Thick-walled high-strength hot rolled steel sheet having excellent hydrogen induced cracking resistance and manufacturing method thereof

Abstract

A thick-walled high-strength hot rolled steel sheet having excellent hydrogen induced cracking resistance which is preferably used as a raw material for a high-strength welded steel pipe of X65 grade or more and a method of manufacturing the thick-walled high-strength hot rolled steel sheet are provided. The composition of the thick-walled high-strength hot rolled steel sheet contains by mass % 0.02 to 0.08% C, 0.50 to 1.85% Mn, 0.03 to 0.10% Nb, 0.001 to 0.05% Ti, 0.0005% or less B in such a manner that (Ti+Nb/2)/C<4 is satisfied or also contains one or two kinds or more of 0.010% or less Ca, 0.02% or less REM, and Fe and unavoidable impurities as a balance. The steel sheet has the structure formed of a bainitic ferrite phase or a bainite phase. Surface layer hardness is 230HV or less in terms of Vickers hardness.

1 . A thick-walled high-strength hot rolled steel sheet having a composition which contains by mass % 0.02 to 0.08% C, 1.0% or less Si, 0.50 to 1.85% Mn, 0.03% or less P, 0.005% or less S, 0.1% or less Al, 0.03 to 0.10% Nb, 0.001 to 0.05% Ti, 0.0005% or less B, and Fe and unavoidable impurities as a balance, wherein the steel sheet contains Nb, Ti and C in such a manner that a following formula (1) is satisfied, the steel sheet has the structure formed of a bainitic ferrite phase or a bainite phase, and surface layer hardness is 230HV or less in terms of Vickers hardness, wherein
   (Ti+Nb/2)/C<4 Ti, Nb, C: contents of respective elements (mass %).   
     
     
         2 . The thick-walled high-strength hot rolled steel sheet according to  claim 1 , wherein the composition further contains by mass % one or two kinds or more selected from a group consisting of 0.5% or less V, 1.0% or less Mo, 1.0% or less Cr, 4.0% or less Ni, and 2.0% or less Cu in addition to the composition. 
     
     
         3 . The thick-walled high-strength hot rolled steel sheet according to  claim 1 , wherein the composition further contains by mass % one or two kinds or more selected from a group consisting of 0.010% or less Ca, 0.02% or less REM, and 0.003% or less Mg in addition to the composition. 
     
     
         4 . The thick-walled high-strength hot rolled steel sheet according to  claim 1 , wherein the composition further satisfies at least one of a condition that Ceq defined by a following formula (2) is 0.32% or less and a condition that Pcm defined by a following formula (3) is 0.13% or less, wherein
   Ceq=C+Mn/6+(Cr+Mo+V)/5+(Cu+Ni)/15  (2)
     Pcm=C+Si/30+(Mn+Cu+Cr)/20+Ni/60+Mo/15+V/10+5B  (3)
   Here, C, Si, Mn, Cr, Mo, V, Cu, Ni, B: contents of respective elements (mass %).   
     
     
         5 . A method of manufacturing a thick-walled high-strength hot rolled steel sheet having surface layer hardness of 230HV or less in terms of Vickers hardness, wherein in manufacturing a hot rolled steel sheet by applying hot rolling consisting of rough rolling and finish rolling to a raw steel material having the composition according to  claim 1 , after the finish rolling is finished, a first cooling step in which the hot rolled steel sheet is cooled by accelerated cooling at an average surface cooling rate of 30° C./s or more until a surface temperature becomes 500° C. or below, a second cooling step in which the hot rolled steel sheet is cooled by air cooling for 10s or less after the first cooling step is finished, and a third cooling step in which the hot rolled steel sheet is cooled by accelerated cooling to a temperature which falls within a temperature range from 350° C. or above to a temperature below 600° C. at the center of a sheet-thickness at an average cooling rate of 10° C./s or more at the center of the sheet-thickness are applied to the hot rolled steel sheet, and the hot rolled steel sheet is coiled in a coil shape after the third cooling step is finished. 
     
     
         6 . The method of manufacturing a thick-walled high-strength hot rolled steel sheet according to  claim 5 , wherein the accelerated cooling in the third cooling step is cooling performed at a heat flow rate of 1.5 Gcal/m 2  hr or more in entire surface nuclear boiling. 
     
     
         7 . The method of manufacturing a thick-walled high-strength hot rolled steel sheet according to  claim 5 , wherein the composition further contains by mass % one or two kinds or more selected from a group consisting of 0.5% or less V, 1.0% or less Mo, 1.0% or less Cr, 4.0% or less Ni, and 2.0% or less Cu in addition to the composition. 
     
     
         8 . The method of manufacturing a thick-walled high-strength hot rolled steel sheet according to  claim 5 , wherein the composition further contains by mass % one or two kinds or more selected from a group consisting of 0.010% or less Ca, 0.02% or less REM, and 0.003% or less Mg in addition to the composition. 
     
     
         9 . The method of manufacturing a thick-walled high-strength hot rolled steel sheet according to  claim 5 , wherein the composition further satisfies at least one of a condition that Ceq defined by a following formula (2) is 0.32% or less and a condition that Pcm defined by a following formula (3) is 0.13% or less, wherein
   Ceq=C+Mn/6+(Cr+Mo+V)/5+(Cu+Ni)/15  (2)
     Pcm=C+Si/30+(Mn+Cu+Cr)/20+Ni/60+Mo/15+V/10+5B  (3)
   Here, C, Si, Mn, Cr, Mo, V, Cu, Ni, B: contents of respective elements (mass %).   
     
     
         10 . A method of manufacturing a thick-walled high-strength hot rolled steel sheet having tensile strength of 520 MPa or more and a surface layer hardness of 230HV or less in terms of Vickers hardness, wherein in manufacturing a hot rolled steel sheet by applying hot rolling consisting of rough rolling and finish rolling to a raw steel material having the composition according to  claim 1 , after the finish rolling is finished, a first cooling step in which the hot rolled steel sheet is cooled by accelerated cooling at an average cooling rate of 20° C./s or more and less than a martensite formation critical cooling rate on a surface of the hot rolled steel sheet until a surface temperature becomes a temperature not more than an A r3  transformation temperature and not less than an Ms temperature, a second cooling step in which the hot rolled steel sheet is rapidly cooled to a temperature within a temperature range from 350° C. or above to a temperature below 600° C. at the center of a sheet-thickness after the first cooling step is finished, and a third cooling step in which, after the second cooling step is finished, the hot rolled steel sheet is coiled in a coil shape at a coiling temperature falling within a temperature range from 350° C. or above to a temperature below 600° C. in terms of a temperature at the center of sheet-thickness and, thereafter, a temperature of the hot rolled steel sheet at least at a position of ¼ sheet-thickness to ¾ sheet-thickness in a coil thickness direction is held or kept within a temperature range from 350° C. or above to a temperature below 600° C. for 30 min or more are sequentially applied to the hot rolled steel sheet. 
     
     
         11 . The method of manufacturing a thick-walled high-strength hot rolled steel sheet according to  claim 10 , wherein the rapid cooling in the second cooling step is cooling at a heat flow rate of 1.0 Gcal/m 2  hr or more in entire surface nuclear boiling. 
     
     
         12 . The method of manufacturing a thick-walled high-strength hot rolled steel sheet according to  claim 10 , wherein the composition further contains by mass % one or two kinds or more selected from a group consisting of 0.5% or less V, 1.0% or less Mo, 1.0% or less Cr, 4.0% or less Ni, and 2.0% or less Cu in addition to the composition. 
     
     
         13 . The method of manufacturing a thick-walled high-strength hot rolled steel sheet according to  claim 10 , wherein the composition further contains by mass % one or two kinds selected from a group consisting of 0.010% or less Ca, 0.02% or less REM, 0.003% or less Mg in addition to the composition. 
     
     
         14 . The method of manufacturing a thick-walled high-strength hot rolled steel sheet according to  claim 10 , wherein the composition further satisfies at least one of a condition that Ceq defined by a following formula (2) is 0.32% or less and a condition that Pcm defined by a following formula (3) is 0.13% or less, wherein
   Ceq=C+Mn/6+(Cr+Mo+V)/5+(Cu+Ni)/15  (2)
     Pcm=C+Si/30+(Mn+Cu+Cr)/20+Ni/60+Mo/15+V/10+5B  (3)
   C, Si, Mn, Cr, Mo, V, Cu, Ni, B: contents of respective elements (mass %).