US2012017806A1PendingUtilityA1

Ophthalmic and Contact Lens Solutions Using Low Molecular Weight Amines

68
Assignee: SMITH FRANCIS XPriority: Nov 4, 2000Filed: Aug 1, 2011Published: Jan 26, 2012
Est. expiryNov 4, 2020(expired)· nominal 20-yr term from priority
A01N 47/44A61L 12/12A45C 11/005A01N 59/00A61L 12/143A61L 2/18A01N 37/44C09D 7/63A01N 33/12C09D 5/00A01N 43/50G02B 1/18A61L 12/086A01N 43/38A61L 12/145A61L 12/124A61L 12/142
68
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Claims

Abstract

The present invention relates to a lens care solution comprising: 0.001 to about 5 weight percent of a low molecular weight amine of the general formula: Where R 1 , R 2 , R 3 and R 4 are —H or low molecular weight radicals, and R 5 is a low molecular weight radical, or salt thereof; an effective amount of tonicity agent; and the balance water.

Claims

exact text as granted — not AI-modified
1 . An ophthalmic solution comprising:
 0.001 to about 5 weight percent of a low molecular weight amine of the general formula:   
       
         
           
           
               
               
           
         
         where R 1 , R 2 , R 3 , and R 4  are —H or low molecular weight radicals, and R 5  is a low molecular weight radical, or salts thereof; an effective amount of biologically compatible buffer to maintain the pH of the solution between 5.5 and 8.5 pH; and 
         the balance water. 
       
     
     
         2 . The ophthalmic solution of  claim 1  that further comprises an effective amount of a tonicity agent. 
     
     
         3 . The ophthalmic solution of  claim 1  where the amine is Betaine. 
     
     
         4 . The ophthalmic solution of  claim 1  where the amine is Bicine (N,N-Bis(2-hydroxyethyl)-glycline). 
     
     
         5 . The ophthalmic solution of  claim 1  where the amine is Bis-Tris(Bis-(2-hydroxyethyl)imino-tris(hydroxymethyl)methane. 
     
     
         6 . The ophthalmic solution of  claim 1  where the amine is Choline. 
     
     
         7 . The ophthalmic solution of  claim 1  where the amine is Carnitine. 
     
     
         8 . The ophthalmic solution of  claim 1  where the amine is Creatine. 
     
     
         9 . The ophthalmic solution of  claim 1  where the amine is Creatinine. 
     
     
         10 . The ophthalmic solution of  claim 1  where the amine is Diisopropylamine. 
     
     
         11 . The ophthalmic solution of  claim 1  where the amine is Diethanolamine. 
     
     
         12 . The ophthalmic solution of  claim 1  where the amine is Dimethyl Aspartic Acid. 
     
     
         13 . The ophthalmic solution of  claim 1  where the amine is Dimethyl glutamate. 
     
     
         14 . The ophthalmic solution of  claim 1  where the amine is Methyl Aspartate. 
     
     
         15 . The ophthalmic solution of  claim 1  where the amine is Methylethanolamine. 
     
     
         16 . The ophthalmic solution of  claim 1  where the amine is Hydroxymethyl Glycinate. 
     
     
         17 . The ophthalmic solution of  claim 1  where the amine is Triethylamine. 
     
     
         18 . The ophthalmic solution of  claim 1  where the amine is Triethanolamine. 
     
     
         19 . The ophthalmic solution of  claim 1  where the amine is Tricine (N-tris(hydroxymethyl)methyl glycine). 
     
     
         20 . The ophthalmic solution of  claim 1  where the amine is Triisopropanolamine. 
     
     
         21 . The ophthalmic solution of  claim 1  wherein R 1  is chosen from the group of radicals presented by the following formulae: 
       
         
           
                 
               
                     
                 
                   D,L Side Chains 
                 
                   R1 
                 
                     
                 
                   —H 
                 
                   —CH 3   
                 
                   —CH 2 —COO −   
                 
                   —CH 2 CH 2 —COO −   
                 
                   —CH 2 CH 2 OH 
                 
                   —CH 2 CH(CH 3 ) 2   
                 
                   —CH(CH 3 ) 2   
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   —CH 2 OH 
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   —CH 2 —SH 
                 
                   —CH 2 CH 2 —S—CH 3   
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
             
                
                
                
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
       
     
     
         22 . The ophthalmic solution of  claim 1  wherein R 2  is chosen from the group of radicals presented by the following formulae: 
       
         
           
           
               
               
           
         
       
     
     
         23 . The ophthalmic solution of  claim 1  wherein R 3  is chosen from the group of radicals presented by the following formulae: 
       
         
           
           
               
               
           
         
       
     
     
         24 . The ophthalmic solution of  claim 1  wherein R 4  is chosen from the group of radicals presented by the following formulae: 
       
         
           
           
               
               
           
         
       
     
     
         25 . The ophthalmic solution of  claim 1  wherein R 5  is chosen from the group of radicals presented by the following formulae: 
       
         
           
           
               
               
           
         
       
     
     
         26 . An ophthalmic product comprising:
 at least one contact lens;   a contact lens container; and   sufficient contact lens solution to wet said contact lens where said solution comprises:   0.001 to about 5 weight percent of a low molecular weight amine of the general formula:   
       
         
           
           
               
               
           
         
         where R 1 , R 2 , R 3  and R 4  are —H or low molecular weight radicals, and R 5  is a low molecular weight radical, or salts thereof; and the balance water. 
       
     
     
         27 . The ophthalmic product of  claim 26  where R 1 , R 2 , R 3 , R 4  and R 5  are chosen from the following groups or salts thereof; 
       
         
           
                 
               
                     
                 
                   D,L Side Chains 
                 
                     
                 
                   R1 
                 
                   —H 
                 
                   —CH 3   
                 
                   —CH 2 —COO −   
                 
                   —CH 2 CH 2 —COO −   
                 
                   —CH 2 CH 2 OH 
                 
                   —CH 2 CH(CH 3 ) 2   
                 
                   —CH(CH 3 ) 2   
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   —CH 2 OH 
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   —CH 2 —SH 
                 
                   —CH 2 CH 2 —S—CH 3   
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   R2 
                 
                   —COO −   
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   —CH 2 OH 
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   —CH 3   
                 
                   R3, R4, R5 
                 
                   —H 
                 
                   —CH 3   
                 
                   —CH 2 CH 3   
                 
                   —CH 2 CH 2 CH 3   
                 
                   —CH(CH 3 ) 2   
                 
                   —CH 2 OH 
                 
                   —CH 2 CH 2 OH 
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
             
                
                
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
       
     
     
         28 . A method for treating a contact lens in order to decrease its affinity to protein deposition which comprises the step of:
 soaking a contact lens in an aqueous solution comprising 0.001 to 5 weight percent a low molecular weight amine of the general formula:   
       
         
           
           
               
               
           
         
         where R 3  and R 4  are low molecular weight radicals; and R 1  and R 2  are —H or low molecular weight radicals; and where R 1 , R 2 , R 3 , R 4  and R 5  can be chosen from the following groups or salts thereof; 
       
       
         
           
                 
               
                     
                 
                   D,L Side Chains 
                 
                     
                 
                   R1 
                 
                   —H 
                 
                   —CH 3   
                 
                   —CH 2 —COO −   
                 
                   —CH 2 CH 2 —COO −   
                 
                   —CH 2 CH 2 OH 
                 
                   —CH 2 CH(CH 3 ) 2   
                 
                   —CH(CH 3 ) 2   
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   —CH 2 OH 
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   —CH 2 —SH 
                 
                   —CH 2 CH 2 —S—CH 3   
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   R2 
                 
                   —COO −   
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   —CH 2 OH 
                 
                     
                 
                   
                     
                       
                       
                           
                           
                       
                     
                   
                 
                     
                 
                   —CH 3   
                 
                   R3, R4, R5 
                 
                   —H 
                 
                   —CH 3   
                 
                   —CH 2 CH 3   
                 
                   —CH 2 CH 2 CH 3   
                 
                   —CH(CH 3 ) 2   
                 
                   —CH 2 OH 
                 
                   —CH 2 CH 2 OH

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