Asphalt oxidation process using liquid jet ejection

Abstract

Provided is a process for increasing the softening temperature of asphalts by use of liquid jet ejector technology, which is used as both an air compressor and an air/oil mixer. The liquid jet ejector motive fluid is hot asphalt and the entrained vapor is air.

1 . A process for increasing the softening point of asphalt comprising the following steps:
 providing a liquid jet ejector comprising a motive inlet, a motive nozzle, a suction port, a main ejector body, a venturi throat and diffuser, and a discharge connection;   conducting a preheated asphalt feed including fresh asphalt and recycled oxidized asphalt, at a temperature from 125° C. to 300° C., as the motive liquid into the motive inlet of the liquid jet ejector;   drawing atmospheric air or compressed air into the suction port of the liquid jet ejector;   mixing the preheated asphalt within the main ejector body with the air from the suction port of the liquid jet ejector to form a mixture;   conducting the mixture to a heated and pressurized oxidizer vessel;   collecting an off-gas from the overhead of said oxidizer vessel and an oxidized asphalt product stream from the bottoms of said oxidizer vessel, wherein said oxidized asphalt product stream has softening temperature greater than the preheated asphalt feed; and   recycling a portion of the oxidized asphalt product stream back to the liquid jet ejector to form the recycled oxidized asphalt.   
     
     
         2 . The process of  claim 1  wherein the oxidizer vessel is operated at a temperature from 150° C. to 300° C. with the proviso that it be at least 10° C. greater than the temperature of the preheated asphalt feed being conducted to said motive inlet of the liquid jet ejector. 
     
     
         3 . The process of  claim 2  wherein the oxidizer vessel is operated at a temperature from 200° C. to 270° C. 
     
     
         4 . The process of  claim 1  wherein the recycled oxidized asphalt feed rate is at least 5 times greater than that of the fresh asphalt feed rate. 
     
     
         5 . The process of  claim 4  wherein the recycled oxidized asphalt feed rate is at least 20 times greater than that of the fresh asphalt feed rate. 
     
     
         6 . The process of  claim 1  wherein the oxidizer vessel is operated at a pressure of from 0 to 10 barg. 
     
     
         7 . The process of  claim 6  wherein the oxidizer vessel is operated at a to pressure of from 0 to 5 barg. 
     
     
         8 . The process of  claim 1  wherein the air feed rate is at least a stoichiometric amount based on the preheated asphalt feed rate. 
     
     
         9 . The process of  claim 1  further including the step of injecting steam from a steam generator to the oxidizer vessel. 
     
     
         10 . The process of  claim 9  wherein the injecting steam to the oxidizer vessel is above or below the liquid mixture in the oxidizer vessel. 
     
     
         11 . The process of  claim 1  wherein the air is compressed. 
     
     
         12 . The process of  claim 1  wherein the air is atmospheric. 
     
     
         13 . Oxidized asphalt produced by the process of  claim 1 .