or oxetane compound is a siloxane having the formula:
M f M E h M PE i M H j D k D E l D PE m D H n T o T E p T PE q T H r Q s with
M=R 9 R 10 R 11 SiO 1/2 ;
M H =R 12 R 13 HSiO 1/2 ;
M PE =R 12 R 13 (—CH 2 CH(R 14 )(R 15 ) t O(R 16 ) u (C 2 H 4 O) v (C 3 H 6 O) w (C 4 H 8 O) x R 17 )SiO 1/2 ;
M E =R 12 R 13 (R E )SiO 1/2
D=R 18 R 19 SiO 2/2 ; and
D H =R 20 HSiO 2/2
D PE =R 20 (—CH 2 CH(R 14 )(R 15 ) t O(R 16 ) u (C 2 H 4 O) v (C 3 H 6 O) w (C 4 H 8 O) x R 17 )SiO 2/2
D E =R 20 R E SiO 2/2 .
T=R 21 SiO 3/2 ;
T H =HSiO 3/2 ;
T PE =(—CH 2 CH(R 14 )(R 15 ) t O(R 16 ) u (C 2 H 4 O) v (C 3 H 6 O) w (C 4 H 8 O) x R 17 )SiO 3/2 ;
T E =R E SiO 3/2 ; and
Q=SiO 4/2 ;
where R 9 , R 10 , R 11 , R 12 , R 13 , R 18 , R 19 , R 20 , and R 21 are each independently selected from the group of monovalent hydrocarbon radicals having from 1 to 60 carbon atoms;
R 14 is H or a 1 to 6 carbon atom alkyl group; R 15 is a divalent alkyl radical of 1 to 6 carbons; R 16 is selected from the group of divalent radicals consisting of —C 2 H 4 O—, —C 3 H 6 O—, and —C 4 H 8 O—; R 17 is selected from the group consisting of H, monofunctional hydrocarbon radicals of 1 to 6 carbons, and acetyl;
R E is independently a monovalent hydrocarbon radical containing one or more oxirane or oxetane moieties having from one to sixty carbon atoms;
the subscript f may be zero or positive subject to the limitation that when the subscript f is zero, h must be positive;
the subscript h is zero or positive subject to the limitations that when h is zero, the subscript f is positive, and that the sum of the subscripts h, l and p is positive;
the subscript k is zero or positive and has a value ranging from about 0 to about 1,000;
the subscript l is zero or positive and has a value ranging from about 0 to about 400 subject to the limitation that the sum of the subscripts h, l and p is positive;
the subscript o is zero or positive and has a value ranging from 0 to about 50;
the subscript p is zero or positive and has a value ranging from 0 to about 30 subject to the limitation that the sum of the subscripts h, l and p is positive;
the subscript s is zero or positive and has a value ranging from 0 to about 20;
the subscript i is zero or positive and has a value ranging from 0 to about 20;
the subscript m is zero or positive and has a value ranging from 0 to about 200;
the subscript q is zero or positive and has a value ranging from 0 to about 30;
the subscript j is zero or positive and has a value ranging from 0 to about 2;
the subscript n is zero or positive and has a value ranging from 0 to about 20;
the subscript r is zero or positive and has a value ranging from 0 to about 30;
the subscript t is zero or one;
the subscript u is zero or one;
the subscript v is zero or positive and has a value ranging from 0 to about 100 subject to the limitation that (v+w+x)>0;
the subscript w is zero or positive and has a value ranging from 0 to about 100 subject to the limitation that (v+w+x)>0;
the subscript x is zero or positive and has a value ranging from 0 to about 100 subject to the limitation that (v+w+x)>0;
68 . The method of claim 65 wherein the oxirane or oxetane compound is a hydrocarbon having the formula:
R 22 y (R 23 ) z (R 24 α )(R 25 ) β
where R 22 and R 25 are independently a monovalent hydrocarbon radical containing one or more oxirane or oxetane moieties having from 3 to 12 carbon atoms;
R 23 and R 24 are each selected from the group consisting of H or a linear or branched monovalent hydrocarbon radical of 1 to 1000 carbons;
the subscripts y, z, α, β are zero or positive ranging from zero to four subject to the limitation that (y+β)>2.
69 . The method of claim 66 wherein the oxirane or oxetane compound is a polyether having the formula:
R 26 O(R 27 ) γ (C 2 H 4 O) δ (C 3 H 6 O) ε (C 4 H 8 O) ζ R 28
where R 26 and R 28 are independently a monovalent hydrocarbon radical containing one or more oxirane or oxetane moieties having from 3 to 12 carbon atoms;
R 27 is selected from the group of divalent radicals consisting of —C 2 H 4 O—, —C 3 H 6 O—, and —C 4 H 8 O—;
the subscript γ is zero or 1;
the subscript δ is zero or positive and has a value ranging from 0 to about 100 subject to the limitation that (δ+ε+ζ)>0;
the subscript ε is zero or positive and has a value ranging from 0 to about 100 subject to the limitation that (δ+ε+ζ)>0;
the subscript ζ is zero or positive and has a value ranging from 0 to about 100 subject to the limitation that (δ+ε+ζ)>0.
70 . The method of claim 66 , wherein the composition is an emulsion having a continuous phase comprising the reaction product and a discontinuous phase comprising water.
71 . The method of claim 66 , wherein the composition is an emulsion having a discontinuous phase comprising the reaction product and a continuous phase comprising water.
72 . Method of topically applying a personal care composition, comprising adding to the personal care composition, a composition comprising the reaction product of
(vi) an oxirane or oxetane compound comprising at least two oxirane or oxetane groups; and (vii) an amino silane having the formula:
N(H)(R 1 )R 2 Si(OR 3 ) 3-a-b-c (OR 4 ) a (R 5 Si(OR 6 ) d (R 7 ) e ) b R 8 c
with R 1 is chosen from the group consisting of H or a monovalent hydrocarbon radical containing one to 20 carbon atoms; R 2 is selected from a group consisting of a divalent linear or branched hydrocarbon radical consisting of 1-60 carbons; R 4 is a hydrocarbon radical that contains 3 to 200 carbon atoms; R 5 is selected from a group consisting of oxygen or a divalent linear or branched hydrocarbon radical consisting of 1-60 carbons; R 3 , R 6 , R 7 , and R 8 and are each independently selected from the group of monovalent linear or branched hydrocarbon radicals having from 1 to 200 carbon atoms; the subscript b is zero or a positive number and has a value ranging from 0 to 3; the subscripts a, and c are zero or positive and have a value ranging from 0 to 3 subject to the limitation that (a+b+c)≦3; the subscripts d and e are zero or positive and have a value ranging from 0 to 3 subject to the limitation that (d+e)≦3, wherein said textile has an enhanced response to water.
73 . The method of claim 72 wherein the oxirane or oxetane compound is selected from the group consisting of siloxanes, hydrocarbons and polyethers.
74 . The method of claim 73 wherein the oxirane or oxetane compound is a siloxane having the formula:
M f M E h M PE i M H j D k D E l D PE m D H n T o T E p T PE q T H r Q s with
M=R 9 R 10 R 11 SiO 1/2 ;
M H =R 12 R 13 HSiO 1/2 ;
M PE =R 12 R 13 (—CH 2 CH(R 14 )(R 15 ) t O(R 16 ) u (C 2 H 4 O) v (C 3 H 6 O) w (C 4 H 8 O) x R 17 )SiO 1/2 ;
M E =R 12 R 13 (R E )SiO 1/2
D=R 18 R 19 SiO 2/2 ; and
D H =R 20 HSiO 2/2
D PE =R 20 (—CH 2 CH(R 14 )(R 15 ) t O(R 16 ) u (C 2 H 4 O) v (C 3 H 6 O) w (C 4 H 8 O) x R 17 )SiO 2/2
D E =R 20 R E SiO 2/2 .
T=R 21 SiO 3/2 ;
T H =HSiO 3/2 ;
T PE =(—CH 2 CH(R 14 )(R 15 ) t O(R 16 ) u (C 2 H 4 O) v (C 3 H 6 O) w (C 4 H 8 O) x R 17 )SiO 3/2 ;
T E =R E SiO 3/2 ; and
Q=SiO 4/2 ;
where R 9 , R 10 , R 11 , R 12 , R 13 , R 18 , R 19 , R 20 , and R 21 are each independently selected from the group of monovalent hydrocarbon radicals having from 1 to 60 carbon atoms;
R 14 is H or a 1 to 6 carbon atom alkyl group; R 15 is a divalent alkyl radical of 1 to 6 carbons; R 16 is selected from the group of divalent radicals consisting of —C 2 H 4 O—, —C 3 H 6 O—, and —C 4 H 8 O—; R 17 is selected from the group consisting of H, monofunctional hydrocarbon radicals of 1 to 6 carbons, and acetyl;
R E is independently a monovalent hydrocarbon radical containing one or more oxirane or oxetane moieties having from one to sixty carbon atoms;
the subscript f may be zero or positive subject to the limitation that when the subscript f is zero, h must be positive;
the subscript h is zero or positive subject to the limitations that when h is zero, the subscript f is positive, and that the sum of the subscripts h, l and p is positive;
the subscript k is zero or positive and has a value ranging from about 0 to about 1,000;
the subscript l is zero or positive and has a value ranging from about 0 to about 400 subject to the limitation that the sum of the subscripts h, l and p is positive;
the subscript o is zero or positive and has a value ranging from 0 to about 50;
the subscript p is zero or positive and has a value ranging from 0 to about 30 subject to the limitation that the sum of the subscripts h, l and p is positive;
the subscript s is zero or positive and has a value ranging from 0 to about 20;
the subscript i is zero or positive and has a value ranging from 0 to about 20;
the subscript m is zero or positive and has a value ranging from 0 to about 200;
the subscript q is zero or positive and has a value ranging from 0 to about 30;
the subscript j is zero or positive and has a value ranging from 0 to about 2;
the subscript n is zero or positive and has a value ranging from 0 to about 20;
the subscript r is zero or positive and has a value ranging from 0 to about 30;
the subscript t is zero or one;
the subscript u is zero or one;
the subscript v is zero or positive and has a value ranging from 0 to about 100 subject to the limitation that (v+w+x)>0;
the subscript w is zero or positive and has a value ranging from 0 to about 100 subject to the limitation that (v+w+x)>0;
the subscript x is zero or positive and has a value ranging from 0 to about 100 subject to the limitation that (v+w+x)>0;
75 . The method of claim 72 wherein the oxirane or oxetane compound is a hydrocarbon having the formula:
R 22 y (R 23 ) z (R 24 α )(R 25 ) β
where R 22 and R 25 are independently a monovalent hydrocarbon radical containing one or more oxirane or oxetane moieties having from 3 to 12 carbon atoms;
R 23 and R 24 are each selected from the group consisting of H or a linear or branched monovalent hydrocarbon radical of 1 to 1000 carbons;
the subscripts y, z, α, β are zero or positive ranging from zero to four subject to the limitation that (y+β)>2.
76 . The method of claim 73 wherein the oxirane or oxetane compound is a polyether having the formula:
R 26 O(R 27 ) γ (C 2 H 4 O) δ (C 3 H 6 O) ε (C 4 H 8 O) ζ R 28
where R 26 and R 28 are independently a monovalent hydrocarbon radical containing one or more oxirane or oxetane moieties having from 3 to 12 carbon atoms;
R 27 is selected from the group of divalent radicals consisting of —C 2 H 4 O—, —C 3 H 6 O—, and —C 4 H 6 O—;
the subscript γ is zero or 1;
the subscript δ is zero or positive and has a value ranging from 0 to about 100 subject to the limitation that (δ+ε+ζ)>0;
the subscript ε is zero or positive and has a value ranging from 0 to about 100 subject to the limitation that (δ+ε+ζ)>0;
the subscript ζ is zero or positive and has a value ranging from 0 to about 100 subject to the limitation that (δ+ε+ζ)>0.
77 . The method of claim 72 , wherein the composition is an emulsion having a continuous phase comprising the reaction product and a discontinuous phase comprising water.
78 . The method of claim 72 , wherein the composition is an emulsion having a discontinuous phase comprising the reaction product and a continuous phase comprising water.
79 . Method of treating water, comprising adding a composition comprising the reaction product of
(a) oxirane or oxetane compound comprising at least two oxirane or oxetane groups; and (b) an amino silane having the formula:
N(H)(R 1 )R 2 Si(OR 3 ) 3-a-b-c (OR 4 ) a (R 5 Si(OR 6 ) d (R 7 ) e ) b R 8 c
with R 1 is chosen from the group consisting of H or a monovalent hydrocarbon radical containing one to 20 carbon atoms; R 2 is selected from a group consisting of a divalent linear or branched hydrocarbon radical consisting of 1-60 carbons; R 4 is a hydrocarbon radical that contains 3 to 200 carbon atoms; R 5 is selected from a group consisting of oxygen or a divalent linear or branched hydrocarbon radical consisting of 1-60 carbons; R 3 , R 6 , R 7 , and R 8 and are each independently selected from the group of monovalent linear or branched hydrocarbon radicals having from 1 to 200 carbon atoms; the subscript b is zero or a positive number and has a value ranging from 0 to 3; the subscripts a, and c are zero or positive and have a value ranging from 0 to 3 subject to the limitation that (a+b+c)≦3; the subscripts d and e are zero or positive and have a value ranging from 0 to 3 subject to the limitation that (d+e)≦3, wherein said textile has an enhanced response to water.
80 . The method of claim 79 wherein the oxirane or oxetane compound is selected from the group consisting of siloxanes, hydrocarbons and polyethers.
81 . The method of claim 80 wherein the oxirane or oxetane compound is a siloxane having the formula:
M f M E h M PE i M H j D k D E l D PE m D H n T o T E p T PE q T H r Q s with
M=R 9 R 10 R 11 SiO 1/2 ;
M H =R 12 R 13 HSiO 1/2 ;
M PE =R 12 R 13 (—CH 2 CH(R 14 )(R 15 ) t O(R 16 ) u (C 2 H 4 O) v (C 3 H 6 O) w (C 4 H 8 O) x R 17 )SiO 1/2 ;
M E =R 12 R 13 (R E )SiO 1/2
D=R 18 R 19 SiO 2/2 ; and
D H =R 20 HSiO 2/2
D PE =R 20 (—CH 2 CH(R 14 )(R 15 ) t O(R 16 ) u (C 2 H 4 O) v (C 3 H 6 O) w (C 4 H 8 O) x R 17 )SiO 2/2
D E =R 20 R E SiO 2/2 .
T=R 21 SiO 3/2 ;
T H =HSiO 3/2 ;
T PE =(—CH 2 CH(R 14 )(R 15 ) t O(R 16 ) u (C 2 H 4 O) v (C 3 H 6 O) w (C 4 H 8 O) x R 17 )SiO 3/2 ;
T E =R E SiO 3/2 ; and
Q=SiO 4/2 ;
where R 9 , R 10 , R 11 , R 12 , R 13 , R 18 , R 19 , R 20 , and R 21 are each independently selected from the group of monovalent hydrocarbon radicals having from 1 to 60 carbon atoms;
R 14 is H or a 1 to 6 carbon atom alkyl group; R 15 is a divalent alkyl radical of 1 to 6 carbons; R 16 is selected from the group of divalent radicals consisting of —C 2 H 4 O—, —C 3 H 6 O—, and —C 4 H 8 O—; R 17 is selected from the group consisting of H, monofunctional hydrocarbon radicals of 1 to 6 carbons, and acetyl;
R E is independently a monovalent hydrocarbon radical containing one or more oxirane or oxetane moieties having from one to sixty carbon atoms;
the subscript f may be zero or positive subject to the limitation that when the subscript f is zero, h must be positive;
the subscript h is zero or positive subject to the limitations that when h is zero, the subscript f is positive, and that the sum of the subscripts h, l and p is positive;
the subscript k is zero or positive and has a value ranging from about 0 to about 1,000;
the subscript l is zero or positive and has a value ranging from about 0 to about 400 subject to the limitation that the sum of the subscripts h, l and p is positive;
the subscript o is zero or positive and has a value ranging from 0 to about 50;
the subscript p is zero or positive and has a value ranging from 0 to about 30 subject to the limitation that the sum of the subscripts h, l and p is positive;
the subscript s is zero or positive and has a value ranging from 0 to about 20;
the subscript i is zero or positive and has a value ranging from 0 to about 20;
the subscript m is zero or positive and has a value ranging from 0 to about 200;
the subscript q is zero or positive and has a value ranging from 0 to about 30;
the subscript j is zero or positive and has a value ranging from 0 to about 2;
the subscript n is zero or positive and has a value ranging from 0 to about 20;
the subscript r is zero or positive and has a value ranging from 0 to about 30;
the subscript t is zero or one;
the subscript u is zero or one;
the subscript v is zero or positive and has a value ranging from 0 to about 100 subject to the limitation that (v+w+x)>0;
the subscript w is zero or positive and has a value ranging from 0 to about 100 subject to the limitation that (v+w+x)>0;
the subscript x is zero or positive and has a value ranging from 0 to about 100 subject to the limitation that (v+w+x)>0;
82 . The method of claim 79 wherein the oxirane or oxetane compound is a hydrocarbon having the formula:
R 22 y (R 23 ) z (R 24 α )(R 25 ) β
where R 22 and R 25 are independently a monovalent hydrocarbon radical containing one or more oxirane or oxetane moieties having from 3 to 12 carbon atoms;
R 23 and R 24 are each selected from the group consisting of H or a linear or branched monovalent hydrocarbon radical of 1 to 1000 carbons;
the subscripts y, z, α, β are zero or positive ranging from zero to four subject to the limitation that (y+β)>2.
83 . The method of claim 80 wherein the oxirane or oxetane compound, is a polyether having the formula:
R 26 O(R 27 ) γ (C 2 H 4 O) δ (C 3 H 6 O) ε (C 4 H 8 O) ζ R 28
where R 26 and R 28 are independently a monovalent hydrocarbon radical containing one or more oxirane or oxetane moieties having from 3 to 12 carbon atoms;
R 27 is selected from the group of divalent radicals consisting of —C 2 H 4 O—, —C 3 H 6 O—, and —C 4 H 8 O—;
the subscript γ is zero or 1;
the subscript δ is zero or positive and has a value ranging from 0 to about 100 subject to the limitation that (δ+ε+ζ)>0;
the subscript ε is zero or positive and has a value ranging from 0 to about 100 subject to the limitation that (δ+ε+ζ)>0;
the subscript ζ is zero or positive and has a value ranging from 0 to about 100 subject to the limitation that (δ+ε+ζ)>0.
84 . The method of claim 79 , wherein the composition is an emulsion having a continuous phase comprising the reaction product and a discontinuous phase comprising water.
85 . The method of claim 79 , wherein the composition is an emulsion having a discontinuous phase comprising the reaction product and a continuous phase comprising water.Cited by (0)
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