High performance rock bit grease

Abstract

The present disclosure relates to greases containing metal sulfonate thickeners. In one example the thickener may be a calcium sulfonate thickener. In other examples grease may contain a combination of a metal sulfonate thickener and another thickener, such as a metal complex soap grease, detergent, or non-soap thickener. The grease may be formulated to meet specific performance criteria relevant to lubrication of a roller cone drill bit in downhole conditions. The disclosure also relates to a roller cone drill bit containing a grease of the disclosure.

1 . A rock bit grease for use with a roller cone drill bit comprising:
 a thickener comprising a metal sulfonate thickener;   a base oil selected from the group consisting of a mineral oil, a synthetic oil, and combinations thereof;   at least one solid additive selected from the group consisting of graphite, polytetrafluoroethylene, silica, inorganic sulfur-containing solids, inorganic phosphorus-containing solids, inorganic boron-containing solids, and any combinations thereof; and   at least one oil-soluble additive selected from the group consisting of extreme pressure (EP) additives, oxidation inhibitors, wear and friction reducing additives, polymer additives for enhanced grease integrity, pour point depressant, or corrosion inhibitor, and any combinations thereof.   
     
     
         2 . The rock bit grease of  claim 1 , further comprising a second thickener comprising a metal complex soap thickener or non-soap thickener. 
     
     
         3 . The rock bit grease of  claim 1 , wherein the thickener comprises at least approximately 40% by weight metal sulfonate thickener. 
     
     
         4 . The rock bit grease of  claim 1 , wherein the thickener comprises at least approximately 90% by weight metal sulfonate thickener. 
     
     
         5 . The rock bit grease of  claim 1 , wherein the thickener comprises at least approximately 95% by weight metal sulfonate thickener. 
     
     
         6 . The rock bit grease of  claim 1 , wherein the metal sulfonate thickener comprises an alkaline earth metal sulfonate thickener. 
     
     
         7 . The rock bit grease of  claim 6 , wherein the metal sulfonate thickener comprises a calcium sulfonate thickener. 
     
     
         8 . The rock bit grease of  claim 2 , wherein the metal complex soap comprises an aluminum or lithium complex soap. 
     
     
         9 . The rock bit grease of  claim 2 , wherein the metal complex soap comprises a calcium complex soap. 
     
     
         10 . The rock bit grease of  claim 2 , wherein the non-soap thickener comprises at least one thickener selected from the group consisting of: silica, clays, silica gels, carbon black, polyurea, synthetic organic materials, and any combinations thereof. 
     
     
         11 . The rock bit grease of  claim 1 , wherein the grease comprises at least approximately 40% up to approximately 100% by weight metal sulfonate thickener. 
     
     
         12 . The rock bit grease of  claim 1 , wherein the grease prevents seizure in at least one journal bearing test at a bearing loading of 12,000 kgf at 400 rpm. 
     
     
         13 . The rock bit grease of  claim 1 , wherein the grease exhibits a change in flow point after thermal aging at 16 hours at 177° C. of one order of magnitude or less. 
     
     
         14 . The rock bit grease of  claim 1 , wherein the grease has a dropping point temperature greater than approximately 300° C. 
     
     
         15 . The rock bit grease of  claim 1 , wherein the grease has a worked penetration within NLGI grades 1, 2 and 3. 
     
     
         16 . The rock bit grease in  claim 1 , wherein the grease is operable to reduce friction between bearing surfaces associated with a roller cone drill bit operating at temperatures significantly above 150° C. 
     
     
         17 . The rock bit grease of  claim 1 , wherein the grease is non-toxic. 
     
     
         18 . A rock bit grease for use with a roller cone drill bit comprising:
 a thickener comprising:
 at least 50% by weight calcium sulfonate thickener; and 
 a calcium complex soap thickener; 
   a base oil selected from the group consisting of a mineral oil, a synthetic oil, and combinations thereof;   at least one solid additive selected from the group consisting of graphite, polytetrafluoroethylene, silica, inorganic sulfur-containing solids, inorganic phosphorus-containing solids, inorganic boron-containing solids, and any combinations thereof; and   at least one oil-soluble additive selected from the group consisting of extreme pressure (EP) additives, oxidation inhibitors, wear and friction reducing additives, polymer additives for enhanced grease integrity, pour point depressant, or corrosion inhibitor, and any combinations thereof.   
     
     
         19 . A roller cone drill bit operable to form a wellbore extending through a downhole formation comprising:
 a bit body having at least one support arm extending therefrom;   a respective cone assembly rotatably mounted on a spindle extending from each support arm;   a grease container disposed in each support arm;   at least one grease passageway disposed in each support arm to communicate a grease disposed within the grease chamber to bearing surfaces associated with rotatably supporting the respective cone assembly; and   a rock bit grease comprising:
 a thickener comprising a metal sulfonate thickener; 
 a base oil selected from the group consisting of a mineral oil, a synthetic oil, and combinations thereof; 
 at least one solid additive selected from the group consisting of graphite, polytetrafluoroethylene, silica, inorganic sulfur-containing solids, inorganic phosphorus-containing solids, inorganic boron-containing solids, and any combinations thereof; and 
 at least one oil-soluble additive selected from the group consisting of extreme pressure (EP) additives, oxidation inhibitors, wear and friction reducing additives, polymer additives for enhanced grease integrity, pour point depressant, or corrosion inhibitor, and any combinations thereof. 
   
     
     
         20 . The roller cone drill bit of  claim 19 , wherein the rock bit grease further comprises a second thickener comprising a metal complex soap thickener, detergent, or non-soap thickener.