High performance sealable coextruded biaxially oriented polypropylene film

Abstract

A multilayer biaxially oriented polypropylene film is disclosed which comprises at least three layers. The first layer is an outer layer comprising a first polymer which is a homopolymer polypropylene resin having a melting point of at least 155° C. The second layer is a core layer, having a melting point greater than 1500C. The core layer includes a blend comprising a second polymer which is a polypropylene homopolymer having a melting point of at least 155° C. and a third polymer having a melting point no greater than 145° C. The second polymer comprises from 20% to 80% by weight of the core layer while the third polymer comprises from 80% to 20% by weight of the core layer. The last required layer in the film is a sealant layer. The sealant layer comprises a fourth polymer having a melting point no greater than 145° C.

1 . A multilayer biaxially oriented polypropylene film comprising:
 a. an outer layer comprising a first polymer which is a homopolymer polypropylene resin having a melting point of at least 155° C.;   b. a core layer, with a melting point greater than 150° C., comprising a blend comprising a second polymer which is a polypropylene homopolymer having a melting point of at least 155° C. and a third polymer having a melting point no greater than 145° C., wherein the second polymer comprises from 20% to 80% by weight of the core layer while the third polymer comprises from 80% to 20% by weight of the core layer; and   c. a sealant layer comprising a fourth polymer having a melting point no greater than 145° C.   
     
     
         2 . The film of  claim 1  wherein the film has been coextruded. 
     
     
         3 . The film of  claim 1  wherein the third polymer is a propylene based plastomer or elastomer. 
     
     
         4 . The film of  claim 1  wherein the third polymer is an ethylene copolymer having a density less than 0.916 g/cc. 
     
     
         5 . The film of  claim 1  wherein the third polymer is an olefin block copolymer. 
     
     
         6 . The film of  claim 3  wherein the propylene based elastomer or plastomer comprises units derived from propylene and units derived from ethylene. 
     
     
         7 . The film of  claim 6  wherein the units derived from ethylene comprise from 0.04 to 15% by weight of the propylene based plastomer or elastomer. 
     
     
         8 . The film of  claim 1  wherein the film has a thickness of from 15 μm to 80 μm. 
     
     
         9 . The film of  claim 1  wherein the core layer has a thickness of from 2 μm to 20 μm. 
     
     
         10 . The film of  claim 1  wherein the first polymer has a melting point greater than 160° C. 
     
     
         11 . The film of  claim 1  wherein the fourth polymer has a melting point of at least 90° C. 
     
     
         12 . The film of  claim 1  wherein the film has a heat seal strength of at least 10 N/25 mm. 
     
     
         13 . The film of  claim 1  wherein the film has a heat seal initiation temperature no greater than 100° C. 
     
     
         14 . The film of  claim 1  wherein the first polymer and the second polymer are the same material. 
     
     
         15 . The film of  claim 1  wherein the third polymer and the fourth polymer are the same material.