Carbon nanotube fibers/filaments formulated from metal nanoparticle catalyst and carbon source

Abstract

Disclosed is a method of: providing a mixture of a polymer or a resin and a transition metal compound, producing a fiber from the mixture, and heating the fiber under conditions effective to form a carbon nanotube-containing carbonaceous fiber. The polymer or resin is an aromatic polymer or a precursor thereof and the mixture is a neat mixture or is combined with a solvent. Also disclosed are a carbonaceous fiber or carbonaceous nanofiber sheet having at least 15 wt. % carbon nanotubes, a fiber or nanofiber sheet having the a polymer or a resin and the transition metal compound, and a fiber or nanofiber sheet having an aromatic polymer and metal nanoparticles.

1 . A method comprising:
 providing a polymer or resin that is an aromatic polymer or a precursor thereof;   providing an amount of a transition metal compound;   dissolving the polymer or resin and the amount of the transition metal compound in a solvent to produce a solution;   producing a fiber from the solution;
 wherein the fiber is produced when at least 50% of the amount of the transition metal compound remains in the solution; and 
   heating the fiber under conditions effective to form a carbon nanotube-containing fiber.   
     
     
         2 . A method of  claim 1 , wherein the solvent is a polar aprotic solvent. 
     
     
         3 . The method of  claim 1 , wherein the carbon nanotubes are formed by heating the fiber in an inert atmosphere to a temperature of 600-2700° C. 
     
     
         4 . The method of  claim 1 , further comprising:
 heating the fiber under conditions effective to convert the precursor to the aromatic polymer before heating to form the carbon nanotube-containing fiber.   
     
     
         5 . The method of  claim 4 , wherein the precursor is polyacrylonitrile. 
     
     
         6 . The method of  claim 4 , wherein the resin is a coal pitch polymer, a petroleum pitch polymer, or a pitch resin polymer. 
     
     
         7 . The method of  claim 4 , wherein the precursor or resin is converted to the aromatic polymer by heating in the presence of oxygen to a temperature of 200-300° C. 
     
     
         8 . The method of  claim 1 , wherein the aromatic polymer is a phthalonitrile polymer or thermoset thereof. 
     
     
         9 . The method of  claim 8 , wherein the phthalonitrile polymer is formed from 
       
         
           
           
               
               
           
         
         wherein n is a positive integer. 
       
     
     
         10 . The method of  claim 1 , wherein the transition metal compound is octacarbonyldicobalt, 1-(ferrocenylethynyl)-3-(phenylethynyl)benzene, diironnonacarbonyl, or bis(1,5-cyclooctodiene)nickel(0). 
     
     
         11 . The method of  claim 1 , wherein the fiber is formed using a spinneret. 
     
     
         12 . The carbon nanotube-containing fiber made by the method of  claim 11 . 
     
     
         13 . The carbon nanotube-containing fiber of  claim 12 , wherein the fiber further comprises metal nanoparticles. 
     
     
         14 . The method of  claim 1 , wherein the fiber is formed by electrospinning. 
     
     
         15 . The carbon nanotube-containing fiber made by the method of  claim 1 . 
     
     
         16 . The carbon nanotube-containing fiber of  claim 15 , wherein the fiber further comprises metal nanoparticles. 
     
     
         17 . The method of  claim 1 , wherein the fiber is a component of a nanofiber sheet. 
     
     
         18 . The carbon nanotube-containing sheet made by the method of  claim 17 . 
     
     
         19 . The carbon nanotube-containing sheet of  claim 18 , wherein the sheet further comprises metal nanoparticles.