Process and a Reactor for Oxidation of a Hydrocarbon

Abstract

A process and related reactor ( 1 ) for oxidation of a hydrocarbon feedstock are disclosed, the reactor ( 1 ) comprising a vessel ( 3 ) and a neck ( 5 ) with an axial burner ( 6 ) and a tangential gas inlet ( 2 ), wherein the neck ( 5 ) has a swirling chamber ( 10 ) located below said burner ( 6 ) and connected to said gas inlet ( 2 ), to produce a gas vortex (V) which optimizes the mixing between the gas stream (G) and the oxidizer in said neck ( 5 ). Preferably the swirling chamber ( 10 ) has an internal surface ( 12 ) with a log-spiral profile.

1 . A reactor for reacting a hydrocarbon-containing feedstock with an oxidizer stream, the reactor comprising:
 a vessel defining a combustion chamber,   at least an axial burner for delivering said oxidizer stream to said combustion chamber,   an inlet for said hydrocarbon-containing feedstock, and   a swirling chamber connected to said inlet, wherein said swirling chamber is located downstream of said burner and upstream of said combustion chamber, and is in fluid communication with said burner and combustion chamber,   wherein said inlet and swirling chamber are arranged to impart a swirling motion around an axis of the reformer to the hydrocarbon-containing feedstock.   
     
     
         2 . The reactor according to  claim 1 , wherein said vessel has a neck delimiting at least part of said combustion chamber, the neck having a portion with enlarged cross section, and wherein said portion delimits the swirling chamber and is connected with the hydrocarbon-containing feedstock inlet. 
     
     
         3 . The reactor according to  claim 2 , wherein said swirling chamber is located at the top of the neck. 
     
     
         4 . The reactor according to  claim 1 , wherein there is a gap between said swirling chamber and the tip of said burner, so that a pre-chamber is formed downstream the burner and above said swirling chamber. 
     
     
         5 . The reactor according to  claim 1 , wherein said swirling chamber is delimited laterally by a side wall with a spiral-like internal surface so that the distance of said internal surface from the axis of the reformer progressively decreases from the inlet section of said hydrocarbon-containing feedstock inlet. 
     
     
         6 . The reactor according to  claim 5 , wherein said spiral-like internal surface of the swirling chamber covers an angle of about 360 degrees. 
     
     
         7 . The reactor according to  claim 6 , wherein said spiral-like internal surface has one end matching an internal wall of the hydrocarbon-containing feedstock inlet, at the inlet section, and an opposite end matching an opposite internal side of said inlet. 
     
     
         8 . The reactor according to  claim 6 , wherein said spiral-like internal surface is a log-spiral surface, having a cross-section profile following a logarithmic spiral. 
     
     
         9 . The reactor according to  claim 1 , wherein said swirling chamber is delimited laterally by a side wall with a cylindrical internal surface. 
     
     
         10 . The reactor according to  claim 1 , wherein the vessel contains a catalytic bed and the combustion chamber is above said catalytic bed. 
     
     
         11 . The reactor according to  claim 1 , said reactor being an autothermal reformer, a secondary reformer of a hydrocarbon-reforming equipment, or a partial oxidation gas generator. 
     
     
         12 . A process for reacting a hydrocarbon-containing feedstock with an oxidizer stream inside a combustion chamber, wherein said oxidizer stream is fed to said combustion chamber in direction of an axis of said chamber, the process being characterized in that a swirling motion around said axis is imparted to said gas stream entering the combustion chamber. 
     
     
         13 . The process according to  claim 12 , wherein a substantially axial-symmetric velocity field is imparted to said hydrocarbon-containing feedstock inside the combustion chamber, by feeding said stream to said combustion chamber via a spiral-like path. 
     
     
         14 . The process according to  claim 13 , wherein said spiral-like path follows a logarithmic spiral around said axis of the combustion chamber. 
     
     
         15 . The process according to  claim 12 , wherein said hydrocarbon-containing feedstock is a gas stream containing gaseous hydrocarbon(s) such as natural gas or methane, or a gaseous flow containing suspended solid combustible such as coal dust or carbon soot, or a gaseous flow comprising dispersed liquid hydrocarbons, and the oxidizer stream contains air, enriched air or pure oxygen.